Oxygen Reduction Catalyzed by a Fluorinated Tetraphenylporphyrin Free Base at Liquid/Liquid Interfaces

The diprotonated form of a fluorinated free base porphyrin, namely 5-(p-aminophenyl)-10,15,20-tris(pentafluorophenyl)porphyrin (H(2)FAP), can catalyze the reduction of oxygen by a weak electron donor, namely ferrocene (Fc). At a water/1,2-dichloroethane interface, the interfacial formation of H(4)FA...

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Bibliographic Details
Published in:	Journal of the American Chemical Society Vol. 132; no. 39; pp. 13733 - 13741
Main Authors:	Hatay, Imren, Su, Bin, Mendez, Manuel A., Corminboeuf, Clemence, Khoury, Tony, Gros, Claude P., Bourdillon, Melanie, Meyer, Michel, Barbe, Jean-Michel, Ersoz, Mustafa, Zalis, Stanislav, Samec, Zdenek, Girault, Hubert H.
Format:	Journal Article
Language:	English
Published:	WASHINGTON Amer Chemical Soc 06.10.2010
Subjects:	Catalysis Chemistry Chemistry, Multidisciplinary Ethylene Dichlorides - chemistry Ferrous Compounds - chemistry Metallocenes Models, Molecular Molecular Structure Oxidation-Reduction Oxygen - chemistry Physical Sciences Porphyrins - chemical synthesis Porphyrins - chemistry Science & Technology Stereoisomerism Water - chemistry MESO FERROCENE DERIVATIVES SYNTHETIC MODELS PLESSET PERTURBATION-THEORY IMMISCIBLE ELECTROLYTE-SOLUTIONS POLARIZED INTERFACE LOCAL TRIATOMICS BASIS-SETS MOLECULAR-OXYGEN WATER
ISSN:	0002-7863, 1520-5126, 1520-5126
Online Access:	Get more information
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