Spin Isomers and Ligand Isomerization in a Three-Coordinate Cobalt(I) Carbonyl Complex

Hemilabile ligands, which have one donor that can reversibly bind to a metal, are widely used in transition-metal catalysts to create open coordination sites. This change in coordination at the metal can also cause spin-state changes. Here, we explore a cobalt(I) system that is poised on the brink o...

Full description

Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 137; no. 33; pp. 10689 - 10699
Main Authors:	Al-Afyouni, Malik H, Suturina, Elizaveta, Pathak, Shubhrodeep, Atanasov, Mihail, Bill, Eckhard, DeRosha, Daniel E, Brennessel, William W, Neese, Frank, Holland, Patrick L
Format:	Journal Article
Language:	English
Published:	United States 26.08.2015
ISSN:	1520-5126
Online Access:	Get more information
Tags:	Add Tag No Tags, Be the first to tag this record!