Electronic properties of 4,4',5,5'-tetramethyl-2,2'-biphosphinine (tmbp) in the redox series fac-[Mn(Br)(CO)3(tmbp)], [Mn(CO)3(tmbp)]2, and [Mn(CO)3(tmbp)](-): crystallographic, spectroelectrochemical, and DFT computational study

Stepwise electrochemical reduction of the complex fac-[Mn(Br)(CO)(3)(tmbp)] (tmbp = 4,4',5,5'-tetramethyl-2,2'-biphosphinine) produces the dimer [Mn(CO)(3)(tmbp)](2) and the five-coordinate anion [Mn(CO)(3)(tmbp)](-). All three members of the redox series have been characterized by si...

Full description

Bibliographic Details

Published in:	Inorganic chemistry Vol. 42; no. 14; p. 4442
Main Authors:	Hartl, Frantisek, Mahabiersing, Taasje, Le Floch, Pascal, Mathey, Francois, Ricard, Louis, Rosa, Patrick, Zális, Stanislav
Format:	Journal Article
Language:	English
Published:	United States 14.07.2003
ISSN:	0020-1669
Online Access:	Get more information
Tags:	Add Tag No Tags, Be the first to tag this record!