Air Stable, Photosensitive, Phase Pure Iron Pyrite Nanocrystal Thin Films for Photovoltaic Application

Iron pyrite (FeS2) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones; however existing iron pyrite photovoltaic devices contain thermodynamically unstable FeS2 film surfaces that lead to low open circuit voltages. We repor...

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Veröffentlicht in:	Nano letters Jg. 11; H. 11; S. 4953 - 4957
Hauptverfasser:	Bi, Yu, Yuan, Yongbo, Exstrom, Christopher L, Darveau, Scott A, Huang, Jinsong
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	Washington, DC American Chemical Society 09.11.2011
Schlagworte:	Air Applied sciences Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science; rheology Crystallization - methods Decomposition Devices Electric Conductivity Electronics Exact sciences and technology Iron Iron - chemistry Iron - radiation effects Light Materials Materials science Materials Testing Membranes, Artificial Molecular electronics, nanoelectronics Nanocrystalline materials Nanocrystals Nanoscale materials and structures: fabrication and characterization Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals Nanostructure Nanostructures - chemistry Nanostructures - radiation effects Open circuit voltage Photovoltaic cells Physics Pyrite Radiation Dosage Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices Solar cells Structure of solids and liquids; crystallography Sulfides - chemistry Sulfides - radiation effects Thin films photoconductive iron pyrite Nanocrystals photovoltaic Cubic lattices Iron Iron sulfide Photovoltaic cell Thin films Pyrite Silicon Carrier mobility Photoconductivity Sulfur Nanostructured materials TOPO Nanocrystal
ISSN:	1530-6984, 1530-6992, 1530-6992
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Abstract	Iron pyrite (FeS2) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones; however existing iron pyrite photovoltaic devices contain thermodynamically unstable FeS2 film surfaces that lead to low open circuit voltages. We report the rational synthesis of phase pure, highly crystalline cubic FeS2 nanocrystals (NCs) using a trioctylphosphine oxide (TOPO) assisted hot-injection method. The synthesized pyrite NC films have excellent air stability over one year. In contrast, obvious surface decomposition was observed on the surface of FeS2 NCs synthesized without TOPO. A high carrier mobility of 80 cm2/(V s) and a strong photoconductivity were observed for the first time for pyrite films at room temperature. Our results indicate that TOPO passivates both iron and sulfur atoms on FeS2 NC surfaces, efficiently inhibiting surface decomposition.
AbstractList	Iron pyrite (FeS(2)) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones; however existing iron pyrite photovoltaic devices contain thermodynamically unstable FeS(2) film surfaces that lead to low open circuit voltages. We report the rational synthesis of phase pure, highly crystalline cubic FeS(2) nanocrystals (NCs) using a trioctylphosphine oxide (TOPO) assisted hot-injection method. The synthesized pyrite NC films have excellent air stability over one year. In contrast, obvious surface decomposition was observed on the surface of FeS(2) NCs synthesized without TOPO. A high carrier mobility of 80 cm(2)/(V s) and a strong photoconductivity were observed for the first time for pyrite films at room temperature. Our results indicate that TOPO passivates both iron and sulfur atoms on FeS(2) NC surfaces, efficiently inhibiting surface decomposition.Iron pyrite (FeS(2)) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones; however existing iron pyrite photovoltaic devices contain thermodynamically unstable FeS(2) film surfaces that lead to low open circuit voltages. We report the rational synthesis of phase pure, highly crystalline cubic FeS(2) nanocrystals (NCs) using a trioctylphosphine oxide (TOPO) assisted hot-injection method. The synthesized pyrite NC films have excellent air stability over one year. In contrast, obvious surface decomposition was observed on the surface of FeS(2) NCs synthesized without TOPO. A high carrier mobility of 80 cm(2)/(V s) and a strong photoconductivity were observed for the first time for pyrite films at room temperature. Our results indicate that TOPO passivates both iron and sulfur atoms on FeS(2) NC surfaces, efficiently inhibiting surface decomposition. Iron pyrite (FeS sub(2)) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones; however existing iron pyrite photovoltaic devices contain thermodynamically unstable FeS sub(2) film surfaces that lead to low open circuit voltages. We report the rational synthesis of phase pure, highly crystalline cubic FeS sub(2) nanocrystals (NCs) using a trioctylphosphine oxide (TOPO) assisted hot-injection method. The synthesized