Ultrafast photochemical dissociation of an equatorial CO ligand from trans(X,X)-[Ru(X)2(CO)2(bpy)] (X = Cl, Br, I): a picosecond time-resolved infrared spectroscopic and DFT computational study

Ultrafast photochemistry of the complexes trans(X,X)-[Ru(X)(2)(CO)(2)(bpy)] (X = Cl, Br, I) was studied in order to understand excited-state reactivity of equatorial CO ligands, coordinated trans to the 2,2'-bipyridine ligand (bpy). TD-DFT calculations have identified the lowest electronic tran...

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Bibliographic Details

Published in:	Inorganic chemistry Vol. 43; no. 23; p. 7380
Main Authors:	Gabrielsson, Anders, Zális, Stanislav, Matousek, Pavel, Towrie, Mike, Vlcek, Jr, Antonín
Format:	Journal Article
Language:	English
Published:	United States 15.11.2004
ISSN:	0020-1669
Online Access:	Get more information
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