Suchergebnisse - "Albold, Uta"
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NIR‐Emissive Chromium(0), Molybdenum(0), and Tungsten(0) Complexes in the Solid State at Room Temperature
ISSN: 0947-6539, 1521-3765, 1521-3765Veröffentlicht: Germany Wiley Subscription Services, Inc 09.09.2021Veröffentlicht in Chemistry : a European journal (09.09.2021)“… The development of NIR emitters based on earth‐abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl …”
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Electronic structure of mononuclear and radical-bridged dinuclear cobalt(II) single-molecule magnets
ISSN: 2041-1723, 2041-1723Veröffentlicht: London Nature Publishing Group UK 04.03.2025Veröffentlicht in Nature communications (04.03.2025)“… Metal-organic compounds that feature magnetic bistability have been proposed as bits for magnetic storage, but progress has been slow. Four-coordinate …”
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Iron(II), Cobalt(II), and Nickel(II) Complexes of Bis(sulfonamido)benzenes: Redox Properties, Large Zero-Field Splittings, and Single-Ion Magnets
ISSN: 1520-510X, 1520-510XVeröffentlicht: United States 01.03.2021Veröffentlicht in Inorganic chemistry (01.03.2021)“… Metal complexes of 1,2-diamidobenzenes have been long studied because of their intriguing redox properties and electronic structures. We present here a series …”
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Rhodium diamidobenzene complexes: a tale of different substituents on the diamidobenzene ligand
ISSN: 2041-6520, 2041-6539Veröffentlicht: CAMBRIDGE Royal Soc Chemistry 14.09.2022Veröffentlicht in Chemical science (Cambridge) (14.09.2022)“… Diamidobenzene ligands are a prominent class of redox-active ligands owing to their electron reservoir behaviour, as well as the possibility of tuning the …”
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Mono‐ and Di‐Mesoionic Carbene‐Boranes: Synthesis, Structures and Utility as Reducing Agents
ISSN: 1434-1948, 1099-0682Veröffentlicht: WEINHEIM Wiley 25.06.2021Veröffentlicht in European journal of inorganic chemistry (25.06.2021)“… Mesoionic carbenes (MIC) of the 1,2,3‐triazol‐5‐ylidene type are currently popular ligands in organometallic chemistry. Their use in main group chemistry has …”
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Strong Exchange Couplings Drastically Slow Down Magnetization Relaxation in an Air‐Stable Cobalt(II)‐Radical Single‐Molecule Magnet (SMM)
ISSN: 1433-7851, 1521-3773, 1521-3773Veröffentlicht: Germany Wiley Subscription Services, Inc 15.07.2019Veröffentlicht in Angewandte Chemie International Edition (15.07.2019)“… The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating …”
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Precursor molecules for 1,2-diamidobenzene containing cobalt(II), nickel(II) and zinc(II) complexes - synthesis and magnetic properties
ISSN: 1477-9234, 1477-9234Veröffentlicht: England 10.06.2024Veröffentlicht in Dalton transactions : an international journal of inorganic chemistry (10.06.2024)“… Molecular magnetic materials based on 1,2-diamidobenzenes are well known and have been intensively studied both experimentally and computationally. They …”
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d–d Dative Bonding Between Iron and the Alkaline‐Earth Metals Calcium, Strontium, and Barium
ISSN: 1433-7851, 1521-3773, 1521-3773Veröffentlicht: Germany Wiley Subscription Services, Inc 17.08.2020Veröffentlicht in Angewandte Chemie International Edition (17.08.2020)“… Double deprotonation of the diamine 1,1′‐(tBuCH2NH)‐ferrocene (1‐H2) by alkaline‐earth (Ae) or EuII metal reagents gave the complexes 1‐Ae (Ae=Mg, Ca, Sr, Ba) …”
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Chromium(0) and Molydenum(0) Complexes with a Pyridyl-Mesoionic Carbene Ligand: Structural, (Spectro)electrochemical, Photochemical, and Theoretical Investigations
ISSN: 1520-510X, 1520-510XVeröffentlicht: 19.10.2020Veröffentlicht in Inorganic chemistry (19.10.2020)“… This work reports on the synthesis and in-depth electrochemical and photochemical characterization of two chromium(0) and molydenum(0) metal complexes with …”
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Synthesis, Characterization, and Evaluation of Antibacterial Activity of Ferrocenyl‐1,2,3‐Triazoles, Triazolium Salts, and Triazolylidene Complexes of Gold(i) and Silver(i)
ISSN: 1434-1948, 1099-0682Veröffentlicht: Weinheim Wiley Subscription Services, Inc 15.04.2021Veröffentlicht in European journal of inorganic chemistry (15.04.2021)“… 1,2,3‐triazoles, the corresponding triazolium salts, and the resulting mesoionic carbenes (MICs) of the 1,2,3‐triazol‐5‐ylidene type are at the forefront of …”
