Comb polymers prepared by ATRP from hydroxypropyl cellulose

Hydroxypropyl cellulose (HPC) was used as a core molecule for controlled grafting of monomers by ATRP, the aim being to produce densely grafted comb polymers. HPC was either allowed to react with an ATRP initiator or the first generation initiator-functionalized 2,2-bis(methylol)propionic acid dendr...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Biomacromolecules Jg. 8; H. 4; S. 1138 - 1148
Hauptverfasser:	Ostmark, Emma, Harrisson, Simon, Wooley, Karen L., Malmstrom, Eva E.
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	WASHINGTON Amer Chemical Soc 01.04.2007
Schlagworte:	Biochemistry & Molecular Biology Carbohydrate Conformation Carbohydrate Sequence Cellulose - analogs & derivatives Cellulose - chemistry Chemistry Chemistry, Organic Life Sciences & Biomedicine Molecular Sequence Data Particle Size Physical Sciences Polymer Science Polymers - chemical synthesis Polymers - chemistry Rheology Science & Technology Temperature POLYESTERS BLOCK-COPOLYMERS TEMPERATURE DIVERGENT SYNTHESIS SURFACE INTERFACES SCANNING FORCE MICROSCOPY TRANSFER RADICAL POLYMERIZATION DENDRONIZED POLYMERS REAL-TIME
ISSN:	1525-7797, 1526-4602
Online-Zugang:	Weitere Angaben
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Abstract	Hydroxypropyl cellulose (HPC) was used as a core molecule for controlled grafting of monomers by ATRP, the aim being to produce densely grafted comb polymers. HPC was either allowed to react with an ATRP initiator or the first generation initiator-functionalized 2,2-bis(methylol)propionic acid dendron to create macroinitiators having high degrees of functionality. The macroinitiators were then "grafted from" using ATRP of methyl methacrylate (MMA) or hexadecyl methacrylate. Block copolymers were obtained by chain extending PMMA-grafted HPCs via the ATRP of tert-butyl acrylate. Subsequent selective acidolysis of the tert-butyl ester moieties was performed to form a block of poly(acrylic acid) resulting in amphiphilic block copolymer grafts. The graft copolymers were characterized by H-1 NMR and FT-IR spectroscopies, DSC, TGA, rheological measurements, DLS, and tapping mode AFM on samples spin coated upon mica. It was found that the comb (co)polymers were in the nanometer size range and that the dendronization had an interesting effect on the rheological properties.
AbstractList	Hydroxypropyl cellulose (HPC) was used as a core molecule for controlled grafting of monomers by ATRP, the aim being to produce densely grafted comb polymers. HPC was either allowed to react with an ATRP initiator or the first generation initiator-functionalized 2,2-bis(methylol)propionic acid dendron to create macroinitiators having high degrees of functionality. The macroinitiators were then "grafted from" using ATRP of methyl methacrylate (MMA) or hexadecyl methacrylate. Block copolymers were obtained by chain extending PMMA-grafted HPCs via the ATRP of tert-butyl acrylate. Subsequent selective acidolysis of the tert-butyl ester moieties was performed to form a block of poly(acrylic acid) resulting in amphiphilic block copolymer grafts. The graft copolymers were characterized by 1H NMR and FT-IR spectroscopies, DSC, TGA, rheological measurements, DLS, and tapping mode AFM on samples spin coated upon mica. It was found that the comb (co)polymers were in the nanometer size range and that the dendronization had an interesting effect on the rheological properties. Hydroxypropyl cellulose (HPC) was used as a core molecule for controlled grafting of monomers by ATRP, the aim being to produce densely grafted comb polymers. HPC was either allowed to react with an ATRP initiator or the first generation initiator-functionalized 2,2-bis(methylol)propionic acid dendron to create macroinitiators having high degrees of functionality. The macroinitiators were then "grafted from" using ATRP of