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Covalent Functionalization of Graphene and Carbon Nanotubes by Radical Decarboxylation

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Title: Covalent Functionalization of Graphene and Carbon Nanotubes by Radical Decarboxylation
Authors: Ashleigh L. Farnsworth, Yvonne Hora, Ruoxin Wang, Chima Anyaegbu, Bhagya Dharmasiri, Luke C. Henderson, Joel F. Hooper
Publication Year: 2025
Subject Terms: Biochemistry, Medicine, Genetics, Pharmacology, Biotechnology, Cancer, Space Science, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Mathematical Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, complex drug molecule, two complementary methods, utilizing oxidative, small molecules, reductive conditions, radical decarboxylation, generate radicals, effective strategy, covalent modification, covalent functionalization, carboxylic acids, carbon nanotubes, active esters
Description: We have demonstrated that the radical decarboxylation of carboxylic acids or redox-active esters is a simple and effective strategy for the covalent modification of graphene and carbon nanotubes. Two complementary methods are described in this paper, utilizing oxidative or reductive conditions to generate radicals from carboxylic acids or redox-active esters, respectively. We have applied these methods to the conjugation of small molecules, a complex drug molecule, and polymers to graphene and carbon nanotubes.
Document Type: article in journal/newspaper
Language: unknown
Relation: https://figshare.com/articles/journal_contribution/Covalent_Functionalization_of_Graphene_and_Carbon_Nanotubes_by_Radical_Decarboxylation/29355336
DOI: 10.1021/acsami.5c04671.s001
Availability: https://doi.org/10.1021/acsami.5c04671.s001
https://figshare.com/articles/journal_contribution/Covalent_Functionalization_of_Graphene_and_Carbon_Nanotubes_by_Radical_Decarboxylation/29355336
Rights: CC BY-NC 4.0
Accession Number: edsbas.EFE653DF
Database: BASE
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  – Url: https://doi.org/10.1021/acsami.5c04671.s001#
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PubType: Academic Journal
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  Data: Covalent Functionalization of Graphene and Carbon Nanotubes by Radical Decarboxylation
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  Data: <searchLink fieldCode="AR" term="%22Ashleigh+L%2E+Farnsworth%22">Ashleigh L. Farnsworth</searchLink><br /><searchLink fieldCode="AR" term="%22Yvonne+Hora%22">Yvonne Hora</searchLink><br /><searchLink fieldCode="AR" term="%22Ruoxin+Wang%22">Ruoxin Wang</searchLink><br /><searchLink fieldCode="AR" term="%22Chima+Anyaegbu%22">Chima Anyaegbu</searchLink><br /><searchLink fieldCode="AR" term="%22Bhagya+Dharmasiri%22">Bhagya Dharmasiri</searchLink><br /><searchLink fieldCode="AR" term="%22Luke+C%2E+Henderson%22">Luke C. Henderson</searchLink><br /><searchLink fieldCode="AR" term="%22Joel+F%2E+Hooper%22">Joel F. Hooper</searchLink>
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  Data: 2025
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  Data: <searchLink fieldCode="DE" term="%22Biochemistry%22">Biochemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Medicine%22">Medicine</searchLink><br /><searchLink fieldCode="DE" term="%22Genetics%22">Genetics</searchLink><br /><searchLink fieldCode="DE" term="%22Pharmacology%22">Pharmacology</searchLink><br /><searchLink fieldCode="DE" term="%22Biotechnology%22">Biotechnology</searchLink><br /><searchLink fieldCode="DE" term="%22Cancer%22">Cancer</searchLink><br /><searchLink fieldCode="DE" term="%22Space+Science%22">Space Science</searchLink><br /><searchLink fieldCode="DE" term="%22Environmental+Sciences+not+elsewhere+classified%22">Environmental Sciences not elsewhere classified</searchLink><br /><searchLink fieldCode="DE" term="%22Biological+Sciences+not+elsewhere+classified%22">Biological Sciences not elsewhere classified</searchLink><br /><searchLink fieldCode="DE" term="%22Mathematical+Sciences+not+elsewhere+classified%22">Mathematical Sciences not elsewhere classified</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+Sciences+not+elsewhere+classified%22">Chemical Sciences not elsewhere classified</searchLink><br /><searchLink fieldCode="DE" term="%22complex+drug+molecule%22">complex drug molecule</searchLink><br /><searchLink fieldCode="DE" term="%22two+complementary+methods%22">two complementary methods</searchLink><br /><searchLink fieldCode="DE" term="%22utilizing+oxidative%22">utilizing oxidative</searchLink><br /><searchLink fieldCode="DE" term="%22small+molecules%22">small molecules</searchLink><br /><searchLink fieldCode="DE" term="%22reductive+conditions%22">reductive conditions</searchLink><br /><searchLink fieldCode="DE" term="%22radical+decarboxylation%22">radical decarboxylation</searchLink><br /><searchLink fieldCode="DE" term="%22generate+radicals%22">generate radicals</searchLink><br /><searchLink fieldCode="DE" term="%22effective+strategy%22">effective strategy</searchLink><br /><searchLink fieldCode="DE" term="%22covalent+modification%22">covalent modification</searchLink><br /><searchLink fieldCode="DE" term="%22covalent+functionalization%22">covalent functionalization</searchLink><br /><searchLink fieldCode="DE" term="%22carboxylic+acids%22">carboxylic acids</searchLink><br /><searchLink fieldCode="DE" term="%22carbon+nanotubes%22">carbon nanotubes</searchLink><br /><searchLink fieldCode="DE" term="%22active+esters%22">active esters</searchLink>
– Name: Abstract
  Label: Description
  Group: Ab
  Data: We have demonstrated that the radical decarboxylation of carboxylic acids or redox-active esters is a simple and effective strategy for the covalent modification of graphene and carbon nanotubes. Two complementary methods are described in this paper, utilizing oxidative or reductive conditions to generate radicals from carboxylic acids or redox-active esters, respectively. We have applied these methods to the conjugation of small molecules, a complex drug molecule, and polymers to graphene and carbon nanotubes.
– Name: TypeDocument
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  Data: article in journal/newspaper
– Name: Language
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  Data: unknown
– Name: NoteTitleSource
  Label: Relation
  Group: SrcInfo
  Data: https://figshare.com/articles/journal_contribution/Covalent_Functionalization_of_Graphene_and_Carbon_Nanotubes_by_Radical_Decarboxylation/29355336
– Name: DOI
  Label: DOI
  Group: ID
  Data: 10.1021/acsami.5c04671.s001
– Name: URL
  Label: Availability
  Group: URL
  Data: https://doi.org/10.1021/acsami.5c04671.s001<br />https://figshare.com/articles/journal_contribution/Covalent_Functionalization_of_Graphene_and_Carbon_Nanotubes_by_Radical_Decarboxylation/29355336
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  Data: CC BY-NC 4.0
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  Label: Accession Number
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  Data: edsbas.EFE653DF
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        Value: 10.1021/acsami.5c04671.s001
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      – Text: unknown
    Subjects:
      – SubjectFull: Biochemistry
        Type: general
      – SubjectFull: Medicine
        Type: general
      – SubjectFull: Genetics
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      – SubjectFull: Pharmacology
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      – SubjectFull: Chemical Sciences not elsewhere classified
        Type: general
      – SubjectFull: complex drug molecule
        Type: general
      – SubjectFull: two complementary methods
        Type: general
      – SubjectFull: utilizing oxidative
        Type: general
      – SubjectFull: small molecules
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      – SubjectFull: reductive conditions
        Type: general
      – SubjectFull: radical decarboxylation
        Type: general
      – SubjectFull: generate radicals
        Type: general
      – SubjectFull: effective strategy
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      – SubjectFull: covalent modification
        Type: general
      – SubjectFull: covalent functionalization
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      – SubjectFull: carboxylic acids
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      – SubjectFull: carbon nanotubes
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      – SubjectFull: active esters
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      – TitleFull: Covalent Functionalization of Graphene and Carbon Nanotubes by Radical Decarboxylation
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            NameFull: Ashleigh L. Farnsworth
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              Y: 2025
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