Tuning reactivity and mechanism in oxidation reactions by mononuclear nonheme iron(IV)-oxo complexes

Mononuclear nonheme iron enzymes generate high-valent iron(IV)-oxo intermediates that effect metabolically important oxidative transformations in the catalytic cycle of dioxygen activation. In 2003, researchers first spectroscopically characterized a mononuclear nonheme iron(IV)-oxo intermediate in...

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Vydané v:	Accounts of chemical research Ročník 47; číslo 4; s. 1146
Hlavní autori:	Nam, Wonwoo, Lee, Yong-Min, Fukuzumi, Shunichi
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	United States 15.04.2014
Predmet:	Biomimetics Electrons Heme Iron - chemistry Ligands Oxidation-Reduction Oxygen - chemistry Protons Water
ISSN:	1520-4898, 1520-4898
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