methyl methacrylate (MMA) or hexadecyl methacrylate. Block copolymers were obtained by chain extending PMMA-grafted HPCs via the ATRP of tert-butyl acrylate. Subsequent selective acidolysis of the tert-butyl ester moieties was performed to form a block of poly(acrylic acid) resulting in amphiphilic block copolymer grafts. The graft copolymers were characterized by H-1 NMR and FT-IR spectroscopies, DSC, TGA, rheological measurements, DLS, and tapping mode AFM on samples spin coated upon mica. It was found that the comb (co)polymers were in the nanometer size range and that the dendronization had an interesting effect on the rheological properties. Hydroxypropyl cellulose (HPC) was used as a core molecule for controlled grafting of monomers by ATRP, the aim being to produce densely grafted comb polymers. HPC was either allowed to react with an ATRP initiator or the first generation initiator-functionalized 2,2-bis(methylol)propionic acid dendron to create macroinitiators having high degrees of functionality. The macroinitiators were then "grafted from" using ATRP of methyl methacrylate (MMA) or hexadecyl methacrylate. Block copolymers were obtained by chain extending PMMA-grafted HPCs via the ATRP of tert-butyl acrylate. Subsequent selective acidolysis of the tert-butyl ester moieties was performed to form a block of poly(acrylic acid) resulting in amphiphilic block copolymer grafts. The graft copolymers were characterized by 1H NMR and FT-IR spectroscopies, DSC, TGA, rheological measurements, DLS, and tapping mode AFM on samples spin coated upon mica. It was found that the comb (co)polymers were in the nanometer size range and that the dendronization had an interesting effect on the rheological properties.Hydroxypropyl cellulose (HPC) was used as a core molecule for controlled grafting of monomers by ATRP, the aim being to produce densely grafted comb polymers. HPC was either allowed to react with an ATRP initiator or the first generation initiator-functionalized 2,2-bis(methylol)propionic acid dendron to create macroinitiators having high degrees of functionality. The macroinitiators were then "grafted from" using ATRP of methyl methacrylate (MMA) or hexadecyl methacrylate. Block copolymers were obtained by chain extending PMMA-grafted HPCs via the ATRP of tert-butyl acrylate. Subsequent selective acidolysis of the tert-butyl ester moieties was performed to form a block of poly(acrylic acid) resulting in amphiphilic block copolymer grafts. The graft copolymers were characterized by 1H NMR and FT-IR spectroscopies, DSC, TGA, rheological measurements, DLS, and tapping mode AFM on samples spin coated upon mica. It was found that the comb (co)polymers were in the nanometer size range and that the dendronization had an interesting effect on the rheological properties.
Author	Malmstrom, Eva E. Harrisson, Simon Wooley, Karen L. Ostmark, Emma
Author_xml	– sequence: 1 givenname: Emma surname: Ostmark fullname: Ostmark, Emma – sequence: 2 givenname: Simon orcidid: 0000-0001-6267-2599 surname: Harrisson fullname: Harrisson, Simon – sequence: 3 givenname: Karen L. orcidid: 0000-0003-4086-384X surname: Wooley fullname: Wooley, Karen L. – sequence: 4 givenname: Eva E. surname: Malmstrom fullname: Malmstrom, Eva E. email: mave@polymer.kth.se
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/17367185$$D View this record in MEDLINE/PubMed
BookMark	eNqNkEtPg0AUhSemxrbowj9gWLkx6NxhHhBXDfGVNNGYuiYMXCIGGJyBVP691FbXru5ZfDn57lmSWWtaJOQc6DVQBje6oRIoD7dHZAGCyYBLymY_WQRKxWpOls59UErjkIsTMgcVSgWRWJDbxDTa70w9Nmid31nsMouFr0d_tXl98UtrGv99LKz5GjtrurH2c6zroTYOT8lxmdUOzw7XI2_3d5vkMVg_Pzwlq3WQcS76IAtLqSXXpaZKc60L4FEMWigFmpdQxErHOYLkFHLkEWOCAzAKZc6inSfzyOW-dxL4HND1aVO5nUXWohlcqmgoaTwt4ZGLAzjoBou0s1WT2TH9fXcCrvbAFrUpXV5hm-MfNu3DuBBAYUoQTnT0fzqp-qyvTJuYoe3ZN8kkd2E
