Plasmon-Mediated Oxidase-like Activity on Ag@ZnS Heterostructured Hollow Nanowires for Rapid Visual Detection of Nitrite
Rational design of fast and sensitive determination of nitrite (NO ) from a complicated actual sample overtakes a crucial role in constructing a high-efficiency sensing platform. Herein, a visual NO sensing platform with outstanding selectivity, sensitivity, and stability based on a surface plasmon...
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| Published in: | Inorganic chemistry Vol. 62; no. 4; p. 1659 |
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| Main Authors: | , , , , , , , , |
| Format: | Journal Article |
| Language: | English |
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United States
30.01.2023
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| ISSN: | 1520-510X, 1520-510X |
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| Abstract | Rational design of fast and sensitive determination of nitrite (NO
) from a complicated actual sample overtakes a crucial role in constructing a high-efficiency sensing platform. Herein, a visual NO
sensing platform with outstanding selectivity, sensitivity, and stability based on a surface plasmon resonance (SPR)-enhanced oxidase-like activity has been proposed. Benefiting from the intrinsic photocatalytic activity and limited light penetration of ZnS, the oxidase-like activity based on ZnS decorated on Ag nanowires (Ag@ZnS) is determined. It is demonstrated that the electrons are generated efficiently on the surface of ZnS and then transferred into the hot electrons of Ag with the help of localized SPR excitation, thus greatly oxidating the colorless 3,3',5,5'-tetramethylbenzidine (TMB) to produce dark blue oxidized TMB (oxTMB). When nitrite is added into the reaction system, the oxTMB will selectively react with NO
to generate diazotized oxTMB, leading to a visual color change from dark blue to light green and subsequently to dark yellow. Owing to the specific recognition between nitrite and oxTMB, the recovery of catalytic activity induced an enhanced colorimetric test with a wider linear range for NO
determination, an ultralow detection limit of 0.1 μM, excellent selectivity, and practicability for application in real samples. This plasmon-enhanced oxidase-like activity not only provides a smart approach to realize a colorimetric assay with high sensitivity and simplicity but also modulates oxidase-like activities. |
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| AbstractList | Rational design of fast and sensitive determination of nitrite (NO
) from a complicated actual sample overtakes a crucial role in constructing a high-efficiency sensing platform. Herein, a visual NO
sensing platform with outstanding selectivity, sensitivity, and stability based on a surface plasmon resonance (SPR)-enhanced oxidase-like activity has been proposed. Benefiting from the intrinsic photocatalytic activity and limited light penetration of ZnS, the oxidase-like activity based on ZnS decorated on Ag nanowires (Ag@ZnS) is determined. It is demonstrated that the electrons are generated efficiently on the surface of ZnS and then transferred into the hot electrons of Ag with the help of localized SPR excitation, thus greatly oxidating the colorless 3,3',5,5'-tetramethylbenzidine (TMB) to produce dark blue oxidized TMB (oxTMB). When nitrite is added into the reaction system, the oxTMB will selectively react with NO
to generate diazotized oxTMB, leading to a visual color change from dark blue to light green and subsequently to dark yellow. Owing to the specific recognition between nitrite and oxTMB, the recovery of catalytic activity induced an enhanced colorimetric test with a wider linear range for NO
determination, an ultralow detection limit of 0.1 μM, excellent selectivity, and practicability for application in real samples. This plasmon-enhanced oxidase-like activity not only provides a smart approach to realize a colorimetric assay with high sensitivity and simplicity but also modulates oxidase-like activities. Rational design of fast and sensitive determination of nitrite (NO2-) from a complicated actual sample overtakes a crucial role in constructing a high-efficiency sensing platform. Herein, a visual NO2- sensing platform with outstanding selectivity, sensitivity, and stability based on a surface plasmon resonance (SPR)-enhanced oxidase-like activity has been proposed. Benefiting from the intrinsic photocatalytic activity and limited light penetration of ZnS, the oxidase-like activity based on ZnS decorated on Ag nanowires (Ag@ZnS) is determined. It is demonstrated that the electrons are generated efficiently on the surface of ZnS and then transferred into the hot electrons of Ag with the help of localized SPR excitation, thus greatly oxidating the colorless 3,3',5,5'-tetramethylbenzidine (TMB) to produce dark blue oxidized TMB (oxTMB). When