Covalent Functionalization of Graphene and Carbon Nanotubes by Radical Decarboxylation

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Názov: Covalent Functionalization of Graphene and Carbon Nanotubes by Radical Decarboxylation
Autori: Ashleigh L. Farnsworth, Yvonne Hora, Ruoxin Wang, Chima Anyaegbu, Bhagya Dharmasiri, Luke C. Henderson, Joel F. Hooper
Rok vydania: 2025
Predmety: Biochemistry, Medicine, Genetics, Pharmacology, Biotechnology, Cancer, Space Science, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Mathematical Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, complex drug molecule, two complementary methods, utilizing oxidative, small molecules, reductive conditions, radical decarboxylation, generate radicals, effective strategy, covalent modification, covalent functionalization, carboxylic acids, carbon nanotubes, active esters
Popis: We have demonstrated that the radical decarboxylation of carboxylic acids or redox-active esters is a simple and effective strategy for the covalent modification of graphene and carbon nanotubes. Two complementary methods are described in this paper, utilizing oxidative or reductive conditions to generate radicals from carboxylic acids or redox-active esters, respectively. We have applied these methods to the conjugation of small molecules, a complex drug molecule, and polymers to graphene and carbon nanotubes.
Druh dokumentu: article in journal/newspaper
Jazyk: unknown
Relation: https://figshare.com/articles/journal_contribution/Covalent_Functionalization_of_Graphene_and_Carbon_Nanotubes_by_Radical_Decarboxylation/29355336
DOI: 10.1021/acsami.5c04671.s001
Dostupnosť: https://doi.org/10.1021/acsami.5c04671.s001
https://figshare.com/articles/journal_contribution/Covalent_Functionalization_of_Graphene_and_Carbon_Nanotubes_by_Radical_Decarboxylation/29355336
Rights: CC BY-NC 4.0
Prístupové číslo: edsbas.EFE653DF
Databáza: BASE
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