CitedBy_id	crossref_primary_10_1016_j_carbpol_2014_09_037 crossref_primary_10_1016_j_progpolymsci_2009_08_001 crossref_primary_10_1002_pola_29481 crossref_primary_10_1002_pola_22406 crossref_primary_10_1021_ma702681u crossref_primary_10_1039_b808639g crossref_primary_10_1016_j_polymer_2012_01_003 crossref_primary_10_1016_j_eurpolymj_2010_01_021 crossref_primary_10_1039_D1PY01322J crossref_primary_10_4028_www_scientific_net_AMR_221_90 crossref_primary_10_1002_pola_23011 crossref_primary_10_1016_j_carbpol_2013_03_011 crossref_primary_10_1016_j_polymer_2009_06_045 crossref_primary_10_1002_pola_29171 crossref_primary_10_1016_j_polymer_2008_10_060 crossref_primary_10_1016_j_progpolymsci_2010_11_005 crossref_primary_10_1002_pi_3090 crossref_primary_10_1007_s10570_023_05345_y crossref_primary_10_1016_j_eurpolymj_2015_01_041 crossref_primary_10_1002_cjoc_201200658 crossref_primary_10_3389_fchem_2019_00367 crossref_primary_10_1002_marc_201000072 crossref_primary_10_1016_j_eurpolymj_2011_10_010 crossref_primary_10_1017_S0007114511003497 crossref_primary_10_1016_j_surfin_2024_105590 crossref_primary_10_1016_j_polymer_2008_11_011 crossref_primary_10_1007_s40242_013_2058_2 crossref_primary_10_1016_j_eurpolymj_2022_111476 crossref_primary_10_1007_s10965_012_9842_4 crossref_primary_10_1016_j_carbpol_2012_09_014 crossref_primary_10_1016_j_polymer_2015_05_041 crossref_primary_10_1002_pola_24409 crossref_primary_10_1016_j_apsusc_2011_10_087 crossref_primary_10_1021_ma800216v crossref_primary_10_1038_ncomms8237 crossref_primary_10_1007_s10570_008_9218_4 crossref_primary_10_1002_pola_23553 crossref_primary_10_1007_s10965_015_0838_8 crossref_primary_10_1080_10601325_2019_1673174 crossref_primary_10_1007_s10965_011_9782_4 crossref_primary_10_1021_ma9003715 crossref_primary_10_1016_j_ijbiomac_2016_09_104 crossref_primary_10_1016_j_jconrel_2017_12_033 crossref_primary_10_1016_j_carbpol_2010_02_017 crossref_primary_10_1016_j_eurpolymj_2009_07_003 crossref_primary_10_1039_C4CS00053F crossref_primary_10_1002_pi_2782 crossref_primary_10_1016_j_carbpol_2011_07_037 crossref_primary_10_15171_apb_2019_015 crossref_primary_10_1007_s13233_013_1080_z crossref_primary_10_1080_01932691_2016_1277358 crossref_primary_10_1002_pola_24876 crossref_primary_10_1007_s10853_009_3843_7 crossref_primary_10_1002_app_43405 crossref_primary_10_1039_D1PY01442K crossref_primary_10_1016_j_ijbiomac_2025_140856 crossref_primary_10_1002_app_51458 crossref_primary_10_1002_pola_24431 crossref_primary_10_1016_j_jcis_2009_01_050 crossref_primary_10_1111_j_1467_789X_2012_01020_x crossref_primary_10_1016_j_carbpol_2015_11_001 crossref_primary_10_1016_j_carbpol_2018_07_060
Cites_doi	10.1039/b304204a 10.1002/pola.20918 10.1016/S0039-6028(03)00388-1 10.1002/app.12194 10.1021/ma049432a 10.1021/ja016582h 10.1021/ma0347464 10.1021/ma048722o 10.1016/j.eurpolymj.2005.04.040 10.1002/pi.1684 10.1002/marc.200400423 10.1002/pat.389 10.1016/j.polymer.2005.06.028 10.1002/pola.20846 10.1021/bm034352k 10.1021/bm050465n 10.1016/j.polymer.2004.08.042 10.1021/ma050701m 10.1002/pola.20703 10.1021/jp058081e 10.1021/la047490j 10.1002/pola.20216 10.1021/ma010698g 10.1002/app.23457 10.1021/ma021472w 10.1021/bm030046v 10.1039/b307425k 10.1021/ja061892r 10.1002/chem.200400174 10.1002/pola.10190 10.1002/pola.20908 10.1016/j.polymer.2005.04.061 10.1016/j.polymer.2006.02.067 10.1021/bm034421v
ContentType	Journal Article
DBID	17B 1KM BLEPL DTL EGQ GAMXJ CGR CUY CVF ECM EIF NPM 7X8
DOI	10.1021/bm061043w
DatabaseName	Web of Knowledge Index Chemicus Web of Science Core Collection Science Citation Index Expanded Web of Science Primary (SCIE, SSCI & AHCI) Web of Science - Science Citation Index Expanded - 2007 Medline MEDLINE MEDLINE (Ovid) MEDLINE MEDLINE PubMed MEDLINE - Academic
DatabaseTitle	Web of Science MEDLINE Medline Complete MEDLINE with Full Text PubMed MEDLINE (Ovid) MEDLINE - Academic
DatabaseTitleList	MEDLINE Web of Science MEDLINE - Academic
