Coaxial Spinning of All-Cellulose Systems for Enhanced Toughness: Filaments of Oxidized Nanofibrils Sheathed in Cellulose II Regenerated from a Protic Ionic Liquid
Hydrogels of TEMPO-oxidized nanocellulose were stabilized for dry-jet wet spinning using a shell of cellulose dissolved in 1,5-diazabicyclo[4.3.0]non-5-enium propionate ([DBNH][CO Et]), a protic ionic liquid (PIL). Coagulation in an acidic water bath resulted in continuous core-shell filaments (CSFs...
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| Veröffentlicht in: | Biomacromolecules Jg. 21; H. 2; S. 878 |
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| Sprache: | Englisch |
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10.02.2020
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| ISSN: | 1526-4602, 1526-4602 |
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| Abstract | Hydrogels of TEMPO-oxidized nanocellulose were stabilized for dry-jet wet spinning using a shell of cellulose dissolved in 1,5-diazabicyclo[4.3.0]non-5-enium propionate ([DBNH][CO
Et]), a protic ionic liquid (PIL). Coagulation in an acidic water bath resulted in continuous core-shell filaments (CSFs) that were tough and flexible with an average dry (and wet) toughness of ∼11 (2) MJ·m
and elongation of ∼9 (14) %. The CSF morphology, chemical composition, thermal stability, crystallinity, and bacterial activity were assessed using scanning electron microscopy with energy-dispersive X-ray spectroscopy, liquid-state nuclear magnetic resonance, Fourier transform infrared spectroscopy, thermogravimetric analysis, pyrolysis gas chromatography-mass spectrometry, wide-angle X-ray scattering, and bacterial cell culturing, respectively. The coaxial wet spinning yields PIL-free systems carrying on the surface the cellulose II polymorph, which not only enhances the toughness of the filaments but facilities their functionalization. |
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| AbstractList | Hydrogels of TEMPO-oxidized nanocellulose were stabilized for dry-jet wet spinning using a shell of cellulose dissolved in 1,5-diazabicyclo[4.3.0]non-5-enium propionate ([DBNH][CO2Et]), a protic ionic liquid (PIL). Coagulation in an acidic water bath resulted in continuous core-shell filaments (CSFs) that were tough and flexible with an average dry (and wet) toughness of ∼11 (2) MJ·m-3 and elongation of ∼9 (14) %. The CSF morphology, chemical composition, thermal stability, crystallinity, and bacterial activity were assessed using scanning electron microscopy with energy-dispersive X-ray spectroscopy, liquid-state nuclear magnetic resonance, Fourier transform infrared spectroscopy, thermogravimetric analysis, pyrolysis gas chromatography-mass spectrometry, wide-angle X-ray scattering, and bacterial cell culturing, respectively. The coaxial wet spinning yields PIL-free systems carrying on the surface the cellulose II polymorph, which not only enhances the toughness of the filaments but facilities their functionalization.Hydrogels of TEMPO-oxidized nanocellulose were stabilized for dry-jet wet spinning using a shell of cellulose dissolved in 1,5-diazabicyclo[4.3.0]non-5-enium propionate ([DBNH][CO2Et]), a protic ionic liquid (PIL). Coagulation in an acidic water bath resulted in continuous core-shell filaments (CSFs) that were tough and flexible with an average dry (and wet) toughness of ∼11 (2) MJ·m-3 and elongation of ∼9 (14) %. The CSF morphology, chemical composition, thermal stability, crystallinity, and bacterial activity were assessed using scanning electron microscopy with energy-dispersive X-ray spectroscopy, liquid-state nuclear magnetic resonance, Fourier transform infrared spectroscopy, thermogravimetric analysis, pyrolysis gas chromatography-mass spectrometry, wide-angle X-ray scattering, and bacterial cell culturing, respectively. The coaxial wet spinning yields PIL-free systems