Suchergebnisse - "Smolders, Simon"

Enhancing Metal Separations by Liquid–Liquid Extraction Using Polar Solvents von Li, Zheng, Zhang, Zidan, Smolders, Simon, Li, Xiaohua, Raiguel, Stijn, Nies, Erik, De Vos, Dirk E., Binnemans, Koen

“… The less polar phase of liquid–liquid extraction systems has been studied extensively for improving metal separations; however, the role of the more polar …”
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The isotopic exchangeability of phosphate in Mg-Al layered double hydroxides von Everaert, Maarten, Slenders, Kris, Dox, Kris, Smolders, Simon, De Vos, Dirk, Smolders, Erik

“… [Display omitted] Layered double hydroxides (LDH) of Mg/Al are anion exchangers that are candidate materials for phosphate (PO4) recovery and recycling from …”
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Unravelling Why and to What Extent the Topology of Similar Ce‐Based MOFs Conditions their Photodynamic: Relevance to Photocatalysis and Photonics von Caballero‐Mancebo, Elena, Cohen, Boiko, Smolders, Simon, De Vos, Dirk E., Douhal, Abderrazzak

“… Metal–organic frameworks (MOFs) are emerging materials for luminescent and photochemical applications. Armed with femto to millisecond spectroscopies, and …”
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Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity von Lammert, Martin, Wharmby, Michael T, Smolders, Simon, Bueken, Bart, Lieb, Alexandra, Lomachenko, Kirill A, Vos, Dirk De, Stock, Norbert

“… A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were …”
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Layered Double Hydroxides as Slow-Release Fertilizer Compounds for the Micronutrient Molybdenum von Everaert, Maarten, Smolders, Erik, McLaughlin, Mike J, Andelkovic, Ivan, Smolders, Simon, Degryse, Fien

“… Molybdenum (Mo) is an essential plant micronutrient. Despite low plant Mo requirements, deficiencies are not uncommon and soluble Mo fertilizers are often …”
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A Titanium(IV)‐Based Metal–Organic Framework Featuring Defect‐Rich Ti‐O Sheets as an Oxidative Desulfurization Catalyst von Smolders, Simon, Willhammar, Tom, Krajnc, Andraž, Sentosun, Kadir, Wharmby, Michael T., Lomachenko, Kirill A., Bals, Sara, Mali, Gregor, Roeffaers, Maarten B. J., De Vos, Dirk E., Bueken, Bart

“… While titanium‐based metal–organic frameworks (MOFs) have been widely studied for their (photo)catalytic potential, only a few TiIV MOFs have been reported …”
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Bipyridine-based UiO-67 as novel filler in mixed-matrix membranes for CO2-selective gas separation von Thür, Raymond, Van Velthoven, Niels, Slootmaekers, Sam, Didden, Jeroen, Verbeke, Rhea, Smolders, Simon, Dickmann, Marcel, Egger, Werner, De Vos, Dirk, Vankelecom, Ivo F.J.

“… Bipyridine-based UiO-67 Metal-Organic Frameworks (MOFs) are for the first time successfully applied as filler material in Matrimid mixed-matrix membranes …”
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Enhancing the phosphorus content of layered double hydroxide fertilizers by intercalating polymeric phosphate instead of orthophosphate: A feasibility study von Everaert, Maarten, Degryse, Fien, McLaughlin, Mike J., Smolders, Simon, Andelkovic, Ivan, Baird, Roslyn, Smolders, Erik

“… [Display omitted] Layered double hydroxide (LDH) loaded with orthophosphate (PO4) are suggested as slow-release P fertilizers. However, PO4-LDHs have a low …”
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A precursor method for the synthesis of new Ce(iv) MOFs with reactive tetracarboxylate linkers von Smolders, Simon, Struyf, Arnaud, Reinsch, Helge, Bueken, Bart, Rhauderwiek, Timo, Mintrop, Luise, Kurz, Philipp, Stock, Norbert, De Vos, Dirk E

“… A precursor method has been developed to synthesize Ce(iv) MOFs that could not be prepared directly from Ce(iv) salts. Starting from Ce clusters, two Ce-UiO-66 …”
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Interplay between structural parameters and reactivity of Zr6-based MOFs as artificial proteases von Loosen, Alexandra, de Azambuja, Francisco, Smolders, Simon, Moons, Jens, Simms, Charlotte, De Vos, Dirk, Parac-Vogt, Tatjana N

“… Structural parameters influencing the reactivity of metal–organic frameworks (MOF) are challenging to establish. However, understanding their effect is crucial …”
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Interplay between structural parameters and reactivity of Zr 6 -based MOFs as artificial proteases von Loosen, Alexandra, de Azambuja, Francisco, Smolders, Simon, Moons, Jens, Simms, Charlotte, De Vos, Dirk, Parac-Vogt, Tatjana N.

