Thermal Analysis and Thermodynamic Properties of Solids
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| Main Author: | |
|---|---|
| Format: | eBook |
| Language: | English |
| Published: |
Chantilly
Elsevier
2021
|
| Edition: | 2 |
| Subjects: | |
| ISBN: | 0323855377, 9780323855372 |
| Online Access: | Get full text |
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Table of Contents:
- Front cover -- Half Title -- Title -- Copyright -- Contents -- Dedication -- Acknowledgment -- About the Author -- Forward -- Introduction: Anniversary of the half century development and formation of a new field of thermal analysis -- Historical prologue -- Eastern stream of thermoanalytical progression and the foundation of Journal of Thermal Analysis -- The Western course of thermal analysis advancement and foundation of Thermochimica Acta -- Word in Conclusion -- Glossary of terms, definitions and symbols -- Chapter 1 Thermophysical examinations, experimental set-ups, sample and temperature control -- 1.1 Exploring the environment and scale dimensions -- 1.2 Thermal measurements, modes of assessment and thermal methods grouping -- 1.3 Temperature control -- 1.4 Characterisation of experimental curves -- 1.5 Comments on the thermoanalytical sample -- 1.6 Particularities of further temperature modulation -- Chapter 2 Understanding of temperature, heat, gradients and related thermodynamics -- 2.1 A historical look at the development of the temperature concept -- 2.2 What is temperature, its scope and how to specify its thermodynamic description: concept of tempericity -- 2.3 Varying temperature depending on the measurement procedure used and the related new view of the phase diagram kinetics -- 2.4 Heat transfer, Newton cooling law and sample heat inertia -- 2.5 Thermal inertia values calculated for temperature measurement -- 2.6 Illustrative approach to temperature fields developed inside an inert infinite cylinder -- 2.7 Response differential curves for temperature sensor location in temperature gradients -- 2.8 Discussion on temperature and its physical and operational use -- 2.9Appendix: A generalised view on temperature from the cosmic macro-dimension to the quantum micro-world
- 9.4 Fundamental aspects of kinetic evaluations under non-isothermal conditions -- 9.5 Integral and differential methods of kinetic data evaluation -- 9.6 Non-integral power exponents, formal kinetic models and the role of an accommodation function -- 9.7 Practicality and peculiarity of non-isothermal approach -- 9.7.1 Apparent values of activation energies -- 9.7.2 An alternative view on the kinetics: non-parametric approach -- 9.7.3 Non-isothermal studies performed close to equilibrium -- 9.8 Optimal kinetic evaluation procedures of experimental data -- 9.8.1 Málek's master plot -- 9.8.2 Koga's approach to overlapping reactions -- 9.8.3 Evaluation based on polynomial regression: Netzsch software by Moukina -- 9.8.4 Overlapping models, including uncertainty and distort activation energy -- 9.8.5 Special cases of CRTA and temperature oscillation modes -- 9.9 Kinetic compensation effect -- Chapter 10 Thermokinetics in DTA experiments -- 10.1 On the historical outline of differential methods -- 10.2 DTA equation and its testing by rectangular heat pulse -- 10.3 What exactly is the DTA curve and what is its scope and responsibility? -- 10.4 A continuous model of phase transition and temperature profiles within a simple case of cylinder -- 10.5 Temperature profile, temperature modulation and revised DTA equation -- Chapter 11 Physical thermokinetics of reversible thermal decomposition by thermogravimetry -- 11.1 Some notes on the historical thermogravimetry -- 11.2 Specific case of TG study of calcium carbonate decomposition -- 11.3 How are thermo-gravimetric results usable in practice? -- 11.3.1 Micro-kinetics -- 11.3.2 Macro-kinetics -- 11.4 How is the thermodynamic-equilibrium temperature represented in TG curves? -- 11.5 Practical consequences -- 11.6 Yet further accompaniments
- Chapter 12 Exploiting fractals, tackle thermal processes and truer non-isothermal kinetics -- 12.1 Introduction to fractal analysis -- 12.2 Heat capacity by means of fractal structures -- 12.3 Nucleation-induced crystallisation within fractal scrutiny -- 12.4 Heterogeneity, fractals and solid-state reaction kinetics -- 12.5 All-purpose use of yet atypical fractal geometry -- 12.6 Mathematical instigation and impact of logistic models -- 12.7 Origin of the Šesták-Berggren (SB) equation and the impact of logistic tactic -- 12.8 How we are doing and our other prospects and effects -- Chapter 13 Constrained states of glasses, exploitation of transition temperatures, glass-forming coefficients and concepts of fragility -- 13.1 Introduction-a brief look at