nitrite is added into the reaction system, the oxTMB will selectively react with NO2- to generate diazotized oxTMB, leading to a visual color change from dark blue to light green and subsequently to dark yellow. Owing to the specific recognition between nitrite and oxTMB, the recovery of catalytic activity induced an enhanced colorimetric test with a wider linear range for NO2- determination, an ultralow detection limit of 0.1 μM, excellent selectivity, and practicability for application in real samples. This plasmon-enhanced oxidase-like activity not only provides a smart approach to realize a colorimetric assay with high sensitivity and simplicity but also modulates oxidase-like activities.Rational design of fast and sensitive determination of nitrite (NO2-) from a complicated actual sample overtakes a crucial role in constructing a high-efficiency sensing platform. Herein, a visual NO2- sensing platform with outstanding selectivity, sensitivity, and stability based on a surface plasmon resonance (SPR)-enhanced oxidase-like activity has been proposed. Benefiting from the intrinsic photocatalytic activity and limited light penetration of ZnS, the oxidase-like activity based on ZnS decorated on Ag nanowires (Ag@ZnS) is determined. It is demonstrated that the electrons are generated efficiently on the surface of ZnS and then transferred into the hot electrons of Ag with the help of localized SPR excitation, thus greatly oxidating the colorless 3,3',5,5'-tetramethylbenzidine (TMB) to produce dark blue oxidized TMB (oxTMB). When nitrite is added into the reaction system, the oxTMB will selectively react with NO2- to generate diazotized oxTMB, leading to a visual color change from dark blue to light green and subsequently to dark yellow. Owing to the specific recognition between nitrite and oxTMB, the recovery of catalytic activity induced an enhanced colorimetric test with a wider linear range for NO2- determination, an ultralow detection limit of 0.1 μM, excellent selectivity, and practicability for application in real samples. This plasmon-enhanced oxidase-like activity not only provides a smart approach to realize a colorimetric assay with high sensitivity and simplicity but also modulates oxidase-like activities. |
| Author | Huang, Zijun Yang, Huimin Lu, Xinhua Huang, Tianzi Cheng, Wenjing Tian, Lin Li, Tongxiang Li, Zhao Wang, Tingjian |
| Author_xml | – sequence: 1 givenname: Lin orcidid: 0000-0002-4345-5414 surname: Tian fullname: Tian, Lin organization: School of Chemistry and Environmental Science, Yili Normal University, Yili 835000, China – sequence: 2 givenname: Zijun surname: Huang fullname: Huang, Zijun organization: School of Materials and Chemical Engineering, Xuzhou University of Technology, Xuzhou 221018, PR China – sequence: 3 givenname: Xinhua surname: Lu fullname: Lu, Xinhua organization: School of Materials and Chemical Engineering, Xuzhou University of Technology, Xuzhou 221018, PR China – sequence: 4 givenname: Tingjian surname: Wang fullname: Wang, Tingjian organization: School of Materials and Chemical Engineering, Xuzhou University of Technology, Xuzhou 221018, PR China – sequence: 5 givenname: Wenjing surname: Cheng fullname: Cheng, Wenjing organization: School of Chemistry and Environmental Science, Yili Normal University, Yili 835000, China – sequence: 6 givenname: Huimin surname: Yang fullname: Yang, Huimin organization: School of Chemistry and Environmental Science, Yili Normal University, Yili 835000, China – sequence: 7 givenname: Tianzi surname: Huang fullname: Huang, Tianzi organization: Engineering Research Center for Food Biotransformation and Safety Testing, Xuzhou University of Technology, Xuzhou 221018, PR China – sequence: 8 givenname: Tongxiang surname: Li fullname: Li, Tongxiang organization: Engineering Research Center for Food Biotransformation and Safety Testing, Xuzhou University of Technology, Xuzhou 221018, PR China – sequence: 9 givenname: Zhao surname: Li fullname: Li, Zhao organization: School of Materials and Chemical Engineering, Xuzhou University of Technology, Xuzhou 221018, PR China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/36649641$$D View this record in MEDLINE/PubMed |
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| Snippet | Rational design of fast and sensitive determination of nitrite (NO
) from a complicated actual sample overtakes a crucial role in constructing a... Rational design of fast and sensitive determination of nitrite (NO2-) from a complicated actual sample overtakes a crucial role in constructing a... |
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| SubjectTerms | Colorimetry Limit of Detection Nanowires Nitrites Nitrogen Dioxide Oxidoreductases |
| Title | Plasmon-Mediated Oxidase-like Activity on Ag@ZnS Heterostructured Hollow Nanowires for Rapid Visual Detection of Nitrite |
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