A five-coordinate nickel(II) fluoroalkyl complex as a precursor to a spectroscopically detectable Ni(III) species

Mechanistic proposals for nickel-catalyzed coupling reactions often invoke five-coordinate alkyl- or aryl-bound Ni(II) and/or high-valent nickel(III) species, but because of their reactive nature, they have been difficult to study and fingerprint. In this work, we invoked the stabilizing properties...

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Vydané v:	Journal of the American Chemical Society Ročník 135; číslo 22; s. 8141
Hlavní autori:	Zhang, Cheng-Pan, Wang, Huan, Klein, Axel, Biewer, Christian, Stirnat, Kathrin, Yamaguchi, Yoshitaka, Xu, Long, Gomez-Benitez, Valente, Vicic, David A
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	United States 05.06.2013
ISSN:	1520-5126, 1520-5126
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