A Robust Ethane-Trapping Metal-Organic Framework with a High Capacity for Ethylene Purification
The separation of ethane from ethylene is of prime importance in the purification of chemical feedstocks for industrial manufacturing. However, differentiating these compounds is notoriously difficult due to their similar physicochemical properties. High-performance porous adsorbents provide a solut...
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| Published in: | Journal of the American Chemical Society Vol. 141; no. 12; p. 5014 |
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| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
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United States
27.03.2019
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| ISSN: | 1520-5126, 1520-5126 |
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| Abstract | The separation of ethane from ethylene is of prime importance in the purification of chemical feedstocks for industrial manufacturing. However, differentiating these compounds is notoriously difficult due to their similar physicochemical properties. High-performance porous adsorbents provide a solution. Conventional adsorbents trap ethylene in preference to ethane, but this incurs multiple steps in separation processes. Alternatively, high-purity ethylene can be obtained in a single step if the adsorbent preferentially adsorbs ethane over ethylene. We herein report a metal-organic framework, MUF-15 (MUF, Massey University Framework), constructed from inexpensive precursors that sequesters ethane from ethane/ethylene mixtures. The productivity of this material is exceptional: 1 kg of MOF produces 14 L of polymer-grade ethylene gas in a single adsorption step starting from an equimolar ethane/ethylene mixture. Computational simulations illustrate the underlying mechanism of guest adsorption. The separation performance was assessed by measuring multicomponent breakthrough curves, which illustrate that the separation performance is maintained over a wide range of feed compositions and operating pressures. MUF-15 is robust, maintains its performance in the presence of acetylene, and is easily regenerated by purging with inert gas or by placing under reduced pressure. |
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| AbstractList | The separation of ethane from ethylene is of prime importance in the purification of chemical feedstocks for industrial manufacturing. However, differentiating these compounds is notoriously difficult due to their similar physicochemical properties. High-performance porous adsorbents provide a solution. Conventional adsorbents trap ethylene in preference to ethane, but this incurs multiple steps in separation processes. Alternatively, high-purity ethylene can be obtained in a single step if the adsorbent preferentially adsorbs ethane over ethylene. We herein report a metal-organic framework, MUF-15 (MUF, Massey University Framework), constructed from inexpensive precursors that sequesters ethane from ethane/ethylene mixtures. The productivity of this material is exceptional: 1 kg of MOF produces 14 L of polymer-grade ethylene gas in a single adsorption step starting from an equimolar ethane/ethylene mixture. Computational simulations illustrate the underlying mechanism of guest adsorption. The separation performance was assessed by measuring multicomponent breakthrough curves, which illustrate that the separation performance is maintained over a wide range of feed compositions and operating pressures. MUF-15 is robust, maintains its performance in the presence of acetylene, and is easily regenerated by purging with inert gas or by placing under reduced pressure. The separation of ethane from ethylene is of prime importance in the purification of chemical feedstocks for industrial manufacturing. However, differentiating these compounds is notoriously difficult due to their similar physicochemical properties. High-performance porous adsorbents provide a solution. Conventional adsorbents trap ethylene in preference to ethane, but this incurs multiple steps in separation processes. Alternatively, high-purity ethylene can be obtained in a single step if the adsorbent preferentially adsorbs ethane over ethylene. We herein report a metal-organic framework, MUF-15 (MUF, Massey University Framework), constructed from inexpensive precursors that sequesters ethane from ethane/ethylene mixtures. The productivity of this material is exceptional: 1 kg of MOF produces 14 L of polymer-grade ethylene gas in a single adsorption step starting from an equimolar ethane/ethylene mixture. Computational simulations illustrate the underlying mechanism of guest adsorption. The separation performance was assessed by measuring multicomponent breakthrough curves, which illustrate that the separation performance is maintained over a wide range of feed compositions and operating pressures. MUF-15 is robust, maintains its performance in the presence of acetylene, and is easily regenerated by purging with inert gas or by placing under reduced pressure.The separation of ethane from ethylene is of prime importance in the purification of chemical feedstocks for industrial manufacturing. However, differentiating these compounds is notoriously difficult due to their similar physicochemical properties. High-performance porous adsorbents provide a solution. Conventional adsorbents trap ethylene in preference to ethane, but this incurs multiple steps in separation processes. Alternatively, high-purity ethylene can be obtained in a single step if the adsorbent preferentially adsorbs ethane over ethylene. We herein report a metal-organic framework, MUF-15 (MUF, Massey University Framework), constructed from inexpensive precursors that sequesters ethane from ethane/ethylene mixtures. The productivity of this material is exceptional: 1 kg of MOF produces 14 L of polymer-grade ethylene gas in a single adsorption step starting from an equimolar ethane/ethylene mixture. Computational simulations illustrate the underlying mechanism of guest adsorption. The separation performance was assessed by measuring multicomponent breakthrough curves, which illustrate that the separation performance is maintained over a wide range of feed compositions and operating pressures. MUF-15 is robust, maintains its performance in the presence of acetylene, and is easily regenerated by purging with inert gas or by placing under reduced pressure. |
| Author | Qazvini, Omid T Shi, Zhao-Lin Babarao, Ravichandar Telfer, Shane G Zhang, Yue-Biao |
| Author_xml | – sequence: 1 givenname: Omid T surname: Qazvini fullname: Qazvini, Omid T organization: MacDiarmid Institute for Advanced Materials and Nanotechnology, Institute of Fundamental Sciences , Massey University , Palmerston North , New Zealand – sequence: 2 givenname: Ravichandar surname: Babarao fullname: Babarao, Ravichandar organization: Commonwealth Scientific and Industrial Research Organisation (CSIRO) Manufacturing , Clayton , Victoria 3169 , Australia – sequence: 3 givenname: Zhao-Lin surname: Shi fullname: Shi, Zhao-Lin organization: School of Physical Science and Technology , ShanghaiTech University , Shanghai 201210 , China – sequence: 4 givenname: Yue-Biao orcidid: 0000-0002-8270-1067 surname: Zhang fullname: Zhang, Yue-Biao organization: School of Physical Science and Technology , ShanghaiTech University , Shanghai 201210 , China – sequence: 5 givenname: Shane G orcidid: 0000-0003-1596-6652 surname: Telfer fullname: Telfer, Shane G organization: MacDiarmid Institute for Advanced Materials and Nanotechnology, Institute of Fundamental Sciences , Massey University , Palmerston North , New Zealand |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30860821$$D View this record in MEDLINE/PubMed |
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