Strong Plasmon Reflection at Nanometer-Size Gaps in Monolayer Graphene on SiC

We employ tip-enhanced infrared near-field microscopy to study the plasmonic properties of epitaxial quasi-free-standing monolayer graphene on silicon carbide. The near-field images reveal propagating graphene plasmons, as well as a strong plasmon reflection at gaps in the graphene layer, which appe...

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Vydáno v:Nano letters Ročník 13; číslo 12; s. 6210 - 6215
Hlavní autoři: Chen, Jianing, Nesterov, Maxim L, Nikitin, Alexey Yu, Thongrattanasiri, Sukosin, Alonso-González, Pablo, Slipchenko, Tetiana M, Speck, Florian, Ostler, Markus, Seyller, Thomas, Crassee, Iris, Koppens, Frank H. L, Martin-Moreno, Luis, García de Abajo, F. Javier, Kuzmenko, Alexey B, Hillenbrand, Rainer
Médium: Journal Article
Jazyk:angličtina
Vydáno: Washington, DC American Chemical Society 11.12.2013
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ISSN:1530-6984, 1530-6992, 1530-6992
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Abstract We employ tip-enhanced infrared near-field microscopy to study the plasmonic properties of epitaxial quasi-free-standing monolayer graphene on silicon carbide. The near-field images reveal propagating graphene plasmons, as well as a strong plasmon reflection at gaps in the graphene layer, which appear at the steps between the SiC terraces. When the step height is around 1.5 nm, which is two orders of magnitude smaller than the plasmon wavelength, the reflection signal reaches 20% of its value at graphene edges, and it approaches 50% for step heights as small as 5 nm. This intriguing observation is corroborated by numerical simulations and explained by the accumulation of a line charge at the graphene termination. The associated electromagnetic fields at the graphene termination decay within a few nanometers, thus preventing efficient plasmon transmission across nanoscale gaps. Our work suggests that plasmon propagation in graphene-based circuits can be tailored using extremely compact nanostructures, such as ultranarrow gaps. It also demonstrates that tip-enhanced near-field microscopy is a powerful contactless tool to examine nanoscale defects in graphene.
AbstractList We employ tip-enhanced infrared near-field microscopy to study the plasmonic properties of epitaxial quasi-free-standing monolayer graphene on silicon carbide. The near-field images reveal propagating graphene plasmons, as well as a strong plasmon reflection at gaps in the graphene layer, which appear at the steps between the SiC terraces. When the step height is around 1.5 nm, which is two orders of magnitude smaller than the plasmon wavelength, the reflection signal reaches 20% of its value at graphene edges, and it approaches 50% for step heights as small as 5 nm. This intriguing observation is corroborated by numerical simulations and explained by the accumulation of a line charge at the graphene termination. The associated electromagnetic fields at the graphene termination decay within a few nanometers, thus preventing efficient plasmon transmission across nanoscale gaps. Our work suggests that plasmon propagation in graphene-based circuits can be tailored using extremely compact nanostructures, such as ultranarrow gaps. It also demonstrates that tip-enhanced near-field microscopy is a powerful contactless tool to examine nanoscale defects in graphene.
We employ tip-enhanced infrared near-field microscopy to study the plasmonic properties of epitaxial quasi-free-standing monolayer graphene on silicon carbide. The near-field images reveal propagating graphene plasmons, as well as a strong plasmon reflection at gaps in the graphene layer, which appear at the steps between the SiC terraces. When the step height is around 1.5 nm, which is two orders of magnitude smaller than the plasmon wavelength, the reflection signal reaches 20% of its value at graphene edges, and it approaches 50% for step heights as small as 5 nm. This intriguing observation is corroborated by numerical simulations and explained by the accumulation of a line charge at the graphene termination. The associated electromagnetic fields at the graphene termination decay within a few nanometers, thus preventing efficient plasmon transmission across nanoscale gaps. Our work suggests that plasmon propagation in graphene-based circuits can be tailored using extremely compact nanostructures, such as ultranarrow gaps. It also demonstrates that tip-enhanced near-field microscopy is a powerful contactless tool to examine nanoscale defects in graphene.We employ tip-enhanced infrared near-field microscopy to study the plasmonic properties of epitaxial quasi-free-standing monolayer graphene on silicon carbide. The near-field images reveal propagating graphene plasmons, as well as a strong plasmon reflection at gaps in the graphene layer, which appear at the steps between the SiC terraces. When the step height is around 1.5 nm, which is two orders of magnitude smaller than the plasmon wavelength, the reflection signal reaches 20% of its value at graphene edges, and it approaches 50% for step heights as small as 5 nm. This intriguing observation is corroborated by numerical simulations and explained by the accumulation of a line charge at the graphene termination. The associated electromagnetic fields at the graphene termination decay within a few nanometers, thus preventing efficient plasmon transmission across nanoscale gaps. Our work suggests that plasmon propagation in graphene-based circuits can be tailored using extremely compact nanostructures, such as ultranarrow gaps. It also demonstrates that tip-enhanced near-field microscopy is a powerful contactless tool to examine nanoscale defects in graphene.
