Synthesis, characterization, and multilayer assembly of pH sensitive graphene-polymer nanocomposites
pH sensitive graphene-polymer composites have been prepared by the modification of graphene basal planes with pyrene-terminated poly(2-N,N'-(dimethyl amino ethyl acrylate) (PDMAEA) and poly(acrylic acid) (PAA) via pi-pi stacking. The pyrene-terminal PDMAEA and PAA were synthesized using reversi...
Uložené v:
| Vydané v: | Langmuir Ročník 26; číslo 12; s. 10068 |
|---|---|
| Hlavní autori: | , , , , , , , |
| Médium: | Journal Article |
| Jazyk: | English |
| Vydavateľské údaje: |
United States
15.06.2010
|
| ISSN: | 1520-5827, 1520-5827 |
| On-line prístup: | Zistit podrobnosti o prístupe |
| Tagy: |
Pridať tag
Žiadne tagy, Buďte prvý, kto otaguje tento záznam!
|
| Shrnutí: | pH sensitive graphene-polymer composites have been prepared by the modification of graphene basal planes with pyrene-terminated poly(2-N,N'-(dimethyl amino ethyl acrylate) (PDMAEA) and poly(acrylic acid) (PAA) via pi-pi stacking. The pyrene-terminal PDMAEA and PAA were synthesized using reversible addition-fragmentation chain transfer (RAFT) polymerization with a pyrene-functional RAFT agent. The graphene-polymer composites were found to demonstrate phase transfer behavior between aqueous and organic media at different pH values. Atomic force microscopy (AFM) analysis revealed that the thicknesses of the graphene-polymer sheets were approximately 3.0 nm when prepared using PDMAEA (M(n): 6800 and PDI: 1.12). The surface coverage of polymer chains on the graphene basal plane was calculated to be 5.3 x 10(-11) mol cm(-2) for PDMAEA and 1.3 x 10(-10) mol cm(-2) for PAA. The graphene-polymer composites were successfully characterized using X-ray photoelectron spectroscopy (XPS), attenuated total reflection infrared (ATR-IR) spectroscopy, and thermogravimetric analysis (TGA). Self-assembly of the two oppositely charged graphene-polymer composites afforded layer-by-layer (LbL) structures as evidenced by high-resolution scanning electron microscopy (SEM) and quartz crystal microbalance (QCM) measurements. |
|---|---|
| Bibliografia: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 1520-5827 1520-5827 |
| DOI: | 10.1021/la1001978 |