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Iridium Azocarboxamide Complexes: Variable Coordination Modes, C-H Activation, Transfer Hydrogenation Catalysis, and Mechanistic Insights
ISSN: 0276-7333, 1520-6041Veröffentlicht: WASHINGTON Amer Chemical Soc 13.12.2021Veröffentlicht in Organometallics (13.12.2021)“… Azocarboxamides, a special class of azo ligands, display intriguing electronic properties due to their versatile binding modes and coordination flexibility …”
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Cobalt Corroles as Electrocatalysts for Water Oxidation: Strong Effect of Substituents on Catalytic Activity
ISSN: 1520-510X, 1520-510XVeröffentlicht: 16.11.2020Veröffentlicht in Inorganic chemistry (16.11.2020)“… Two Co(III) complexes (1Py2 and 2Py2) of new corrole ligands H3L1 (5,15-bis(p-methylcarboxyphenyl)-10-(o-methylcarboxyphenyl)corrole) and H3L2 …”
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Cover Feature: NIR‐Emissive Chromium(0), Molybdenum(0), and Tungsten(0) Complexes in the Solid State at Room Temperature (Chem. Eur. J. 51/2021)
ISSN: 0947-6539, 1521-3765Veröffentlicht: 09.09.2021Veröffentlicht in Chemistry : a European journal (09.09.2021)“… This work presents emissive Cr(0), Mo(0) and W(0) complexes that contain a bidentate pyridyl‐mesoionic carbene ligand and CO coligands. These systems exhibit …”
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A Binuclear Cobalt Complex in the Electrochemical Water Oxidation Reaction
ISSN: 0044-2313, 1521-3749Veröffentlicht: Weinheim Wiley Subscription Services, Inc 14.07.2022Veröffentlicht in Zeitschrift für anorganische und allgemeine Chemie (1950) (14.07.2022)“… The water splitting reaction represents an appealing approach to store solar energy. The 4e−/4H+ oxidation of water generating O2 is considered as the …”
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Corrigendum: NIR‐Emissive Chromium(0), Molybdenum(0), and Tungsten(0) Complexes in the Solid State at Room Temperature
ISSN: 0947-6539, 1521-3765, 1521-3765Veröffentlicht: Germany Wiley Subscription Services, Inc 03.07.2023Veröffentlicht in Chemistry : a European journal (03.07.2023)Volltext
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Tuning Pt II ‐Based Donor–Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis
ISSN: 0947-6539, 1521-3765Veröffentlicht: Germany Wiley-VCH Verlag 27.01.2020Veröffentlicht in Chemistry : a European journal (27.01.2020)“… Asymmetric platinum donor–acceptor complexes [(pimp)Pt(Q 2− )] are presented in this work, in which pimp=[(2,4,6‐trimethylphenylimino)methyl]pyridine and Q 2− …”
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Isolable Cu(I) Complexes of Extremely Electron-Poor, Completely Unreduced o-Quinone and "Di- o-Quinone" Ligands Stabilized through π-π Interactions in the Secondary Coordination Sphere
ISSN: 1520-510X, 1520-510XVeröffentlicht: United States 18.03.2019Veröffentlicht in Inorganic chemistry (18.03.2019)“… The copper-quinone interaction plays important roles in diverse fields such as biochemistry, catalysis, and optically/magnetically switchable materials …”
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A coordinatively unsaturated iridium complex with an unsymmetrical redox-active ligand: (spectro)electrochemical and reactivity studies
ISSN: 1477-9234, 1477-9234Veröffentlicht: England 07.10.2019Veröffentlicht in Dalton transactions : an international journal of inorganic chemistry (07.10.2019)“… Redox-active ligands, owing to their electron reservoir capability, are well suited for the generation of coordinatively unsaturated metal complexes. We …”
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Tuning PtII‐Based Donor–Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis
ISSN: 0947-6539, 1521-3765, 1521-3765Veröffentlicht: Weinheim Wiley Subscription Services, Inc 27.01.2020Veröffentlicht in Chemistry : a European journal (27.01.2020)“… Asymmetric platinum donor–acceptor complexes [(pimp)Pt(Q2−)] are presented in this work, in which pimp=[(2,4,6‐trimethylphenylimino)methyl]pyridine and …”
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d–d Dative Bonding Between Iron and the Alkaline‐Earth Metals Calcium, Strontium, and Barium
ISSN: 0044-8249, 1521-3757Veröffentlicht: Weinheim Wiley Subscription Services, Inc 17.08.2020Veröffentlicht in Angewandte Chemie (17.08.2020)“… Double deprotonation of the diamine 1,1′‐(tBuCH2NH)‐ferrocene (1‐H2) by alkaline‐earth (Ae) or EuII metal reagents gave the complexes 1‐Ae (Ae=Mg, Ca, Sr, Ba) …”
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