In Situ Generated Bulky Palladium Hydride Complexes as Catalysts for the Efficient Isomerization of Olefins. Selective Transformation of Terminal Alkenes to 2-Alkenes

Application of an in situ generated bulky palladium(II) hydride catalyst obtained from a 1:1:1 mixture of Pd(dba)(2), P(tBu)(3), and isobutyryl chloride provides an efficient protocol for the isomerization and migration of a variety of olefins. In addition to the isomerization of (Z)- to (E)-olefins...

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Bibliographic Details
Published in:	Journal of the American Chemical Society Vol. 132; no. 23; pp. 7998 - 8009
Main Authors:	Gauthier, Delphine, Lindhardt, Anders T., Olsen, Esben P. K., Overgaard, Jacob, Skrydstrup, Troels
Format:	Journal Article
Language:	English
Published:	WASHINGTON Amer Chemical Soc 16.06.2010
Subjects:	Alkenes - chemistry Carbon - chemistry Catalysis Chemistry Chemistry, Multidisciplinary Palladium - chemistry Physical Sciences Science & Technology Stereoisomerism Thermodynamics ALLYLIC PROTECTING GROUPS GRUBBS METATHESIS CATALYST DOUBLE-BOND ISOMERIZATION ORGANIC-SYNTHESIS N-HETEROCYCLIC CARBENE TRANSITION-METAL-COMPLEXES TRI-TERT-BUTYLPHOSPHINE RUTHENIUM-CARBENE CARBONYL-COMPOUNDS ARYL CHLORIDES
ISSN:	0002-7863, 1520-5126, 1520-5126
Online Access:	Get more information
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