Gold Nanocages: Bioconjugation and Their Potential Use as Optical Imaging Contrast Agents

Gold nanocages of <40 nm in dimension have been synthesized using the galvanic replacement reaction between Ag nanocubes and HAuCl4 in an aqueous solution. By controlling the molar ratio between Ag and HAuCl4, the gold nanocages could be tuned to display surface plasmon resonance peaks around 800...

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Vydáno v:	Nano letters Ročník 5; číslo 3; s. 473 - 477
Hlavní autoři:	Chen, Jingyi, Saeki, Fusayo, Wiley, Benjamin J., Cang, Hu, Cobb, Michael J., Li, Zhi-Yuan, Au, Leslie, Zhang, Hui, Kimmey, Michael B., Li, Xingde, Xia, Younan
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	Washington, DC American Chemical Society 01.03.2005
Témata:	Cell Line, Tumor Chemical synthesis methods Contrast Media Cross-disciplinary physics: materials science; rheology Crystallization - methods Exact sciences and technology Gold - chemistry Humans Immunoassay - methods Materials science Materials Testing Methods of nanofabrication Nanostructures - chemistry Nanostructures - ultrastructure Neoplasms - pathology Particle Size Phantoms, Imaging Physics Surface Plasmon Resonance - methods Tomography, Optical Coherence - methods Scanning electron microscopy Gold Inorganic compounds Cage Nanocage Experimental study Transmission electron microscopy Near infrared spectrum Transition elements Tomography Ultraviolet visible spectrum Surface plasmon resonance Nanostructured materials
ISSN:	1530-6984, 1530-6992
On-line přístup:	Získat plný text
Tagy:	Přidat tag Žádné tagy, Buďte první, kdo vytvoří štítek k tomuto záznamu!