Database_xml	– sequence: 1 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 2 dbid: 1KM name: Index Chemicus url: https://www.webofscience.com/wos/woscc/search-with-editions?editions=WOS.IC sourceTypes: Enrichment Source Index Database – sequence: 3 dbid: 7X8 name: MEDLINE - Academic url: https://search.proquest.com/medline sourceTypes: Aggregation Database
DeliveryMethod	no_fulltext_linktorsrc
Discipline	Chemistry
EISSN	1526-4602
EndPage	1148
ExternalDocumentID	17367185 000245510100013
Genre	Research Support, U.S. Gov't, Non-P.H.S Research Support, Non-U.S. Gov't Journal Article Research Support, N.I.H., Extramural
GrantInformation_xml	– fundername: NATIONAL HEART, LUNG, AND BLOOD INSTITUTE; United States Department of Health & Human Services; National Institutes of Health (NIH) - USA; NIH National Heart Lung & Blood Institute (NHLBI) grantid: U01HL080729 – fundername: NHLBI NIH HHS; United States Department of Health & Human Services; National Institutes of Health (NIH) - USA; NIH National Heart Lung & Blood Institute (NHLBI) grantid: HL080729 – fundername: NHLBI NIH HHS grantid: HL080729
GroupedDBID	--- -~X 17B 1KM 23N 4.4 53G 55A 5GY 5VS 7~N AABXI AAHBH ABBLG ABJNI ABLBI ABMVS ABQRX ABUCX ACGFS ACS ADHLV AEESW AENEX AFEFF AFFNX AHGAQ ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH BLEPL CS3 CUPRZ DTL DU5 EBS ED~ EJD F5P GGK GNL GROUPED_WOS_SCIENCE_CITATION_INDEX_EXPANDED GROUPED_WOS_WEB_OF_SCIENCE IH9 IHE JG~ LG6 P2P RNS ROL TN5 UI2 VF5 VG9 W1F XKZ ZCA ~02 CGR CUY CVF ECM EIF NPM PKN 7X8
ID	FETCH-LOGICAL-a445t-a3f6b64bfb07b4bbd14891b5771b4f1d97b9ce16401ce48225411201fc2873672
IEDL.DBID	7X8
ISICitedReferencesCount	98
ISICitedReferencesURI	https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=CitingArticles&UT=000245510100013
ISSN	1525-7797
IngestDate	Fri Jul 11 17:04:06 EDT 2025 Wed Feb 19 02:42:32 EST 2025 Fri Dec 05 23:01:05 EST 2025 Wed Jul 09 14:07:05 EDT 2025
IsPeerReviewed	true
IsScholarly	true
Issue	4
Keywords	POLYESTERS BLOCK-COPOLYMERS TEMPERATURE DIVERGENT SYNTHESIS SURFACE INTERFACES SCANNING FORCE MICROSCOPY TRANSFER RADICAL POLYMERIZATION DENDRONIZED POLYMERS REAL-TIME
Language	English
LinkModel	DirectLink
LogoURL	https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg
MergedId	FETCHMERGED-LOGICAL-a445t-a3f6b64bfb07b4bbd14891b5771b4f1d97b9ce16401ce48225411201fc2873672
Notes	Medline NIH RePORTER ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ORCID	0000-0003-4086-384X 0000-0001-6267-2599
PMID	17367185
PQID	70360910
PQPubID	23479
PageCount	11
ParticipantIDs	webofscience_primary_000245510100013 webofscience_primary_000245510100013CitationCount pubmed_primary_17367185 proquest_miscellaneous_70360910
PublicationCentury	2000
PublicationDate	2007-04-01
PublicationDateYYYYMMDD	2007-04-01
PublicationDate_xml	– month: 04 year: 2007 text: 2007-04-01 day: 01
PublicationDecade	2000
PublicationPlace	WASHINGTON
PublicationPlace_xml	– name: WASHINGTON – name: United States
PublicationTitle	Biomacromolecules
PublicationTitleAbbrev	BIOMACROMOLECULES
PublicationTitleAlternate	Biomacromolecules
PublicationYear	2007
Publisher	Amer Chemical Soc
Publisher_xml	– name: Amer Chemical Soc
References	Das, JJ (WOS:000228231200012) 2005; 109 Lee, CC (WOS:000229274800009) 2005; 16 Lee, SB (WOS:000221315200034) 2004; 5 WANG C (WOS:000245510100013.46) 2002; 41 Carlmark, A (WOS:000224197500011) 2004; 37 Stenzel, MH (WOS:000184874100010) 2003; 13 Shen, DW (WOS:000231524100008) 2005; 43 Matyjaszewski, K (WOS:000084540800004) 1999; 32 Qin, SH (WOS:000180868000017) 2003; 36 Cheng, C (WOS:000237816300023) 2006; 128 Schluter, AD (WOS:000085745300002) 2000; 39 Hassan, ML (WOS:000226111300001) 2004; 25 Wang, Y (WOS:000182639100003) 2003; 530 Carlmark, A (WOS:000186729700037) 2003; 4 Lindqvist, J (WOS:000237016200094) 2006; 100 Grayson, SM (WOS:000170853500006) 2001; 34 Lee, CC (WOS:000222420200017) 2004; 42 Liang, CO (WOS:000185750900003) 2003 Heise, A (WOS:000086343500012) 2000; 33 Gallyamov, MO (WOS:000224508000008) 2004; 25 Shi, RW (WOS:000182931900020) 2003; 89 Johnson, RM (WOS:000220109200044) 2004; 5 Gallyamov, MO (WOS:000223850700006) 2004; 215 Gomez-Carracedo, A (WOS:000184955200017) 2003; 73 Ihre, H (WOS:A1996UW48500007) 1996; 118 Zhao, YL (WOS:000230374400048) 2005; 46 Luda, MP (WOS:000188503000002) 2003; 14 Nystrom, A (WOS:000231369700015) 2005; 43 Carlmark, A (WOS:000173783500007) 2002; 124 Hassan, ML (WOS:000232172900007) 2005; 46 Nystrom, AM (WOS:000231989400018) 2005; 43 Vlcek, P (WOS:000236817700002) 2006; 47 Helms, B (WOS:000230023400011) 2005; 38 Maier, S (WOS:000086217600005) 2000; 21 Cheng, CX (WOS:000229086900010) 2005; 43 Yoshida, M (WOS:000226466700018) 2005; 38 Zhang, CD (WOS:000234549100021) 2006; 7 Feng, CL (WOS:000227578700036) 2005; 21 Daly, WH (WOS:000171539100019) 2001; 174 HAWKER, CJ (WOS:A1992HL44000024) 1992; 33 Ning, FL (WOS:000175181400006) 2002; 40 Gallyamov, MO (WOS:000224146800024) 2004; 10 Coskun, M (WOS:000226731900015) 2005; 54 Malkoch, M (WOS:000188383100015) 2004; 37 Hernandez-Guerrero, M (WOS:000232046200007) 2005; 41 (WOS:000245510100013.1) 1987 Shen, DW (WOS:000224213800008) 2004; 45 Claesson, H (WOS:000175439400016) 2002; 43 Ma, QG (WOS:000165713600019) 2000; 38
References_xml	– volume: 13 start-page: 2090 year: 2003 ident: WOS:000184874100010 article-title: Honeycomb structured porous films prepared from carbohydrate based polymers synthesized via the RAFT process publication-title: JOURNAL OF MATERIALS CHEMISTRY doi: 10.1039/b304204a – volume: 43 start-page: 4496 year: 2005 ident: WOS:000231989400018 article-title: Bulk properties of dendronized polymers with tailored end-groups emanating from the same backbone publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY doi: 10.1002/pola.20918 – volume: 530 start-page: 136 year: 2003 ident: WOS:000182639100003 article-title: Understanding tapping-mode atomic force microscopy data on the surface of soft block copolymers publication-title: SURFACE SCIENCE doi: 10.1016/S0039-6028(03)00388-1 – volume: 89 start-page: 718 year: 2003 ident: WOS:000182931900020 article-title: Synthesis and characterization of amphiphilic hydroxypropylcellulose-graft-poly(epsilon-caprolactone) publication-title: JOURNAL OF APPLIED POLYMER SCIENCE doi: 10.1002/app.12194 – volume: 37 start-page: 7491 year: 2004 ident: WOS:000224197500011 article-title: ATRP of dendronized aliphatic macromonomers of generation one, two, and three publication-title: MACROMOLECULES doi: 10.1021/ma049432a – volume: 21 start-page: 226 year: 2000 ident: WOS:000086217600005 article-title: Synthesis of poly(glycerol)-block-poly(methyl acrylate) multi-arm star polymers publication-title: MACROMOLECULAR RAPID COMMUNICATIONS – volume: 124 start-page: 900 year: 2002 ident: WOS:000173783500007 article-title: Atom transfer radical polymerization from cellulose fibers at ambient temperature publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja016582h – volume: 37 start-page: 322 year: 2004 ident: WOS:000188383100015 article-title: Dendronized aliphatic polymers by a combination of ATRP and divergent growth publication-title: MACROMOLECULES doi: 10.1021/ma0347464 – volume: 38 start-page: 334 year: 2005 ident: WOS:000226466700018 article-title: Efficient divergent synthesis of dendronized polymers with extremely high molecular weight: Structural characterization by SEC-MALLS and SFM and novel organic gelation behavior publication-title: MACROMOLECULES doi: 10.1021/ma048722o – volume: 41 start-page: 2264 year: 2005 ident: WOS:000232046200007 article-title: Polystyrene comb polymers built on cellulose or poly(styrene-co-2-hydroxyethylmethacrylate) backbones as substrates for the preparation of structured honeycomb films publication-title: EUROPEAN POLYMER JOURNAL doi: 10.1016/j.eurpolymj.2005.04.040 – volume: 174 start-page: 155 year: 2001 ident: WOS:000171539100019 article-title: Recent