A five-coordinate nickel(II) fluoroalkyl complex as a precursor to a spectroscopically detectable Ni(III) species

Mechanistic proposals for nickel-catalyzed coupling reactions often invoke five-coordinate alkyl- or aryl-bound Ni(II) and/or high-valent nickel(III) species, but because of their reactive nature, they have been difficult to study and fingerprint. In this work, we invoked the stabilizing properties...

Full description

Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 135; no. 22; p. 8141
Main Authors:	Zhang, Cheng-Pan, Wang, Huan, Klein, Axel, Biewer, Christian, Stirnat, Kathrin, Yamaguchi, Yoshitaka, Xu, Long, Gomez-Benitez, Valente, Vicic, David A
Format:	Journal Article
Language:	English
Published:	United States 05.06.2013
ISSN:	1520-5126, 1520-5126
Online Access:	Get more information
Tags:	Add Tag No Tags, Be the first to tag this record!