the glass history -- 13.2 Enthalpy temperature dependence diagrams for a better understanding of the processes taking place in the glasses -- 13.3 GFA and GS -- 13.4 Expressing the Hrubý parameter using temperature relations: r = Tc/Tg and m = Tm/Tg -- 13.5 Relative changes of GS parameters -- 13.6 Modified Angell plot of viscous flow and fragility concept -- 13.7 Reduced glass transition temperature and fragility as parameters for estimating GFA -- 13.8 Stretching exponent against configurational entropy: which factor has greater contribution to kinetic liquid fragility? -- 13.9 The function of temperature dependence of configurational entropy -- Chapter 14 Explanation of crystallisation kinetics both during glass heating and melt cooling, while the incorrectness of the Kissinger method is indicated -- 14.1 Introduction: glass crystallisation and use of DTA -- 14.2 Reminding simple kinetic method proposed by Kissinger -- 14.3 Choice of reaction mechanism, iso-thermal and non-iso-thermal degree of conversion and equilibrium background
- Chapter 3 Phenomenological approach to the caloric theory of heat: An alternative thermodynamics -- 3.1 Fire as a manufacturing tool and its non-matter disposition as caloric -- 3.2 Classical thermodynamics subsist in a phenomenological theory -- 3.3 Heat alike entropy: introduction of caloric theory -- 3.4 Constitutive relations and fundamental laws of thermodynamics within caloric theory -- 3.5 Resolution and determination of caloric -- 3.6 Efficiency of heat engines, dynamic and caloric theory -- Chapter 4 Textbook thermodynamics as thermostatics -- 4.1 Introduction to basic logic of textbook thermodynamics -- 4.2 Force field and measurable deformations -- 4.3 Principles of thermodynamic alternation reaching measurable quantities -- 4.4 Chemical reactions -- 4.5 Heterogeneous systems and the effect of surface energy -- 4.6 Equilibria and impact of Clapeyron equations -- 4.7 Ideal and real solid solutions, phase diagrams -- Chapter 5 Equilibrium background and its importance for temperature and particle size -- 5.1 Some historical facts about the theory of phase transformations -- 5.2 Equilibrium background as a basis for thermal analysis, type of processes and impact of heating -- 5.3 Ehrenfest equations derived for gradual transitions in binary systems -- 5.4 Equilibrium background due to the change in particle curvature -- 5.5 Appendix: A bottom-up inverse approach illustrated by the construction on the atomic level using assembled spheres in a cubic structure -- Chapter 6 Thermodynamics: processes dynamics under constant heating -- 6.1 The validity of thermodynamic laws when ensuring the effect of constant temperature changes -- 6.2 Fourier's heat transfer and the Laws of Fick and Ohm in a historical overview -- 6.3 Phase transitions, their order and concept of broadened transformations
- 6.4 Kinetic degree of transformation and the Holba-Sestak equation -- 6.5 Interpretation of phase diagrams using the new kinetic approach -- 6.6 T-T-T and C-T diagrams -- 6.7 Thermodynamics applied to non-equilibrium glass transition -- 6.8 Influence of fluctuations and some features of rational approach -- Chapter 7 Thermotics-theoretical thermal analysis, thermometry and calorimetry -- 7.1 Heat determination by thermometry and calorimetry -- 7.2 Some remarks on the origins of modern thermal analysis -- 7.3 Measurements of thermal diffusivity -- 7.4 Classification of thermoanalytical methods-heat balance -- 7.5 DSC and DTA as quantitative instruments -- 7.6 DTA calibration and the use of defined electrical pulses -- 7.7 Practical cases of applications -- 7.7.1 Phase diagrams -- 7.7.2 Heat capacity -- 7.7.3 Impurity measurements -- 7.8 Temperature-modulated mode -- 7.9 Fast scanning calorimetry -- Chapter 8 Rationality of creating kinetic models: How to mold a reaction path in solid-state -- 8.1 Some philosophical thoughts on a general exercise towards mathematical models -- 8.2 Portrayal roots applied in modelling solid-state reaction pathway -- 8.3 Rate constant function-Arrhenius and non-Arrhenius expressions -- 8.4 Rate constant functions two: reaction models f(α) based on simple geometrical bodies -- 8.5 Idealised models contrary to the real process mechanisms and morphologies -- Chapter 9 Facilitated reaction kinetics by thermal analysis -- 9.1 Inserted retrospective historical view of early non-isothermal kinetics from the point of view of own experience -- 9.1.1 Supplementary references valid only for the above historical section -- 9.2 Constitutive equations applied in non-isothermal chemical kinetics -- 9.3 Once discussed ill-defined kinetic concept of derivates misuse
- 14.4 The point of maximum temperature deviation at DTA peak is not the point of maximum reaction rate