Author Thongrattanasiri, Sukosin
Speck, Florian
Crassee, Iris
Hillenbrand, Rainer
Alonso-González, Pablo
Ostler, Markus
Nikitin, Alexey Yu
Koppens, Frank H. L
Slipchenko, Tetiana M
García de Abajo, F. Javier
Kuzmenko, Alexey B
Chen, Jianing
Martin-Moreno, Luis
Nesterov, Maxim L
Seyller, Thomas
AuthorAffiliation IKERBASQUE Basque Foundation for Science
ICREA-Institució Catalana de Recerca i Estudis Avançats
Institut für Physik - Technische Physik
Technische Universität Chemnitz
Department of Physics
ICFO-Institut de Ciéncies Fotoniques
Department Physik
Université de Geneve
Kasetsart University
Universität Erlangen-Nürnberg
CSIC-Universidad de Zaragoza
Instituto de Ciencia de Materiales de Aragón and Departamento de Física de la Materia Condensada
Département de Physique de la Matière Condensée
AuthorAffiliation_xml – name: Département de Physique de la Matière Condensée
– name: Institut für Physik - Technische Physik
– name: Technische Universität Chemnitz
– name: Department of Physics
– name: ICFO-Institut de Ciéncies Fotoniques
– name: CSIC-Universidad de Zaragoza
– name: IKERBASQUE Basque Foundation for Science
– name: Department Physik
– name: Universität Erlangen-Nürnberg
– name: Instituto de Ciencia de Materiales de Aragón and Departamento de Física de la Materia Condensada
– name: Kasetsart University
– name: ICREA-Institució Catalana de Recerca i Estudis Avançats
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Issue 12
Keywords plasmon reflection
SiC
Graphene
near-field microscopy
s-SNOM
graphene plasmons
Near infrared radiation
Nanometer scale
Silicon carbide
Epitaxial layers
Epitaxy
Digital simulation
Monolayers
Plasmons
Nanostructures
Language English
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  doi: 10.1038/nature11253
– volume: 103
  start-page: 246804
  year: 2009
  ident: ref15/cit15
  publication-title: Phys. Rev. Lett.
  doi: 10.1103/PhysRevLett.103.246804
SSID ssj0009350
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Snippet We employ tip-enhanced infrared near-field microscopy to study the plasmonic properties of epitaxial quasi-free-standing monolayer graphene on silicon carbide....
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SubjectTerms Carbon Compounds, Inorganic - chemistry
Collective excitations (including excitons, polarons, plasmons and other charge-density excitations)
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science; rheology
Electromagnetic Fields
Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures
Exact sciences and technology
Fullerenes and related materials; diamonds, graphite
Graphene
Graphite - chemistry
Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties
Materials science
Microscopy
Microscopy, Atomic Force
Monolayers
Nanostructure
Nanostructures - chemistry
Physics
Plasmons
Reflection
Silicon carbide
Silicon Compounds - chemistry
Specific materials
Surface and interface electron states
Surface Plasmon Resonance
Surface Properties
Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)
Title Strong Plasmon Reflection at Nanometer-Size Gaps in Monolayer Graphene on SiC
URI http://dx.doi.org/10.1021/nl403622t
https://www.ncbi.nlm.nih.gov/pubmed/24188400
https://www.proquest.com/docview/1467638279
https://www.proquest.com/docview/1753489676
Volume 13
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