Flexibility of an Open Indenyl Ligand in Iron(II) Complexes

[FeI2(thf)(2)] was sequentially treated with Li(C5Me5) and the potassium salt of the phenylmethallyl ("open indenyl") ligand oIndme, leading to selective formation of the half-open ferrocene [(eta(5)-C5Me5)Fe(eta(5)-oInd(Me))] (1). A variable-temperature NMR study revealed a barrier of ca....

Celý popis

Podrobná bibliografia

Vydané v:	Organometallics Ročník 31; číslo 12; s. 4480 - 4494
Hlavní autori:	Gloeckner, Andreas, Bannenberg, Thomas, Ibrom, Kerstin, Daniliuc, Constantin G., Freytag, Matthias, Jones, Peter G., Walter, Marc D., Tamm, Matthias
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	WASHINGTON Amer Chemical Soc 25.06.2012
Predmet:	Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Physical Sciences Science & Technology PENTADIENYL COMPLEXES SANDWICH COMPLEXES RING-SLIPPAGE TRANSITION-METAL-COMPLEXES HAPTOTROPIC SHIFTS ORGANOMETALLIC COMPLEXES PHOSPHINE CHEMISTRY SUBSTITUTION-REACTIONS HALF-OPEN METALLOCENES ELECTRONIC-STRUCTURE
ISSN:	0276-7333, 1520-6041
On-line prístup:	Zistit podrobnosti o prístupe
Tagy:	Pridať tag Žiadne tagy, Buďte prvý, kto otaguje tento záznam!