developments in cellulose grafting chemistry utilizing barton ester intermediates and nitroxide mediation publication-title: MACROMOLECULAR SYMPOSIA – volume: 54 start-page: 342 year: 2005 ident: WOS:000226731900015 article-title: Grafting studies onto cellulose by atom-transfer radical polymerization publication-title: POLYMER INTERNATIONAL doi: 10.1002/pi.1684 – volume: 25 start-page: 1999 year: 2004 ident: WOS:000226111300001 article-title: Regioselective dendritic functionalization of cellulose publication-title: MACROMOLECULAR RAPID COMMUNICATIONS doi: 10.1002/marc.200400423 – volume: 14 start-page: 741 year: 2003 ident: WOS:000188503000002 article-title: Thermal degradation of a brominated bisphenol a derivative publication-title: POLYMERS FOR ADVANCED TECHNOLOGIES doi: 10.1002/pat.389 – volume: 46 start-page: 8947 year: 2005 ident: WOS:000232172900007 article-title: Regioselective combinatorial-type synthesis, characterization, and physical properties of dendronized cellulose publication-title: POLYMER doi: 10.1016/j.polymer.2005.06.028 – volume: 43 start-page: 3852 year: 2005 ident: WOS:000231369700015 article-title: Dendronized polymers with tailored surface groups publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY doi: 10.1002/pola.20846 – volume: 5 start-page: 877 year: 2004 ident: WOS:000221315200034 article-title: Permanent, nonleaching antibacterial surfaces. 1. Synthesis by atom transfer radical polymerization publication-title: BIOMACROMOLECULES doi: 10.1021/bm034352k – volume: 7 start-page: 139 year: 2006 ident: WOS:000234549100021 article-title: Synthesis and characterization of a trifunctional aminoamide cellulose derivative publication-title: BIOMACROMOLECULES doi: 10.1021/bm050465n – volume: 45 start-page: 7091 year: 2004 ident: WOS:000224213800008 article-title: The synthesis of CDA-g-PMMA copolymers through atom transfer radical polymerization publication-title: POLYMER doi: 10.1016/j.polymer.2004.08.042 – volume: 38 start-page: 5411 year: 2005 ident: WOS:000230023400011 article-title: Effects of polymer architecture and nanoenvironment in acylation reactions employing dendritic (dialkylamino)pyridine catalysts publication-title: MACROMOLECULES doi: 10.1021/ma050701m – volume: 43 start-page: 2291 year: 2005 ident: WOS:000229086900010 article-title: Multiple morphologies from a novel diblock copolymer containing dendronized polymethacrylate and linear poly(ethylene oxide) publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY doi: 10.1002/pola.20703 – volume: 109 start-page: 6535 year: 2005 ident: WOS:000228231200012 article-title: A dendronized polymer is a single-molecule glass publication-title: JOURNAL OF PHYSICAL CHEMISTRY B doi: 10.1021/jp058081e – volume: 118 start-page: 6388 year: 1996 ident: WOS:A1996UW48500007 article-title: Synthesis, characterization, and H-1 NMR self-diffusion studies of dendritic aliphatic polyesters based on 2,2-bis(hydroxymethyl)propionic acid and 1,1,1-tris(hydroxyphenyl)ethane publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 21 start-page: 2356 year: 2005 ident: WOS:000227578700036 article-title: Interfacial reactions in confinement: Kinetics and temperature dependence of the surface hydrolysis of polystyrene-block-poly(tert-butyl acrylate) thin films publication-title: LANGMUIR doi: 10.1021/la047490j – volume: 38 start-page: 4805 year: 2000 ident: WOS:000165713600019 article-title: The preparation of t-butyl acrylate, methyl acrylate, and styrene block copolymers by atom transfer radical polymerization: Precursors to amphiphilic and hydrophilic block copolymers and conversion to complex nanostructured materials publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY – volume: 42 start-page: 3563 year: 2004 ident: WOS:000222420200017 article-title: Synthesis of narrow-polydispersity degradable dendronized aliphatic polyesters publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY