Search Results - "Perfetti, Mauro"
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Magnetic Anisotropy Trends along a Full 4f-Series: The fn+7 Effect
ISSN: 1520-5126, 1520-5126Published: 24.05.2021Published in Journal of the American Chemical Society (24.05.2021)“…The combined experimental and computational study of the 13 magnetic complexes belonging to the Na[LnDOTA(H2O)] (H4DOTA =…”
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Beyond the anisotropy barrier: slow relaxation of the magnetization in both easy-axis and easy-plane Ln(trensal) complexes
ISSN: 1364-548X, 1364-548XPublished: England 01.01.2014Published in Chemical communications (Cambridge, England) (01.01.2014)“…We present a spectroscopic and magnetic (both static and dynamic) characterization of two isostructural Dy and Er complexes evidencing that, despite the…”
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3
Quantum coherence in a processable vanadyl complex: new tools for the search of molecular spin qubits
ISSN: 2041-6520, 2041-6539Published: England Royal Society of Chemistry 01.03.2016Published in Chemical science (Cambridge) (01.03.2016)“…Electronic spins in different environments are currently investigated as potential qubits, i.e. the logic units of quantum computers. These have to retain…”
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4
Electric control of magnetic exchange in a molecular spin triangle
ISSN: 2041-1723, 2041-1723Published: London Nature Publishing Group UK 16.07.2025Published in Nature communications (16.07.2025)“…Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism…”
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5
Exchange coupling and single molecule magnetism in redox-active tetraoxolene-bridged dilanthanide complexes
ISSN: 2041-6520, 2041-6539Published: England Royal Society of Chemistry 2018Published in Chemical science (Cambridge) (2018)“…Tetraoxolene radical-bridged lanthanide SMM systems were prepared for the first time by reduction of the respective neutral compounds. Magnetic measurements…”
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Giant field dependence of the low temperature relaxation of the magnetization in a dysprosium(III)-DOTA complex
ISSN: 1364-548X, 1364-548XPublished: England 01.01.2011Published in Chemical communications (Cambridge, England) (01.01.2011)“…The square antiprismatic Na[Dy(DOTA)(H(2)O)]·4H(2)O complex was characterised by single crystal X-ray diffraction and ac magnetic susceptometry. Two competing…”
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7
Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet
ISSN: 2041-1723, 2041-1723Published: London Nature Publishing Group UK 29.03.2018Published in Nature communications (29.03.2018)“…Total control over the electronic spin relaxation in molecular nanomagnets is the ultimate goal in the design of new molecules with evermore realizable…”
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8
Determination of magnetic anisotropy in the LnTRENSAL complexes (Ln = Tb, Dy, Er) by torque magnetometry
ISSN: 1520-510X, 1520-510XPublished: United States 06.04.2015Published in Inorganic chemistry (06.04.2015)“…We report here a study about the magnetic anisotropy of the LnTRENSAL complexes (Ln = Tb, Dy, Er) performed by using cantilever torque magnetometry and…”
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9
Magnetic Anisotropy in Pentacoordinate NiII and CoII Complexes: Unraveling Electronic and Geometrical Contributions
ISSN: 0947-6539, 1521-3765, 1521-3765Published: Weinheim Wiley Subscription Services, Inc 13.03.2017Published in Chemistry : a European journal (13.03.2017)“…The magnetic properties of the pentacoordinate [MII(Me4cyclam)N3]+ (Me4cyclam=tetramethylcyclam; N3=azido; M=Ni, Co) complexes were investigated. Magnetization…”
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10
Determination of the electronic structure of a dinuclear dysprosium single molecule magnet without symmetry idealization
ISSN: 2041-6520, 2041-6539Published: England Royal Society of Chemistry 21.02.2019Published in Chemical science (Cambridge) (21.02.2019)“…We present the in-depth determination of the magnetic properties and electronic structure of the luminescent and volatile dysprosium-based single molecule…”
