Supracrystalline Colloidal Eggs: Epitaxial Growth and Freestanding Three-Dimensional Supracrystals in Nanoscaled Colloidosomes

The concept of template-confined chemical reactions allows the synthesis of complex molecules that would hardly be producible through conventional method. This idea was developed to produce high quality nanocrystals more than 20 years ago. However, template-mediated assembly of colloidal nanocrystal...

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Published in:Journal of the American Chemical Society Vol. 138; no. 10; p. 3493
Main Authors: Yang, Zhijie, Altantzis, Thomas, Zanaga, Daniele, Bals, Sara, Van Tendeloo, Gustaaf, Pileni, Marie-Paule
Format: Journal Article
Language:English
Published: United States 16.03.2016
ISSN:1520-5126, 1520-5126
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Abstract The concept of template-confined chemical reactions allows the synthesis of complex molecules that would hardly be producible through conventional method. This idea was developed to produce high quality nanocrystals more than 20 years ago. However, template-mediated assembly of colloidal nanocrystals is still at an elementary level, not only because of the limited templates suitable for colloidal assemblies, but also because of the poor control over the assembly of nanocrystals within a confined space. Here, we report the design of a new system called "supracrystalline colloidal eggs" formed by controlled assembly of nanocrystals into complex colloidal supracrystals through superlattice-matched epitaxial overgrowth along the existing colloidosomes. Then, with this concept, we extend the supracrystalline growth to lattice-mismatched binary nanocrystal superlattices, in order to reach anisotropic superlattice growths, yielding freestanding binary nanocrystal supracrystals that could not be produced previously.
AbstractList The concept of template-confined chemical reactions allows the synthesis of complex molecules that would hardly be producible through conventional method. This idea was developed to produce high quality nanocrystals more than 20 years ago. However, template-mediated assembly of colloidal nanocrystals is still at an elementary level, not only because of the limited templates suitable for colloidal assemblies, but also because of the poor control over the assembly of nanocrystals within a confined space. Here, we report the design of a new system called "supracrystalline colloidal eggs" formed by controlled assembly of nanocrystals into complex colloidal supracrystals through superlattice-matched epitaxial overgrowth along the existing colloidosomes. Then, with this concept, we extend the supracrystalline growth to lattice-mismatched binary nanocrystal superlattices, in order to reach anisotropic superlattice growths, yielding freestanding binary nanocrystal supracrystals that could not be produced previously.
The concept of template-confined chemical reactions allows the synthesis of complex molecules that would hardly be producible through conventional method. This idea was developed to produce high quality nanocrystals more than 20 years ago. However, template-mediated assembly of colloidal nanocrystals is still at an elementary level, not only because of the limited templates suitable for colloidal assemblies, but also because of the poor control over the assembly of nanocrystals within a confined space. Here, we report the design of a new system called "supracrystalline colloidal eggs" formed by controlled assembly of nanocrystals into complex colloidal supracrystals through superlattice-matched epitaxial overgrowth along the existing colloidosomes. Then, with this concept, we extend the supracrystalline growth to lattice-mismatched binary nanocrystal superlattices, in order to reach anisotropic superlattice growths, yielding freestanding binary nanocrystal supracrystals that could not be produced previously.The concept of template-confined chemical reactions allows the synthesis of complex molecules that would hardly be producible through conventional method. This idea was developed to produce high quality nanocrystals more than 20 years ago. However, template-mediated assembly of colloidal nanocrystals is still at an elementary level, not only because of the limited templates suitable for colloidal assemblies, but also because of the poor control over the assembly of nanocrystals within a confined space. Here, we report the design of a new system called "supracrystalline colloidal eggs" formed by controlled assembly of nanocrystals into complex colloidal supracrystals through superlattice-matched epitaxial overgrowth along the existing colloidosomes. Then, with this concept, we extend the supracrystalline growth to lattice-mismatched binary nanocrystal superlattices, in order to reach anisotropic superlattice growths, yielding freestanding binary nanocrystal supracrystals that could not be produced previously.
Author Altantzis, Thomas
Zanaga, Daniele
Pileni, Marie-Paule
Yang, Zhijie
Van Tendeloo, Gustaaf
Bals, Sara
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  givenname: Zhijie
  surname: Yang
  fullname: Yang, Zhijie
  organization: Université Paris Diderot , Sorbonne Paris Cité, ITODYS, UMR 7086 CNRS, 15 Rue J-A de Baïf, 75205, Cedex 13 Paris, France
– sequence: 2
  givenname: Thomas
  surname: Altantzis
  fullname: Altantzis, Thomas
  organization: Electron Microscopy for Materials Research (EMAT), University of Antwerp , Groenenborgerlaan 171, 2020 Antwerp, Belgium
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  givenname: Daniele
  surname: Zanaga
  fullname: Zanaga, Daniele
  organization: Electron Microscopy for Materials Research (EMAT), University of Antwerp , Groenenborgerlaan 171, 2020 Antwerp, Belgium
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  givenname: Sara
  surname: Bals
  fullname: Bals, Sara
  organization: Electron Microscopy for Materials Research (EMAT), University of Antwerp , Groenenborgerlaan 171, 2020 Antwerp, Belgium
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  givenname: Gustaaf
  surname: Van Tendeloo
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  organization: Electron Microscopy for Materials Research (EMAT), University of Antwerp , Groenenborgerlaan 171, 2020 Antwerp, Belgium
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  givenname: Marie-Paule
  surname: Pileni
  fullname: Pileni, Marie-Paule
  organization: CEA/IRAMIS , CEA Saclay F-91191 Gif-sur-Yvette, France
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Title Supracrystalline Colloidal Eggs: Epitaxial Growth and Freestanding Three-Dimensional Supracrystals in Nanoscaled Colloidosomes
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