doi: 10.1002/pola.20216 – volume: 25 start-page: 1703 year: 2004 ident: WOS:000224508000008 article-title: Real-time scanning force microscopy of a macromolecular conformational transitions publication-title: MACROMOLECULAR RAPID COMMUNICATIONS – volume: 32 start-page: 8716 year: 1999 ident: WOS:000084540800004 article-title: Polymers at interfaces: Using atom transfer radical polymerization in the controlled growth of homopolymers and block copolymers from silicon surfaces in the absence of untethered sacrificial initiator publication-title: MACROMOLECULES – volume: 34 start-page: 6542 year: 2001 ident: WOS:000170853500006 article-title: Divergent synthesis of dendronized poly(p-hydroxystyrene) publication-title: MACROMOLECULES doi: 10.1021/ma010698g – volume: 100 start-page: 4155 year: 2006 ident: WOS:000237016200094 article-title: Surface modification of natural substrates by atom transfer radical polymerization publication-title: JOURNAL OF APPLIED POLYMER SCIENCE doi: 10.1002/app.23457 – volume: 36 start-page: 605 year: 2003 ident: WOS:000180868000017 article-title: Synthesis and visualization of densely grafted molecular brushes with crystallizable poly(octadecyl methacrylate) block segments publication-title: MACROMOLECULES doi: 10.1021/ma021472w – volume: 4 start-page: 1740 year: 2003 ident: WOS:000186729700037 article-title: ATRP grafting from cellulose fibers to create block-copolymer grafts publication-title: BIOMACROMOLECULES doi: 10.1021/bm030046v – volume: 73 start-page: 587 year: 2003 ident: WOS:000184955200017 article-title: Chemical structure and glass transition temperature of non-ionic cellulose ethers DSC, TMDSC (R) - Oscillatory rheometry study publication-title: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY – start-page: 2524 year: 2003 ident: WOS:000185750900003 article-title: Dendronized cyclocopolymers with a radial gradient of polarity and their use to catalyze a difficult esterification publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/b307425k – volume: 16 start-page: 535 year: 2005 ident: WOS:000229274800009 article-title: In vitro and in vivo evaluation of hydrophilic dendronized linear polymers publication-title: BIOCONJUGATE CHEMISTRY – volume: 215 start-page: 245 year: 2004 ident: WOS:000223850700006 article-title: Conformational dynamics of single molecules visualized in real time by scanning force microscopy: macromolecular mobility on a substrate surface in different vapours publication-title: JOURNAL OF MICROSCOPY – volume: 128 start-page: 6808 year: 2006 ident: WOS:000237816300023 article-title: Tandem synthesis of core-shell brush copolymers and their transformation to peripherally cross-linked and hollowed nanostructures publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja061892r – volume: 39 start-page: 864 year: 2000 ident: WOS:000085745300002 article-title: Dendronized polymers: Synthesis, characterization, assembly at interfaces, and manipulation publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION – volume: 43 start-page: 3511 year: 2002 ident: WOS:000175439400016 article-title: Synthesis and characterisation of star branched polyesters with dendritic cores and the effect of structural variations on zero shear rate viscosity publication-title: POLYMER – volume: 10 start-page: 4599 year: 2004 ident: WOS:000224146800024 article-title: Reversible collapse of brushlike macromolecules in ethanol and water vapours as revealed by real-time scanning force microscopy publication-title: CHEMISTRY-A EUROPEAN JOURNAL doi: 10.1002/chem.200400174 – year: 1987 ident: WOS:000245510100013.1 – volume: 33 start-page: 2346 year: 2000 ident: WOS:000086343500012 article-title: Starlike polymeric architectures by atom transfer radical polymerization: Templates for the production of low dielectric constant thin films publication-title: MACROMOLECULES – volume: 