High Resolution Imaging, Spectroscopy and Nuclear Quantum Effects of Interfacial Water

This thesis presents a series of experimental techniques based on scanning probe microscopy, which make it possible access the degree of freedom of protons both in real and energy space. These novel techniques and methods allow direct visualization of the concerted quantum tunneling of protons withi...

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1. Verfasser: Guo, Jing (VerfasserIn)
Format: Elektronisch E-Book
Sprache:Englisch
Veröffentlicht: Singapore : Springer Singapore , 2018.
Ausgabe:1st ed. 2018.
Schriftenreihe:Springer Theses, Recognizing Outstanding Ph.D. Research,
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ISBN:9789811316630
ISSN:2190-5053
Online-Zugang: Volltext
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245 1 0 |a High Resolution Imaging, Spectroscopy and Nuclear Quantum Effects of Interfacial Water  |h [electronic resource] /  |c by Jing Guo. 
250 |a 1st ed. 2018. 
260 1 |a Singapore :  |b Springer Singapore ,  |c 2018. 
300 |a XVIII, 115 p. 49 illus., 48 illus. in color.  |b online resource. 
490 1 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5053 
500 |a Physics and Astronomy  
505 0 |a Introduction -- Submolecular resolution imaging of interfacial water -- Vibrational spectroscopy of interfacial water -- Nuclear quantum effects of interfacial water -- Summary and outlook. 
516 |a text file PDF 
520 |a This thesis presents a series of experimental techniques based on scanning probe microscopy, which make it possible access the degree of freedom of protons both in real and energy space. These novel techniques and methods allow direct visualization of the concerted quantum tunneling of protons within the hydrogen-bonded network and quantification of the quantum component of a single hydrogen bond at a water-solid interface for the first time. Furthermore, the thesis demonstrates that the anharmonic quantum fluctuations of hydrogen nuclei further weaken the weak hydrogen bonds and strengthen the strong ones. However, this trend was reversed when the hydrogen bond coupled to the local environment. These pioneering findings substantially advance our understanding of the quantum nature of H bonds at the molecular level. 
650 0 |a Spectroscopy. 
650 0 |a Microscopy. 
650 0 |a Atomic structure . 
650 0 |a Molecular structure . 
650 0 |a Surfaces (Physics). 
650 0 |a Interfaces (Physical sciences). 
650 0 |a Thin films. 
650 0 |a Physical chemistry. 
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