Atlas of Polymer Structures - Morphology, Deformation and Fracture Structures

Structure and morphology determine the properties of polymeric materials. This atlas provides, with well over 2000 high-quality micrographs, a comprehensive overview of the structural/morphological diversity of all classes of polymers. All microscopic techniques from light microscopy through scannin...

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Bibliographic Details
Main Author: Michler, Goerg H.
Format: eBook Book
Language:English
Published: Munich Hanser Publishers 2016
Cincinnati, Ohio Hanser
Hanser Publications
Edition:1
Subjects:
ISBN:1569905576, 9781569905579
Online Access:Get full text
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Table of Contents:
  • Title Page Preface Table of Contents Part I. Introduction 1. Overview 2. Techniques and Methods 3. Influences of Techniques and Methods on Micrographs Part II. Groups of Polymers 1. Amorphous Polymers 2. Semicrystalline Polymers 3. Block Copolymers 4. Polymer Blends 5. Rubber-Toughened Polymers 6. Composites 7. Fiber-Reinforced Polymer Composites 8. Biopolymers and Polymers for Medical Applications 9. Special Processing Forms Part III. Tables Table 1. Connection of Polymers with Morphological Details and Deformation Structures Table 2. Appearance of Morphological Details in Polymers Table 3. Deformation and Fracture Structures in Polymers Table 4. Structural/Morphological Details with Culinary or Natural Backgrounds List of Abbreviations Subject Index
  • 2.1.3  Parameters Influencing Morphology -- 2.1.4  Deformation and Fracture Mechanisms -- 2.2  Polyethylenes -- 2.2.1  High-Density Polyethylene (Linear PE, HDPE) -- 2.2.2  Ultrahigh Molecular Weight Polyethylene (UHMWPE) -- 2.2.3  Low-Density Polyethylene (Branched PE, LDPE) -- 2.2.4  Linear-Low Density Polyethylenes (LLDPE, VLDPE) -- 2.3  Polypropylene (α-, β-iPP, sPP) -- -- 2.3.1  PP Morphology -- 2.3.2  PP Deformation and Fracture Structures -- 2.4  Additional Polymers (PA, PVDF, PBT, PEN, PEEK, POM, PEO, sPS) -- 2.4.1  Morphology -- 2.4.2  Deformation and Fracture -- 3 Block Copolymers -- 3.1  Overview -- 3.1.1  Morphology of Block Copolymers -- 3.1.1.1  Nanostructures via Self-Assembly -- 3.1.1.2  Influence of Chain Architecture -- 3.1.1.3  Block Copolymer/Homopolymer Blends -- 3.1.1.4  Processing-Induced Nonequilibrium Morphologies -- 3.1.1.5  Block Copolymer Nanocomposites -- 3.1.2  Deformation Mechanisms in Block Copolymers -- 3.2  Block Copolymers - Morphology -- 3.2.1  Morphology of Diblock and Triblock Copolymers -- 3.2.2  Morphology of Block Copolymer / Polymer Blends -- 3.3  Deformation and Fracture Structures -- 4 Polymer Blends -- 4.1  Overview -- 4.1.1  Morphology -- 4.1.2  Deformation Mechanisms -- 4.2  Blends of Amorphous Polymer Components -- 4.2.1  Morphology of the Blends -- 4.2.2  Deformation and Fracture Structures -- 4.3  Blends of Amorphous and Semicrystalline Polymers -- 4.3.1  PE/PS Blends, Morphology, and Deformation Structures -- 4.3.2  PP Blends with PS and PEO -- 4.3.3  Blends of TPU with SAN and ABS -- 4.3.4  Blends of PBT/PET with PC -- 4.3.5  Blends of PA with ABS, HIPS, and sPS -- 4.3.6  PE Multiphase Blends -- 4.4  Blends of Semicrystalline Polymers -- 4.4.1  Blends of HDPE, LDPE, and VLDPE -- 4.4.2  PE/PP Blends -- 4.4.3  PP/PA Blends -- 4.4.4  PBT, PET Blends (with EVA, PE, PP, PA)
