Ligand-to-diimine/metal-to-diimine charge-transfer excited states of [Re(NCS)(CO)3(alpha-diimine)] (alpha-diimine = 2,2'-bipyridine, di-iPr-N,N-1,4-diazabutadiene). A spectroscopic and computational study

Two new complexes fac-[Re(NCS)(CO)3(N,N)] (N,N = 2,2'-bipyridine (bpy), di-iPr-N,N-1,4-diazabutadiene (iPr-DAB)) were synthesized and their molecular structures determined by X-ray diffraction. UV-vis absorption, resonance Raman, emission, and picosecond time-resolved IR spectra were measured e...

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Vydáno v:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Ročník 109; číslo 23; s. 5016
Hlavní autoři:	Blanco Rodríguez, Ana Maria, Gabrielsson, Anders, Motevalli, Majid, Matousek, Pavel, Towrie, Michael, Sebera, Jakub, Zális, Stanislav, Vlcek, Jr, Antonín
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	United States 16.06.2005
Témata:	2,2'-Dipyridyl - chemistry Computer Simulation Imines - chemistry Imines - radiation effects Ligands Light Models, Molecular Molecular Structure Organometallic Compounds - chemistry Organometallic Compounds - radiation effects Quantum Theory Rhenium - chemistry Spectrum Analysis Ultraviolet Rays X-Ray Diffraction
ISSN:	1089-5639
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