Investigating the Photocatalytic Degradation of Oil Paint using ATR-IR and AFM-IR
As linseed oil has a longstanding and continuing history of use as a binder in artistic paints, developing an understanding of its degradation mechanism is critical to conservation efforts. At present, little can be done to detect the early stages of oil paint deterioration due to the complex chemic...
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| Published in: | ACS applied materials & interfaces Vol. 9; no. 11; p. 10169 |
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| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
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United States
22.03.2017
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| Subjects: | |
| ISSN: | 1944-8252, 1944-8252 |
| Online Access: | Get more information |
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| Abstract | As linseed oil has a longstanding and continuing history of use as a binder in artistic paints, developing an understanding of its degradation mechanism is critical to conservation efforts. At present, little can be done to detect the early stages of oil paint deterioration due to the complex chemical composition of degrading paints. In this work, we use advanced infrared analysis techniques to investigate the UV-induced deterioration of model linseed oil paints in detail. Subdiffraction limit infrared analysis (AFM-IR) is applied to identify and map accelerated degradation in the presence of two different grades of titanium white pigment particles (rutile or anatase TiO
). Differentiation between the degradation of these two formulations demonstrates the sensitivity of this approach. The identification of characteristic peaks and transient species residing at the paint surface allows infrared absorbance peaks related to degradation deeper in the film to be extricated from conventional ATR-FTIR spectra, potentially opening up a new approach to degradation monitoring. |
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| AbstractList | As linseed oil has a longstanding and continuing history of use as a binder in artistic paints, developing an understanding of its degradation mechanism is critical to conservation efforts. At present, little can be done to detect the early stages of oil paint deterioration due to the complex chemical composition of degrading paints. In this work, we use advanced infrared analysis techniques to investigate the UV-induced deterioration of model linseed oil paints in detail. Subdiffraction limit infrared analysis (AFM-IR) is applied to identify and map accelerated degradation in the presence of two different grades of titanium white pigment particles (rutile or anatase TiO2). Differentiation between the degradation of these two formulations demonstrates the sensitivity of this approach. The identification of characteristic peaks and transient species residing at the paint surface allows infrared absorbance peaks related to degradation deeper in the film to be extricated from conventional ATR-FTIR spectra, potentially opening up a new approach to degradation monitoring.As linseed oil has a longstanding and continuing history of use as a binder in artistic paints, developing an understanding of its degradation mechanism is critical to conservation efforts. At present, little can be done to detect the early stages of oil paint deterioration due to the complex chemical composition of degrading paints. In this work, we use advanced infrared analysis techniques to investigate the UV-induced deterioration of model linseed oil paints in detail. Subdiffraction limit infrared analysis (AFM-IR) is applied to identify and map accelerated degradation in the presence of two different grades of titanium white pigment particles (rutile or anatase TiO2). Differentiation between the degradation of these two formulations demonstrates the sensitivity of this approach. The identification of characteristic peaks and transient species residing at the paint surface allows infrared absorbance peaks related to degradation deeper in the film to be extricated from conventional ATR-FTIR spectra, potentially opening up a new approach to degradation monitoring. As linseed oil has a longstanding and continuing history of use as a binder in artistic paints, developing an understanding of its degradation mechanism is critical to conservation efforts. At present, little can be done to detect the early stages of oil paint deterioration due to the complex chemical composition of degrading paints. In this work, we use advanced infrared analysis techniques to investigate the UV-induced deterioration of model linseed oil paints in detail. Subdiffraction limit infrared analysis (AFM-IR) is applied to identify and map accelerated degradation in the presence of two different grades of titanium white pigment particles (rutile or anatase TiO ). Differentiation between the degradation of these two formulations demonstrates the sensitivity of this approach. The identification of characteristic peaks and transient species residing at the paint surface allows infrared absorbance peaks related to degradation deeper in the film to be extricated from conventional ATR-FTIR spectra, potentially opening up a new approach to degradation monitoring. |
| Author | Morsch, Suzanne van den Berg, Klaas Jan Dik, Joris van Driel, Birgit A |
| Author_xml | – sequence: 1 givenname: Suzanne orcidid: 0000-0003-3883-2710 surname: Morsch fullname: Morsch, Suzanne organization: Corrosion and Protection Centre,School of Materials, The University of Manchester , The Mill, Sackville Street, Manchester M13 9PL, United Kingdom – sequence: 2 givenname: Birgit A surname: van Driel fullname: van Driel, Birgit A organization: Materials for Arts and Archeology , 3ME, TU Delft, Mekelweg, 3, 2628 CD Delft, The Netherlands – sequence: 3 givenname: Klaas Jan surname: van den Berg fullname: van den Berg, Klaas Jan organization: Cultural Heritage Agency of The Netherlands , Hobbemastraat, 22, 1071 ZC Amsterdam, The Netherlands – sequence: 4 givenname: Joris surname: Dik fullname: Dik, Joris organization: Materials for Arts and Archeology , 3ME, TU Delft, Mekelweg, 3, 2628 CD Delft, The Netherlands |
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