Ruthenium Stilbenyl and Diruthenium Distyrylethene Complexes: Aspects of Electron Delocalization and Electrocatalyzed Isomerization of the Z-Isomer

Regio- and stereoselective insertion of the terminal ethynyl functions of 4-ethynylstilbene, the E and Z isomers of 4,4'-bis(ethynylphenyl)ethene and a backbone-rigidified cyclohexenyl derivative of the Z. isomer into the Ru-H bond of the complex RuClH(CO)((PPr3)-Pr-i)(2) provides the correspon...

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Vydané v:	Journal of the American Chemical Society Ročník 134; číslo 40; s. 16671 - 16692
Hlavní autori:	Linseis, Michael, Zalis, Stanislav, Zabel, Manfred, Winter, Rainer F.
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	WASHINGTON Amer Chemical Soc 10.10.2012
Predmet:	Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology VIBRATIONAL TIME-SCALE CRYSTAL-STRUCTURE MIXED-VALENCE STATE AB-INITIO RADICAL CATIONS ABSORPTION-SPECTRA CYCLIC VOLTAMMETRY CHARGE-TRANSFER RESONANCE RAMAN CIS-TRANS-ISOMERIZATION
ISSN:	0002-7863, 1520-5126, 1520-5126
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