Strong Electronic and Magnetic Coupling in M4 (M = Ni, Cu) Clusters via Direct Orbital Interactions between Low-Coordinate Metal Centers

We present an extensive study of tetranuclear transition-metal cluster compounds M4(NPtBu3)4 and [M4(NPtBu3)4][B(C6F5)4] (M = Ni, Cu; tBu = tert-butyl), which feature low-coordinate metal centers and direct metal-metal orbital overlap. X-ray diffraction, electrochemical, magnetic, spectroscopic, and...

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Vydané v:	Journal of the American Chemical Society Ročník 142; číslo 45; s. 19161
Hlavní autori:	Chakarawet, Khetpakorn, Atanasov, Mihail, Marbey, Jonathan, Bunting, Philip C, Neese, Frank, Hill, Stephen, Long, Jeffrey R
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	11.11.2020
ISSN:	1520-5126, 1520-5126
On-line prístup:	Zistit podrobnosti o prístupe
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