Unraveling the mechanism of cascade reactions of zincke aldehydes

The thermal pericyclic cascade rearrangement of Zincke aldehydes (5-(dialkylamino)-2,4-pentadienals) to afford Z-α,β,γ,δ-unsaturated amides discovered by the Vanderwal group has been studied in depth using quantum mechanical methods. Two mechanistic possibilities that had previously been put forth t...

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Vydané v:	Journal of the American Chemical Society Ročník 133; číslo 11; s. 3895
Hlavní autori:	Paton, Robert S, Steinhardt, Sarah E, Vanderwal, Christopher D, Houk, K N
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	United States 23.03.2011
Predmet:	Aldehydes - chemistry Hydrogen Bonding Models, Molecular Oxidation-Reduction Quantum Theory
ISSN:	1520-5126, 1520-5126
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