“… Structural parameters influencing the reactivity of metal–organic frameworks (MOF) are challenging to establish. However, understanding their effect is crucial …”
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Single-site metal–organic framework catalysts for the oxidative coupling of arenes via C–H/C–H activation von Van Velthoven, Niels, Waitschat, Steve, Chavan, Sachin M., Liu, Pei, Smolders, Simon, Vercammen, Jannick, Bueken, Bart, Bals, Sara, Lillerud, Karl Petter, Stock, Norbert, De Vos, Dirk E.

“… C–H activation reactions are generally associated with relatively low turnover numbers (TONs) and high catalyst concentrations due to a combination of low …”
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Modulator-Mediated Functionalization of MOF-808 as a Platform Tool to Create High-Performance Mixed-Matrix Membranes von Thür, Raymond, Van Velthoven, Niels, Lemmens, Vincent, Bastin, Maarten, Smolders, Simon, De Vos, Dirk, Vankelecom, Ivo F J

“… Modulator-mediated functionalization (MoFu) is introduced as a new and versatile platform tool to improve the separation performance of metal-organic framework …”
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The first water-based synthesis of Ce(iv)-MOFs with saturated chiral and achiral C 4 -dicarboxylate linkers von Jacobsen, Jannick, Achenbach, Bastian, Reinsch, Helge, Smolders, Simon, Lange, Florian-David, Friedrichs, Gernot, De Vos, Dirk, Stock, Norbert

“… Six different chiral and achiral alkane dicarboxylic C -acids, i.e. succinic acid (H SUC), dl-2-methylsuccinic acid (H MS), 2,3-dimethylsuccinic acid (H DMS) …”
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Double metal cyanides as heterogeneous Lewis acid catalysts for nitrile synthesis via acid-nitrile exchange reactions von Marquez, Carlos, Corbet, Matthieu, Smolders, Simon, Marion, Philippe, De Vos, Dirk

“… A series of transition metal-based double metal cyanides (DMCs) were studied as catalysts for the synthesis of nitriles via acid-nitrile exchange reaction. The …”
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Bulk-to-Surface Proton-Coupled Electron Transfer Reactivity of the Metal-Organic Framework MIL-125 von Saouma, Caroline T, Richard, Sarah, Smolders, Simon, Delley, Murielle F, Ameloot, Rob, Vermoortele, Frederik, De Vos, Dirk E, Mayer, James M

“… Stoichiometric proton-coupled electron transfer (PCET) reactions of the metal-organic framework (MOF) MIL-125, Ti O (OH) (bdc) (bdc = terephthalate), are …”
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Unravelling the Redox‐catalytic Behavior of Ce4+ Metal–Organic Frameworks by X‐ray Absorption Spectroscopy von Smolders, Simon, Lomachenko, Kirill A., Bueken, Bart, Struyf, Arnaud, Bugaev, Aram L., Atzori, Cesare, Stock, Norbert, Lamberti, Carlo, Roeffaers, Maarten B. J., De Vos, Dirk E.

“… The introduction of Ce4+ as a structural cation has been shown to be a promising route to redox active metal–organic frameworks (MOFs). However, the mechanism …”
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Bismuth gallate coordination networks inspired by an active pharmaceutical ingredient von Svensson Grape, Erik, Rooth, Victoria, Smolders, Simon, Thiriez, Ambre, Takki, Sofia, De Vos, Dirk, Willhammar, Tom, Inge, A Ken

“… The effect of solvent has been investigated for the synthesis of bismuth gallate compounds, of which the water-based bismuth subgallate has been used as an …”
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The first water-based synthesis of Ce(iv)-MOFs with saturated chiral and achiral C4-dicarboxylate linkers von Jacobsen, Jannick, Achenbach, Bastian, Reinsch, Helge, Smolders, Simon, Lange, Florian-David, Friedrichs, Gernot, De Vos, Dirk, Stock, Norbert

“… Six different chiral and achiral alkane dicarboxylic C4-acids, i.e. succinic acid (H2SUC), dl-2-methylsuccinic acid (H2MS), 2,3-dimethylsuccinic acid (H2DMS) …”
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Sustainable formation of tricarballylic acid from citric acid over highly stable Pd/Nb2O5·nH2O catalysts von Stuyck, Wouter, Bugaev, Aram L., Nelis, Tom, de Oliveira-Silva, Rodrigo, Smolders, Simon, Usoltsev, Oleg A., Arenas Esteban, Daniel, Bals, Sara, Sakellariou, Dimitrios, De Vos, Dirk

“… [Display omitted] •Nb2O5·nH2O proved to be a stable and efficient catalyst for the dehydration of citric acid at mild reaction temperatures.•Investigation of …”
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