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11
Magnetic Anisotropy Switch: Easy Axis to Easy Plane Conversion and Vice Versa
ISSN: 1616-301X, 1616-3028Published: Hoboken Wiley Subscription Services, Inc 08.08.2018Published in Advanced functional materials (08.08.2018)“…The rational design of the magnetic anisotropy of molecular materials constitutes a goal of primary importance in molecular magnetism. Indeed, the applications…”
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Importance of Axial Symmetry in Elucidating Lanthanide-Transition Metal Interactions
ISSN: 1520-510X, 1520-510XPublished: United States 06.01.2020Published in Inorganic chemistry (06.01.2020)“…In this paper, we experimentally study and model the electron donating character of an axial diamagnetic Pd ion in four metalloligated lanthanide complexes of…”
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13
Quantifying Magnetic Anisotropy of Series of Five‐Coordinate CoII Ions: Experimental and Theoretical Insights
ISSN: 2198-3844, 2198-3844Published: Weinheim John Wiley & Sons, Inc 01.03.2025Published in Advanced science (01.03.2025)“…Stabilizing large easy‐axis type magnetic anisotropy in molecular complexes is a challenging task, yet it is crucial for the development of information storage…”
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Er(III) and Yb(III) Complexes with a Tripodal Nitroxyl Radical: Magnetochemical Study and Ab Initio Calculations
ISSN: 2312-7481, 2312-7481Published: Basel MDPI AG 01.02.2025Published in Magnetochemistry (01.02.2025)“…In this paper, we investigate the magnetic exchange interaction and magnetization dynamics of two new members of the [LnRad(NO3)3] family, where Rad is a…”
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Angular-Resolved Magnetometry Beyond Triclinic Crystals Part II: Torque Magnetometry of CpErCOT Single-Molecule Magnets
ISSN: 0947-6539, 1521-3765, 1521-3765Published: Weinheim WILEY-VCH Verlag 20.10.2014Published in Chemistry : a European journal (20.10.2014)“…The experimental investigation of the molecular magnetic anisotropy in crystals in which the magnetic centers are symmetry related, but do not have a parallel…”
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Commentary on "An intermediate state between the kagome-ice and the fully polarized state in Dy2Ti2O7"
ISSN: 1852-4249, 1852-4249Published: Papers in Physics 01.05.2015Published in Papers in physics (01.05.2015)“…A Commentary on the paper by S A Grigera et al. [Pap. Phys. 7, 070009 (2015)]. Received: 25 June 2015, Accepted: 25 June 2015; Edited by: A. Vindigni; DOI:…”
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Mapping of single-site magnetic anisotropy tensors in weakly coupled spin clusters by torque magnetometry
ISSN: 1463-9084, 1463-9084Published: England 28.08.2014Published in Physical chemistry chemical physics : PCCP (28.08.2014)“…Single-crystal torque magnetometry performed on weakly-coupled polynuclear systems provides access to a complete description of single-site anisotropy tensors…”
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18
Cantilever torque magnetometry on coordination compounds: from theory to experiments
ISSN: 0010-8545, 1873-3840Published: Elsevier B.V 01.10.2017Published in Coordination chemistry reviews (01.10.2017)“…[Display omitted] •Possibility to disentangle noncollinearity in all the crystal systems.•A detailed relation between magnetic anisotropy and crystal structure…”
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Electronic structure and magnetic anisotropy design of functional metal complexes
ISSN: 0010-8545, 1873-3840Published: Elsevier B.V 01.09.2023Published in Coordination chemistry reviews (01.09.2023)“…[Display omitted] •Two chemically controllable parameters can assess the potential use of a magnetic material.•Coordination chemistry can be used to engineer…”
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Chiral, Heterometallic Lanthanide–Transition Metal Complexes by Design
ISSN: 2304-6740, 2304-6740Published: Basel MDPI AG 01.09.2018Published in Inorganics (01.09.2018)“…Achieving control over coordination geometries in lanthanide complexes remains a challenge to the coordination chemist. This is particularly the case in the…”
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