carrying on the surface the cellulose II polymorph, which not only enhances the toughness of the filaments but facilities their functionalization. Hydrogels of TEMPO-oxidized nanocellulose were stabilized for dry-jet wet spinning using a shell of cellulose dissolved in 1,5-diazabicyclo[4.3.0]non-5-enium propionate ([DBNH][CO Et]), a protic ionic liquid (PIL). Coagulation in an acidic water bath resulted in continuous core-shell filaments (CSFs) that were tough and flexible with an average dry (and wet) toughness of ∼11 (2) MJ·m and elongation of ∼9 (14) %. The CSF morphology, chemical composition, thermal stability, crystallinity, and bacterial activity were assessed using scanning electron microscopy with energy-dispersive X-ray spectroscopy, liquid-state nuclear magnetic resonance, Fourier transform infrared spectroscopy, thermogravimetric analysis, pyrolysis gas chromatography-mass spectrometry, wide-angle X-ray scattering, and bacterial cell culturing, respectively. The coaxial wet spinning yields PIL-free systems carrying on the surface the cellulose II polymorph, which not only enhances the toughness of the filaments but facilities their functionalization. |
| Author | Lundahl, Meri J Rojas, Orlando J Arteaga-Pérez, Luis E Oviedo, Claudia King, Alistair W T Reyes, Guillermo Alejandro-Martín, Serguei |
| Author_xml | – sequence: 1 givenname: Guillermo orcidid: 0000-0002-3468-1137 surname: Reyes fullname: Reyes, Guillermo organization: Departamento de Ingeniería en Maderas , Universidad del Bı́o-Bı́o , Av. Collao 1202, Casilla 5-C , Concepción , Chile – sequence: 2 givenname: Meri J orcidid: 0000-0003-0979-0486 surname: Lundahl fullname: Lundahl, Meri J organization: Biobased Colloids and Materials, Department of Bioproducts and Biosystems, School of Chemical Engineering , Aalto University , Espoo 02150 , Finland – sequence: 3 givenname: Serguei surname: Alejandro-Martín fullname: Alejandro-Martín, Serguei organization: Nanomaterials and Catalysts for Sustainable Processes (NanoCatpPS) , Universidad del Bı́o-Bı́o , Av. Collao 1202, Casilla 5-C , Concepción 4051381 , Chile – sequence: 4 givenname: Luis E surname: Arteaga-Pérez fullname: Arteaga-Pérez, Luis E organization: Nanomaterials and Catalysts for Sustainable Processes (NanoCatpPS) , Universidad del Bı́o-Bı́o , Av. Collao 1202, Casilla 5-C , Concepción 4051381 , Chile – sequence: 5 givenname: Claudia orcidid: 0000-0002-0846-8420 surname: Oviedo fullname: Oviedo, Claudia organization: Departamento de Química , Universidad del Bı́o-Bı́o , Av. Collao 1202, Casilla 5-C , Concepción 4051381 , Chile – sequence: 6 givenname: Alistair W T orcidid: 0000-0003-3142-9259 surname: King fullname: King, Alistair W T organization: Materials Chemistry Division, Department of Chemistry , University of Helsinki , Helsinki 00100 , Finland – sequence: 7 givenname: Orlando J orcidid: 0000-0003-4036-4020 surname: Rojas fullname: Rojas, Orlando J organization: Departments of Chemical & Biological Engineering, Chemistry and Wood Science , The University of British Columbia , 2360 East Mall , Vancouver BC V6T 1Z3 , Canada |
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| Snippet | Hydrogels of TEMPO-oxidized nanocellulose were stabilized for dry-jet wet spinning using a shell of cellulose dissolved in 1,5-diazabicyclo[4.3.0]non-5-enium... |
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| SubjectTerms | Cellulose - analysis Cellulose - chemical synthesis Gas Chromatography-Mass Spectrometry - methods Hydrogels - analysis Hydrogels - chemical synthesis Ionic Liquids - analysis Ionic Liquids - chemical synthesis Nanofibers - analysis Nanofibers - chemistry Tensile Strength |
| Title | Coaxial Spinning of All-Cellulose Systems for Enhanced Toughness: Filaments of Oxidized Nanofibrils Sheathed in Cellulose II Regenerated from a Protic Ionic Liquid |
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