Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics
Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates...
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| Vydáno v: | Journal of the American Chemical Society Ročník 137; číslo 51; s. 16038 |
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| Hlavní autoři: | , , , , , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
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United States
30.12.2015
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| ISSN: | 1520-5126, 1520-5126 |
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| Abstract | Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis. |
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| AbstractList | Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis. Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis. |
| Author | Sessler, Jonathan L Chang, Jinho Leem, Soojung Park, Jung Su Kim, Dong Sub Thordarson, Pall |
| Author_xml | – sequence: 1 givenname: Dong Sub surname: Kim fullname: Kim, Dong Sub organization: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States – sequence: 2 givenname: Jinho surname: Chang fullname: Chang, Jinho organization: Department of Chemistry, Sungshin Women's University , 55 Dobong-ro, 76 ga-gil, Gangbuk-gu, Seoul 142-732, Republic of Korea – sequence: 3 givenname: Soojung surname: Leem fullname: Leem, Soojung organization: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States – sequence: 4 givenname: Jung Su surname: Park fullname: Park, Jung Su organization: Department of Chemistry, Sookmyung Women's University , Seoul 140-742, Korea – sequence: 5 givenname: Pall surname: Thordarson fullname: Thordarson, Pall organization: School of Chemistry, The University of New South Wales , Sydney, New South Wales 2052, Australia – sequence: 6 givenname: Jonathan L surname: Sessler fullname: Sessler, Jonathan L organization: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26605855$$D View this record in MEDLINE/PubMed |
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| Title | Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics |
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