Suchergebnisse - "De Vos, Dirk E."

Defect-Engineered Metal-Organic Frameworks von Fang, Zhenlan, Bueken, Bart, De Vos, Dirk E., Fischer, Roland A.

“… Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in …”
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Synthesis modulation as a tool to increase the catalytic activity of metal-organic frameworks: the unique case of UiO-66(Zr) von Vermoortele, Frederik, Bueken, Bart, Le Bars, Gaëlle, Van de Voorde, Ben, Vandichel, Matthias, Houthoofd, Kristof, Vimont, Alexandre, Daturi, Marco, Waroquier, Michel, Van Speybroeck, Veronique, Kirschhock, Christine, De Vos, Dirk E

“… The catalytic activity of the zirconium terephthalate UiO-66(Zr) can be drastically increased by using a modulation approach. The combined use of …”
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Electrocarboxylation: towards sustainable and efficient synthesis of valuable carboxylic acids von Matthessen, Roman, Fransaer, Jan, Binnemans, Koen, De Vos, Dirk E

“… The near-unlimited availability of CO 2 has stimulated a growing research effort in creating value-added products from this greenhouse gas. This paper presents …”
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Boosting the Catalytic Performance of Metal–Organic Frameworks for Steroid Transformations by Confinement within a Mesoporous Scaffold von Cirujano, Francisco G., Luz, Ignacio, Soukri, Mustapha, Van Goethem, Cedric, Vankelecom, Ivo F. J., Lail, Marty, De Vos, Dirk E.

“… Solid‐state crystallization achieves selective confinement of metal–organic framework (MOF) nanocrystals within mesoporous materials, thereby rendering active …”
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Enhancing Metal Separations by Liquid–Liquid Extraction Using Polar Solvents von Li, Zheng, Zhang, Zidan, Smolders, Simon, Li, Xiaohua, Raiguel, Stijn, Nies, Erik, De Vos, Dirk E., Binnemans, Koen

“… The less polar phase of liquid–liquid extraction systems has been studied extensively for improving metal separations; however, the role of the more polar …”
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Three-Dimensional Visualization of Defects Formed during the Synthesis of Metal-Organic Frameworks: A Fluorescence Microscopy Study von Ameloot, Rob, Vermoortele, Frederik, Hofkens, Johan, De Schryver, Frans C., De Vos, Dirk E., Roeffaers, Maarten B. J.

“… Imperfections in the spotlight: Fluorescence microscopy was used to detect defects in metal–organic frameworks formed during synthesis. In contrast to …”
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Selective Removal of N-Heterocyclic Aromatic Contaminants from Fuels by Lewis Acidic Metal-Organic Frameworks von Maes, Michael, Trekels, Maarten, Boulhout, Mohammed, Schouteden, Stijn, Vermoortele, Frederik, Alaerts, Luc, Heurtaux, Daniela, Seo, You-Kyong, Hwang, Young Kyu, Chang, Jong-San, Beurroies, Isabelle, Denoyel, Renaud, Temst, Kristiaan, Vantomme, Andre, Horcajada, Patricia, Serre, Christian, De Vos, Dirk E.

“… Bring in the cleaner! Metal–organic frameworks (MOFs) are able to separate nitrogen and sulfur contaminants from fuel, which may lead to the production of …”
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Probing the Lewis Acidity and Catalytic Activity of the Metal-Organic Framework [Cu3(btc)2] (BTC=Benzene-1,3,5-tricarboxylate) von Alaerts, Luc, Séguin, Etienne, Poelman, Hilde, Thibault-Starzyk, Frédéric, Jacobs, Pierre A., De Vos, Dirk E.

“… An optimized procedure was designed for the preparation of the microporous metal–organic framework (MOF) [Cu3(btc)2] (BTC=benzene‐1,3,5‐tricarboxylate). The …”
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Direct Synthesis of Aluminosilicate IWR Zeolite from a Strong Interaction between Zeolite Framework and Organic Template von Hong, Xin, Chen, Wei, Zhang, Guanqun, Wu, Qinming, Lei, Chi, Zhu, Qiuyan, Meng, Xiangju, Han, Shichao, Zheng, Anmin, Ma, Yanhang, Parvulescu, Andrei-Nicolae, Müller, Ulrich, Zhang, Weiping, Yokoi, Toshiyuki, Bao, Xinhe, Marler, Bernd, De Vos, Dirk E, Kolb, Ute, Xiao, Feng-Shou

“… A large amount of zeolite structures are still not synthetically available or not available in the form of aluminosilicate currently. Despite significant …”
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A Hybrid Supercapacitor based on Porous Carbon and the Metal‐Organic Framework MIL‐100(Fe) von Campagnol, Nicolò, Romero‐Vara, Ricardo, Deleu, Willem, Stappers, Linda, Binnemans, Koen, De Vos, Dirk E., Fransaer, Jan