  • 4.5  Rubbers and Elastomers -- 4.5.1  NR and SBR Blends -- 4.5.2  EVA Copolymer -- 4.5.3  Polyurethanes (PU, TPU) -- 4.5.4  Further Elastomers -- 5 Rubber-Toughened Polymers -- 5.1  Overview -- 5.1.1  Morphology -- 5.1.2  Basic Micromechanical Mechanisms -- 5.2  Systems with an Amorphous Matrix -- 5.2.1  High-Impact Polystyrene (HIPS) -- 5.2.1.1  Morphology -- 5.2.1.2  Deformation Mechanisms -- 5.2.2  Acrylonitrile-Butadiene-Styrene (ABS) -- 5.2.2.1  Morphology -- 5.2.2.2  ABS Deformation Mechanisms -- 5.2.3  Rubber-Modified SAN: SAN/EVA, SAN/CPE (ACS), SAN/PBA (ASA) -- 5.2.4  Rubber-Toughened PMMA (RTPMMA) -- 5.2.5  Additional Amorphous Rubber-Toughened Polymers (Rubber‑Toughened PC, COC, Epoxy) -- 5.2.6  Rubber-Toughened PVC -- 5.2.6.1  Toughened PVC with Disperse Structure -- 5.2.6.2  Toughened PVC with Network Structure -- 5.3  Systems with Semicrystalline Matrix -- 5.3.1  Rubber-Modified Polypropylene (PP) -- 5.3.2  Rubber-Modified Polyamide -- 6 Composites -- 6.1  Main Characteristics -- 6.1.1  Particle-Filled Polymer Composites -- 6.1.2  Nanoparticle Polymer Composites -- 6.2  Particle-Filled Polymer Composites -- 6.2.1  Morphology -- 6.2.2  Deformation Structures -- 6.3  Nanoparticle-Filled Polymers (Nanocomposites) -- 6.3.1  Morphology -- 6.3.2  Deformation Structures -- 7 Fiber-Reinforced Polymer Composites -- 7.1  Overview -- 7.2  Inorganic and Carbon Fiber Polymer Composites -- 7.3  Polymer-Polymer Composites and Natural Fiber Composites -- 8 Biopolymers and Polymers for Medical Applications -- 8.1  Overview -- 8.1.1  Biobased and Biodegradable Polymers -- 8.1.2  Biomedical Polymers -- 8.2  Biobased Polymers -- 8.3  Medical Applications -- 9 Special Processing Forms -- 9.1  Overview -- 9.2  Hot-Compacted Fibers and Films -- 9.3  Coextruded Multilayered Polymers -- 9.3.1  Morphology -- 9.3.2  Deformation Structures -- 9.4  Nanofibers
  • Intro -- Contents -- Part I - Introduction -- 1 Overview -- 1.1  Aim of the Atlas -- 1.2  Molecular Structures -- 1.2.1  Constitution -- 1.2.2  Configuration -- 1.2.3  Conformation -- 1.3  Supramolecular Structures and Morphology -- 1.3.1  Homopolymers -- 1.3.2  Copolymers -- 1.3.3  Polymer Blends -- 1.3.4  Composites -- 1.3.5  Additional Morphologies -- 1.4  Mechanical Behavior -- 1.4.1  Types of Deformation -- 1.4.2  Deformation Mechanisms -- 1.4.3  Fracture -- 2 Techniques and Methods -- 2.1  Microscopic Techniques -- 2.2.1  Overview -- 2.1.2  Optical Microscopy -- 2.1.3  Scanning Electron Microscopy -- 2.1.4  Transmission Electron Microscopy -- 2.1.5  Atomic Force Microscopy -- 2.1.6  Image Processing and Image Analysis -- 2.2  Sample Preparation Methods -- 2.2.1  Overview -- 2.2.2  Preparation of Surfaces -- 2.2.3  Preparation of Thin Sections -- 2.2.4  Contrast Enhancement -- 2.2.5  Stereoscopic Imaging and 3D Analysis -- 2.3  Deformation and Fracture Tests -- 3 Influences of Techniques and Methods on Micrographs -- 3.1  Influence of Sample Preparation -- 3.1.1  Influence of Fracture Processes -- 3.1.2  Influence of Section Thickness -- 3.2  Influence of Investigation Parameters in TEM -- 3.2.1  Influence of Electron Beam Intensity -- 3.2.2  High-Resolution Micrographs -- 3.2.3  Tilting of the Specimen in TEM -- Part II - Groups of Polymers -- 1 Amorphous Polymers -- 1.1  Main Characteristics -- 1.1.1  Structure and Morphology -- 1.1.2  Deformation Mechanisms -- 1.2  Homopolymers -- 1.2.1  Polystyrene (PS) -- 1.2.2  Poly(methyl methacrylate) (PMMA) -- 1.2.3  Poly(vinyl chloride) (PVC) -- 1.2.4  Polycarbonate (PC) -- 1.3  Copolymers -- 1.3.1  Styrene Acrylonitrile Copolymers (SAN) -- 1.3.2  Cyclic Olefin Copolymers (COC) -- 2 Semicrystalline Polymers -- 2.1  Overview -- 2.1.1  Lamellar Structure -- 2.1.2  Structural Hierarchy
  • 9.5  Polymeric Foams and Membranes -- Part III - Tables -- Table 1  Connection of Polymers with Morphological Details and Deformation Structures -- Table 2  Appearance of Morphological Details in Polymers -- Table 3  Deformation and Fracture Structures in Polymers -- Table 4  Structural/Morphological Details with Culinary or Natural Backgrounds -- List of Abbreviations -- Subject Index