Aromatic Monomers by in Situ Conversion of Reactive Intermediates in the Acid-Catalyzed Depolymerization of Lignin
Conversion of lignin into well-defined aromatic chemicals is a highly attractive goal but is often hampered by recondensation of the formed fragments, especially in acidolysis. Here, we describe new strategies that markedly suppress such undesired pathways to result in diverse aromatic compounds pre...
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| Published in: | Journal of the American Chemical Society Vol. 137; no. 23; pp. 7456 - 7467 |
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| Main Authors: | , , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
WASHINGTON
Amer Chemical Soc
17.06.2015
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| Subjects: | |
| ISSN: | 0002-7863, 1520-5126 |
| Online Access: | Get more information |
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| Abstract | Conversion of lignin into well-defined aromatic chemicals is a highly attractive goal but is often hampered by recondensation of the formed fragments, especially in acidolysis. Here, we describe new strategies that markedly suppress such undesired pathways to result in diverse aromatic compounds previously not systematically targeted from lignin: Model studies established that a catalytic amount of triflic acid is very effective in cleaving the beta-O-4 linkage, most abundant in lignin. An aldehyde product was identified as the main cause of side reactions under cleavage conditions. Capturing this unstable compound by reaction with diols and by in situ catalytic hydrogenation or decarbonylation lead to three distinct groups of aromatic compounds in high yields acetals, ethanol and ethyl aromatics, and methyl aromatics. Notably, the same product groups were obtained when these approaches were successfully extended to lignin. In addition, the formation of higher molecular weight side products was markedly suppressed, indicating that the aldehyde intermediates play a significant role in these processes. The described strategy has the potential to be generally applicable for the production of interesting aromatic compounds from lignin. |
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| AbstractList | Conversion of lignin into well-defined aromatic chemicals is a highly attractive goal but is often hampered by recondensation of the formed fragments, especially in acidolysis. Here, we describe new strategies that markedly suppress such undesired pathways to result in diverse aromatic compounds previously not systematically targeted from lignin. Model studies established that a catalytic amount of triflic acid is very effective in cleaving the β-O-4 linkage, most abundant in lignin. An aldehyde product was identified as the main cause of side reactions under cleavage conditions. Capturing this unstable compound by reaction with diols and by in situ catalytic hydrogenation or decarbonylation lead to three distinct groups of aromatic compounds in high yields acetals, ethanol and ethyl aromatics, and methyl aromatics. Notably, the same product groups were obtained when these approaches were successfully extended to lignin. In addition, the formation of higher molecular weight side products was markedly suppressed, indicating that the aldehyde intermediates play a significant role in these processes. The described strategy has the potential to be generally applicable for the production of interesting aromatic compounds from lignin. Conversion of lignin into well-defined aromatic chemicals is a highly attractive goal but is often hampered by recondensation of the formed fragments, especially in acidolysis. Here, we describe new strategies that markedly suppress such undesired pathways to result in diverse aromatic compounds previously not systematically targeted from lignin: Model studies established that a catalytic amount of triflic acid is very effective in cleaving the beta-O-4 linkage, most abundant in lignin. An aldehyde product was identified as the main cause of side reactions under cleavage conditions. Capturing this unstable compound by reaction with diols and by in situ catalytic hydrogenation or decarbonylation lead to three distinct groups of aromatic compounds in high yields acetals, ethanol and ethyl aromatics, and methyl aromatics. Notably, the same product groups were obtained when these approaches were successfully extended to lignin. In addition, the formation of higher molecular weight side products was markedly suppressed, indicating that the aldehyde intermediates play a significant role in these processes. The described strategy has the potential to be generally applicable for the production of interesting aromatic compounds from lignin. |
| Author | Deuss, Peter J. Scott, Martin Tran, Fanny Barta, Katalin Westwood, Nicholas J. de Vries, Johannes G. |
| Author_xml | – sequence: 1 givenname: Peter J. orcidid: 0000-0002-2254-2500 surname: Deuss fullname: Deuss, Peter J. organization: Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands – sequence: 2 givenname: Martin orcidid: 0000-0002-9830-3856 surname: Scott fullname: Scott, Martin organization: Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands – sequence: 3 givenname: Fanny surname: Tran fullname: Tran, Fanny organization: Univ St Andrews, Sch Chem & Biomed Sci Res Complex, St Andrews KY16 9ST, Fife, Scotland – sequence: 4 givenname: Nicholas J. orcidid: 0000-0003-0630-0138 surname: Westwood fullname: Westwood, Nicholas J. organization: Univ St Andrews, Sch Chem & Biomed Sci Res Complex, St Andrews KY16 9ST, Fife, Scotland – sequence: 5 givenname: Johannes G. orcidid: 0000-0001-5245-7748 surname: de Vries fullname: de Vries, Johannes G. email: johannes.devries@catalysis.de organization: Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands – sequence: 6 givenname: Katalin surname: Barta fullname: Barta, Katalin email: k.barta@rug.nl organization: Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26001165$$D View this record in MEDLINE/PubMed |
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| Keywords | OXIDATION HYDROGENOLYSIS O BOND-CLEAVAGE ORGANOSOLV LIGNIN METAL-CATALYSTS ETHANOLYSIS PRODUCTS DEGRADATION ARYL ETHERS MODEL COMPOUNDS RENEWABLE CHEMICALS |
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| Snippet | Conversion of lignin into well-defined aromatic chemicals is a highly attractive goal but is often hampered by recondensation of the formed fragments,... |
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| SubjectTerms | Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology |
| Title | Aromatic Monomers by in Situ Conversion of Reactive Intermediates in the Acid-Catalyzed Depolymerization of Lignin |
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