“… Composite supercapacitor electrodes based on carbon nanotubes, carbon black, and a metal–organic framework with iron(III) coordination centers [MIL‐100(Fe), …”
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Adsorptive characterization of the ZIF-68 metal-organic framework: a complex structure with amphiphilic properties von Van der Perre, Stijn, Van Assche, Tom, Bozbiyik, Belgin, Lannoeye, Jeroen, De Vos, Dirk E, Baron, Gino V, Denayer, Joeri F M

“… In this experimental study, the adsorption behavior of the ZIF-68 heterolinked zeolitic imidazolate framework has been explored. Vapor phase adsorption …”
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Super-Resolution Reactivity Mapping of Nanostructured Catalyst Particles von Roeffaers, Maarten B.J, De Cremer, Gert, Libeert, Julien, Ameloot, Rob, Dedecker, Peter, Bons, Anton-Jan, Bückins, Matthias, Martens, Johan A, Sels, Bert F, De Vos, Dirk E, Hofkens, Johan

“… Its a small world: Nanoscale reactivity maps of working heterogeneous catalysts are recorded under in situ conditions by localizing single fluorescent reaction …”
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Framework Breathing in the Vapour-Phase Adsorption and Separation of Xylene Isomers with the Metal-Organic Framework MIL-53 von Finsy, Vincent, Kirschhock, Christine E. A., Vedts, Gill, Maes, Michael, Alaerts, Luc, De Vos, Dirk E., Baron, Gino V., Denayer, Joeri F. M.

“… Vapour‐phase adsorption and separation of the C8 alkyl aromatic compounds p‐xylene, m‐xylene, o‐xylene, and ethylbenzene has been studied on the metal–organic …”
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Optical Encoding of Silver Zeolite Microcarriers von De Cremer, Gert, Sels, Bert F., Hotta, Jun-ichi, Roeffaers, Maarten B. J., Bartholomeeusen, Evelyne, Coutiño-Gonzalez, Eduardo, Valtchev, Valentin, De Vos, Dirk E., Vosch, Tom, Hofkens, Johan

“… Highly resolved fluorescent patterns are generated in an individual silver‐exchanged K‐A zeolite crystal using two‐photon excitation (see figure). The high …”
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Palladium Catalysts on Alkaline-Earth Supports for Racemization and Dynamic Kinetic Resolution of Benzylic Amines von Parvulescu, Andrei N., Jacobs, Pierre A., De Vos, Dirk E.

“… Palladium catalysts on alkaline‐earth supports were studied as new heterogeneous catalysts for racemization of chiral benzylic amines such as …”
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Spatially resolved observation of crystal-face-dependent catalysis by single turnover counting von Roeffaers, Maarten B. J., Sels, Bert F., Uji-i, Hiroshi, De Schryver, Frans C., Jacobs, Pierre A., De Vos, Dirk E., Hofkens, Johan

“… Catalytic processes on surfaces have long been studied by probing model reactions on single-crystal metal surfaces under high vacuum conditions. Yet the vast …”
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Bio-Based Nitriles from the Heterogeneously Catalyzed Oxidative Decarboxylation of Amino Acids von Claes, Laurens, Matthessen, Roman, Rombouts, Ine, Stassen, Ivo, De Baerdemaeker, Trees, Depla, Diederik, Delcour, Jan A., Lagrain, Bert, De Vos, Dirk E.

“… The oxidative decarboxylation of amino acids to nitriles was achieved in aqueous solution by in situ halide oxidation using catalytic amounts of tungstate …”
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A Titanium(IV)‐Based Metal–Organic Framework Featuring Defect‐Rich Ti‐O Sheets as an Oxidative Desulfurization Catalyst von Smolders, Simon, Willhammar, Tom, Krajnc, Andraž, Sentosun, Kadir, Wharmby, Michael T., Lomachenko, Kirill A., Bals, Sara, Mali, Gregor, Roeffaers, Maarten B. J., De Vos, Dirk E., Bueken, Bart

“… While titanium‐based metal–organic frameworks (MOFs) have been widely studied for their (photo)catalytic potential, only a few TiIV MOFs have been reported …”
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Iron(III)-based metal-organic frameworks as visible light photocatalysts von Laurier, Katrien G M, Vermoortele, Frederik, Ameloot, Rob, De Vos, Dirk E, Hofkens, Johan, Roeffaers, Maarten B J

“… Herein, a new group of visible light photocatalysts is described. Iron(III) oxides could be promising visible light photocatalysts because of their small band …”
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Electronic Effects of Linker Substitution on Lewis Acid Catalysis with Metal-Organic Frameworks von Vermoortele, Frederik, Vandichel, Matthias, Van de Voorde, Ben, Ameloot, Rob, Waroquier, Michel, Van Speybroeck, Veronique, De Vos, Dirk E.

“… Functionalized linkers can greatly increase the activity of metal–organic framework (MOF) catalysts with coordinatively unsaturated sites. A clear linear …”
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