Ultrafast Carrier-Coupled Interlayer Contraction, Coherent Intralayer Motions, and Phonon Thermalization Dynamics of Black Phosphorus

Black phosphorus (bP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted, symmetric intralayer vibrations occur concurrently within few...

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Vydané v:Nano letters Ročník 22; číslo 13; s. 5230 - 5235
Hlavní autori: Chebl, Mazhar, He, Xing, Yang, Ding-Shyue
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: American Chemical Society 13.07.2022
Predmet:
structure−property relations
electron−phonon coupling
transition metal dichalcogenides
ultrafast nonequilibrium structural dynamics
2D materials
ISSN:1530-6984, 1530-6992, 1530-6992
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Abstract Black phosphorus (bP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted, symmetric intralayer vibrations occur concurrently within few picoseconds following the photoinjection and relaxation of carriers, using ultrafast electron diffraction in the reflection geometry to probe the out-of-plane motions. A strong coupling between the photocarriers and bP’s puckered structure, with the alignment of the electronic band structure, is at work for such directional atomic motions without a photoinduced phase transition. Three temporal regimes can be identified for the phonon thermalization dynamics where a quasi-equilibrium without anisotropy is reached in about 50 ps, followed by propagation of coherent acoustic phonons and heat diffusion into the bulk. The early time out-of-plane dynamics reported here have important implications for single- and few-layer bP and other vdW materials with strong electronic–lattice correlations.
AbstractList Black phosphorus (bP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted, symmetric intralayer vibrations occur concurrently within few picoseconds following the photoinjection and relaxation of carriers, using ultrafast electron diffraction in the reflection geometry to probe the out-of-plane motions. A strong coupling between the photocarriers and bP’s puckered structure, with the alignment of the electronic band structure, is at work for such directional atomic motions without a photoinduced phase transition. Three temporal regimes can be identified for the phonon thermalization dynamics where a quasi-equilibrium without anisotropy is reached in about 50 ps, followed by propagation of coherent acoustic phonons and heat diffusion into the bulk. The early time out-of-plane dynamics reported here have important implications for single- and few-layer bP and other vdW materials with strong electronic–lattice correlations.
Black phosphorus (bP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted, symmetric intralayer vibrations occur concurrently within few picoseconds following the photoinjection and relaxation of carriers, using ultrafast electron diffraction in the reflection geometry to probe the out-of-plane motions. A strong coupling between the photocarriers and bP's puckered structure, with the alignment of the electronic band structure, is at work for such directional atomic motions without a photoinduced phase transition. Three temporal regimes can be identified for the phonon thermalization dynamics where a quasi-equilibrium without anisotropy is reached in about 50 ps, followed by propagation of coherent acoustic phonons and heat diffusion into the bulk. The early time out-of-plane dynamics reported here have important implications for single- and few-layer bP and other vdW materials with strong electronic-lattice correlations.Black phosphorus (bP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted, symmetric intralayer vibrations occur concurrently within few picoseconds following the photoinjection and relaxation of carriers, using ultrafast electron diffraction in the reflection geometry to probe the out-of-plane motions. A strong coupling between the photocarriers and bP's puckered structure, with the alignment of the electronic band structure, is at work for such directional atomic motions without a photoinduced phase transition. Three temporal regimes can be identified for the phonon thermalization dynamics where a quasi-equilibrium without anisotropy is reached in about 50 ps, followed by propagation of coherent acoustic phonons and heat diffusion into the bulk. The early time out-of-plane dynamics reported here have important implications for single- and few-layer bP and other vdW materials with strong electronic-lattice correlations.
Author He, Xing
Yang, Ding-Shyue
Chebl, Mazhar
AuthorAffiliation Department of Chemistry
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  fullname: Yang, Ding-Shyue
  email: yang@uh.edu
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electron−phonon coupling
transition metal dichalcogenides
ultrafast nonequilibrium structural dynamics
2D materials
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Title Ultrafast Carrier-Coupled Interlayer Contraction, Coherent Intralayer Motions, and Phonon Thermalization Dynamics of Black Phosphorus
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