Magnetic Circular Dichroism Evidence for an Unusual Electronic Structure of a Tetracarbene-Oxoiron(IV) Complex

In biology, high valent oxo-iron(IV) species have been shown to be pivotal intermediates for functionalization of C-H bonds in the catalytic cycles of a range of O -activating iron enzymes. This work details an electronic-structure investigation of [Fe (O)(L )(NCMe)] (L = 3,9,14,20-tetraaza-1,6,12,1...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 138; no. 43; p. 14312
Main Authors:	Ye, Shengfa, Kupper, Claudia, Meyer, Steffen, Andris, Erik, Navrátil, Rafael, Krahe, Oliver, Mondal, Bhaskar, Atanasov, Mihail, Bill, Eckhard, Roithová, Jana, Meyer, Franc, Neese, Frank
Format:	Journal Article
Language:	English
Published:	United States 02.11.2016
ISSN:	1520-5126, 1520-5126
Online Access:	Get more information
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