pyrite NC films have excellent air stability over one year. In contrast, obvious surface decomposition was observed on the surface of FeS sub(2) NCs synthesized without TOPO. A high carrier mobility of 80 cm super(2)/(V s) and a strong photoconductivity were observed for the first time for pyrite films at room temperature. Our results indicate that TOPO passivates both iron and sulfur atoms on FeS sub(2) NC surfaces, efficiently inhibiting surface decomposition. Iron pyrite (FeS2) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones; however existing iron pyrite photovoltaic devices contain thermodynamically unstable FeS2 film surfaces that lead to low open circuit voltages. We report the rational synthesis of phase pure, highly crystalline cubic FeS2 nanocrystals (NCs) using a trioctylphosphine oxide (TOPO) assisted hot-injection method. The synthesized pyrite NC films have excellent air stability over one year. In contrast, obvious surface decomposition was observed on the surface of FeS2 NCs synthesized without TOPO. A high carrier mobility of 80 cm2/(V s) and a strong photoconductivity were observed for the first time for pyrite films at room temperature. Our results indicate that TOPO passivates both iron and sulfur atoms on FeS2 NC surfaces, efficiently inhibiting surface decomposition. Iron pyrite (FeS(2)) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones; however existing iron pyrite photovoltaic devices contain thermodynamically unstable FeS(2) film surfaces that lead to low open circuit voltages. We report the rational synthesis of phase pure, highly crystalline cubic FeS(2) nanocrystals (NCs) using a trioctylphosphine oxide (TOPO) assisted hot-injection method. The synthesized pyrite NC films have excellent air stability over one year. In contrast, obvious surface decomposition was observed on the surface of FeS(2) NCs synthesized without TOPO. A high carrier mobility of 80 cm(2)/(V s) and a strong photoconductivity were observed for the first time for pyrite films at room temperature. Our results indicate that TOPO passivates both iron and sulfur atoms on FeS(2) NC surfaces, efficiently inhibiting surface decomposition.
Author	Huang, Jinsong Bi, Yu Yuan, Yongbo Darveau, Scott A Exstrom, Christopher L
AuthorAffiliation	University of Nebraska at Kearney Chinese Academy of Sciences University of NebraskaLincoln
AuthorAffiliation_xml	– name: Chinese Academy of Sciences – name: University of NebraskaLincoln – name: University of Nebraska at Kearney
Author_xml	– sequence: 1 givenname: Yu surname: Bi fullname: Bi, Yu – sequence: 2 givenname: Yongbo surname: Yuan fullname: Yuan, Yongbo – sequence: 3 givenname: Christopher L surname: Exstrom fullname: Exstrom, Christopher L – sequence: 4 givenname: Scott A surname: Darveau fullname: Darveau, Scott A – sequence: 5 givenname: Jinsong surname: Huang fullname: Huang, Jinsong email: jhuang2@unl.edu
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Keywords	photoconductive iron pyrite Nanocrystals photovoltaic Cubic lattices Iron Iron sulfide Photovoltaic cell Thin films Pyrite Silicon Carrier mobility Photoconductivity Sulfur Nanostructured materials TOPO Nanocrystal
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Snippet	Iron pyrite (FeS2) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones; however... Iron pyrite (FeS(2)) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones; however... Iron pyrite (FeS sub(2)) is a naturally abundant and nontoxic photovoltaic material that can potentially make devices as efficient as silicon-based ones;...
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SubjectTerms	Air Applied sciences Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science; rheology Crystallization - methods Decomposition Devices Electric Conductivity Electronics Exact sciences and technology Iron Iron - chemistry Iron - radiation effects Light Materials Materials science Materials Testing Membranes, Artificial Molecular electronics, nanoelectronics Nanocrystalline materials Nanocrystals Nanoscale materials and structures: fabrication and characterization Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals Nanostructure Nanostructures - chemistry Nanostructures - radiation effects Open circuit voltage Photovoltaic cells Physics Pyrite Radiation Dosage Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices Solar cells Structure of solids and liquids; crystallography Sulfides - chemistry Sulfides - radiation effects Thin films
Title	Air Stable, Photosensitive, Phase Pure Iron Pyrite Nanocrystal Thin Films for Photovoltaic Application
URI	http://dx.doi.org/10.1021/nl202902z https://www.ncbi.nlm.nih.gov/pubmed/21992489 https://www.proquest.com/docview/1762053024 https://www.proquest.com/docview/903144190
Volume	11
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