Orange Light-Driven C(sp2)-C(sp3) Cross-Coupling via Spin-Forbidden Ir(III) Metallaphotoredox Catalysis

We report the development and characterization of a library of Ir(III) photocatalysts capable of undergoing spin-forbidden excitation (SFE) under orange light irradiation (595 nm). These catalysts were successfully applied to the construction of synthetically valuable C(sp(2))-C(sp(3)) bonds inacces...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 145; no. 36; pp. 19925 - 19931
Main Authors:	Xie, Katherine A., Bednarova, Eva, Joe, Candice L., Lin, Chenxi, Sherwood, Trevor C., Simmons, Eric M., Lainhart, Brendan C., Rovis, Tomislav
Format:	Journal Article
Language:	English
Published:	WASHINGTON Amer Chemical Soc 13.09.2023
Subjects:	Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology RED INFRARED LIGHT IRIDIUM(III) COMPLEXES GENERATION RADICALS PHOTOPHYSICAL PROPERTIES PHOTOREDOX CATALYSIS
ISSN:	0002-7863, 1520-5126, 1520-5126
Online Access:	Get more information
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