Abstract	Gold nanocages of <40 nm in dimension have been synthesized using the galvanic replacement reaction between Ag nanocubes and HAuCl4 in an aqueous solution. By controlling the molar ratio between Ag and HAuCl4, the gold nanocages could be tuned to display surface plasmon resonance peaks around 800 nm, a wavelength commonly used in optical coherence tomography (OCT) imaging. OCT measurements on phantom samples indicate that these gold nanocages have a moderate scattering cross-section of ∼8.10 × 10-16 m2 but a very large absorption cross-section of ∼7.26 × 10-15 m2, suggesting their potential use as a new class of contrast agents for optical imaging. When bioconjugated with antibodies, the gold nanocages have also been demonstrated for specific targeting of breast cancer cells.
AbstractList	Gold nanocages of <40 nm in dimension have been synthesized using the galvanic replacement reaction between Ag nanocubes and HAuCl4 in an aqueous solution. By controlling the molar ratio between Ag and HAuCl4, the gold nanocages could be tuned to display surface plasmon resonance peaks around 800 nm, a wavelength commonly used in optical coherence tomography (OCT) imaging. OCT measurements on phantom samples indicate that these gold nanocages have a moderate scattering cross-section of approximately 8.10 x 10(-16) m2 but a very large absorption cross-section of approximately 7.26 x 10(-15) m2, suggesting their potential use as a new class of contrast agents for optical imaging. When bioconjugated with antibodies, the gold nanocages have also been demonstrated for specific targeting of breast cancer cells. Gold nanocages of <40 nm in dimension have been synthesized using the galvanic replacement reaction between Ag nanocubes and HAuCl4 in an aqueous solution. By controlling the molar ratio between Ag and HAuCl4, the gold nanocages could be tuned to display surface plasmon resonance peaks around 800 nm, a wavelength commonly used in optical coherence tomography (OCT) imaging. OCT measurements on phantom samples indicate that these gold nanocages have a moderate scattering cross-section of approximately 8.10 x 10(-16) m2 but a very large absorption cross-section of approximately 7.26 x 10(-15) m2, suggesting their potential use as a new class of contrast agents for optical imaging. When bioconjugated with antibodies, the gold nanocages have also been demonstrated for specific targeting of breast cancer cells.Gold nanocages of <40 nm in dimension have been synthesized using the galvanic replacement reaction between Ag nanocubes and HAuCl4 in an aqueous solution. By controlling the molar ratio between Ag and HAuCl4, the gold nanocages could be tuned to display surface plasmon resonance peaks around 800 nm, a wavelength commonly used in optical coherence tomography (OCT) imaging. OCT measurements on phantom samples indicate that these gold nanocages have a moderate scattering cross-section of approximately 8.10 x 10(-16) m2 but a very large absorption cross-section of approximately 7.26 x 10(-15) m2, suggesting their potential use as a new class of contrast agents for optical imaging. When bioconjugated with antibodies, the gold nanocages have also been demonstrated for specific targeting of breast cancer cells. Gold nanocages of <40 nm in dimension have been synthesized using the galvanic replacement reaction between Ag nanocubes and HAuCl4 in an aqueous solution. By controlling the molar ratio between Ag and HAuCl4, the gold nanocages could be tuned to display surface plasmon resonance peaks around 800 nm, a wavelength commonly used in optical coherence tomography (OCT) imaging. OCT measurements on phantom samples indicate that these gold nanocages have a moderate scattering cross-section of ∼8.10 × 10-16 m2 but a very large absorption cross-section of ∼7.26 × 10-15 m2, suggesting their potential use as a new class of contrast agents for optical imaging. When bioconjugated with antibodies, the gold nanocages have also been demonstrated for specific targeting of breast cancer cells.
Author	Saeki, Fusayo Wiley, Benjamin J. Zhang, Hui Kimmey, Michael B. Li, Xingde Li, Zhi-Yuan Cobb, Michael J. Cang, Hu Xia, Younan Au, Leslie Chen, Jingyi
Author_xml	– sequence: 1 givenname: Jingyi surname: Chen fullname: Chen, Jingyi – sequence: 2 givenname: Fusayo surname: Saeki fullname: Saeki, Fusayo – sequence: 3 givenname: Benjamin J. surname: Wiley fullname: Wiley, Benjamin J. – sequence: 4 givenname: Hu surname: Cang fullname: Cang, Hu – sequence: 5 givenname: Michael J. surname: Cobb fullname: Cobb, Michael J. – sequence: 6 givenname: Zhi-Yuan surname: Li fullname: Li, Zhi-Yuan – sequence: 7 givenname: Leslie surname: Au fullname: Au, Leslie – sequence: 8 givenname: Hui surname: Zhang fullname: Zhang, Hui – sequence: 9 givenname: Michael B. surname: Kimmey fullname: Kimmey, Michael B. – sequence: 10 givenname: Xingde surname: Li fullname: Li, Xingde – sequence: 11 givenname: Younan surname: Xia fullname: Xia, Younan
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Keywords	Scanning electron microscopy Gold Inorganic compounds Cage Nanocage Experimental study Transmission electron microscopy Near infrared spectrum Transition elements Tomography Ultraviolet visible spectrum Surface plasmon resonance Nanostructured materials
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Snippet	Gold nanocages of <40 nm in dimension have been synthesized using the galvanic replacement reaction between Ag nanocubes and HAuCl4 in an aqueous solution. By...
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SubjectTerms	Cell Line, Tumor Chemical synthesis methods Contrast Media Cross-disciplinary physics: materials science; rheology Crystallization - methods Exact sciences and technology Gold - chemistry Humans Immunoassay - methods Materials science Materials Testing Methods of nanofabrication Nanostructures - chemistry Nanostructures - ultrastructure Neoplasms - pathology Particle Size Phantoms, Imaging Physics Surface Plasmon Resonance - methods Tomography, Optical Coherence - methods
Title	Gold Nanocages: Bioconjugation and Their Potential Use as Optical Imaging Contrast Agents
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