40 start-page: 1253 year: 2002 ident: WOS:000175181400006 article-title: Synthesis of amphiphilic block-graft copolymers [poly(styrene-b-ethylene-co-butylene-b-styrene)-g-poly(acrylic acid)] and their aggregation in water publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY doi: 10.1002/pola.10190 – volume: 41 start-page: 273 year: 2002 ident: WOS:000245510100013.46 publication-title: J POLYM SCI A – volume: 43 start-page: 4099 year: 2005 ident: WOS:000231524100008 article-title: Densely grafting copolymers of ethyl cellulose through atom transfer radical polymerization publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY doi: 10.1002/pola.20908 – volume: 46 start-page: 5808 year: 2005 ident: WOS:000230374400048 article-title: Synthesis of well-defined star polymers and star block copolymers from dendrimer initiators by atom transfer radical polymerization publication-title: POLYMER doi: 10.1016/j.polymer.2005.04.061 – volume: 33 start-page: 1507 year: 1992 ident: WOS:A1992HL44000024 article-title: THE SYNTHESIS AND POLYMERIZATION OF A HYPERBRANCHED POLYETHER MACROMONOMER publication-title: POLYMER – volume: 47 start-page: 2587 year: 2006 ident: WOS:000236817700002 article-title: Controlled grafting of cellulose diacetate publication-title: POLYMER doi: 10.1016/j.polymer.2006.02.067 – volume: 5 start-page: 580 year: 2004 ident: WOS:000220109200044 article-title: Metalloinitiation routes to biocompatible poly(lactic acid) and poly(acrylic acid) stars with luminescent ruthenium tris(bipyridine) cores publication-title: BIOMACROMOLECULES doi: 10.1021/bm034421v
SSID	ssj0009345
Score	2.2262
Snippet	Hydroxypropyl cellulose (HPC) was used as a core molecule for controlled grafting of monomers by ATRP, the aim being to produce densely grafted comb polymers....
Source	Web of Science
SourceID	proquest pubmed webofscience
SourceType	Aggregation Database Index Database Enrichment Source
StartPage	1138
SubjectTerms	Biochemistry & Molecular Biology Carbohydrate Conformation Carbohydrate Sequence Cellulose - analogs & derivatives Cellulose - chemistry Chemistry Chemistry, Organic Life Sciences & Biomedicine Molecular Sequence Data Particle Size Physical Sciences Polymer Science Polymers - chemical synthesis Polymers - chemistry Rheology Science & Technology Temperature
Title	Comb polymers prepared by ATRP from hydroxypropyl cellulose
URI	http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000245510100013 https://www.ncbi.nlm.nih.gov/pubmed/17367185 https://www.proquest.com/docview/70360910
Volume	8
WOS	000245510100013
WOSCitedRecordID	wos000245510100013
hasFullText
inHoldings	1
isFullTextHit
isPrint
link	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LS8NAEB6qFfTi-1EfdQ-9hmabbZJFQUqxCNpSpEJvJbvZRaE2sQ-l_96ZtFEPBQUvuSQkk2F3vm9m5wFQCa3Uwoa-I21Uc4RCB0XxUDsi0iEVTqIPkDVxfQg6nbDfl90CXOe1MJRWmdvEzFDHiaYYeZUaRRG23aRvDs2MorPV5QCNNSh6SGRoWwb9717h0stGFNOAH-SQMsj7CtV4Vb0ijLnC-1jFK1dCUAY3rZ3_CboL20uayRqLdbEHBTPah81mPt3tAK7QECiWJsM5Ba5ZOjZZKjpTc9boPXYZlZ2w53lMWS4oQDofMorxz4bJxBzCU-u217xzloMUnEiI-tSJPOsrXyir3EAJpWL0gSRX9SDgSlgey0BJbdBxcrk2AilDXSANc7nV6E95flA7gvVRMjInwIxBiI-lx01NC_QtEe897Rlf4vttKOoluMy1MsA_IsmikUlmk0GulxIcL_Q8SBf9NAacvoG8oQSVn4r_uu9m58NkPDLGWgL-l8eayx7nVNs_Pf1VrDPYWoRtKSnnHIoWd7-5gA39Pn2ZjMvIvO_b5WyB4bXTbX8C10TXUQ
linkProvider	ProQuest
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Comb+polymers+prepared+by+ATRP+from+hydroxypropyl+cellulose&rft.jtitle=Biomacromolecules&rft.au=Ostmark%2C+Emma&rft.au=Harrisson%2C+Simon&rft.au=Wooley%2C+Karen+L&rft.au=Malmstr%C3%B6m%2C+Eva+E&rft.date=2007-04-01&rft.issn=1525-7797&rft.volume=8&rft.issue=4&rft.spage=1138&rft_id=info:doi/10.1021%2Fbm061043w&rft.externalDBID=NO_FULL_TEXT
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1525-7797&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1525-7797&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1525-7797&client=summon