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Multistage Networks for Glassy Holographic Photopolymers

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Titel: Multistage Networks for Glassy Holographic Photopolymers
Autoren: Alexander J. Osterbaan, Andrew N. Sias, Marianela Trujillo-Lemon, Kieran Fung, Jason P. Killgore, Robert R. McLeod, Christopher N. Bowman
Publikationsjahr: 2025
Schlagwörter: Medicine, Neuroscience, Physiology, Biotechnology, Evolutionary Biology, Ecology, Developmental Biology, Computational Biology, Space Science, Chemical Sciences not elsewhere classified, ultimate thermomechanical properties, typical polyurethane matrix, 101 ° c, final glassy nature, diffraction grating structure, glassy holographic photopolymers, final holographic photopolymer, final holographic material, materials promote thermal, g , holographic photopolymers, diffraction efficiency, >< sub, thermally latent, stage design, stage cure, multistage networks, index contrast, high fidelity, epoxide cure
Beschreibung: In the writing of holographic photopolymers, the addition of a third-stage cure to the typical polyurethane matrix and acrylate writing monomer steps is used here to modify the ultimate thermomechanical properties of the final holographic photopolymer. Inclusion of a thermally latent, low-refractive-index epoxide homopolymerization increases the T g from a value of −22 °C during the writing step to a final T g of 101 °C after the epoxide cure. Critically, the diffraction grating structure is retained with high fidelity, an index contrast of 0.0057, and a diffraction efficiency of 89% achieved in these materials. Ultimately, the 3-stage design and final glassy nature of these materials promote thermal and dimensional stability of the final holographic material.
Publikationsart: article in journal/newspaper
Sprache: unknown
Relation: https://figshare.com/articles/journal_contribution/Multistage_Networks_for_Glassy_Holographic_Photopolymers/28955605
DOI: 10.1021/acsami.5c04731.s001
Verfügbarkeit: https://doi.org/10.1021/acsami.5c04731.s001
https://figshare.com/articles/journal_contribution/Multistage_Networks_for_Glassy_Holographic_Photopolymers/28955605
Rights: CC BY-NC 4.0
Dokumentencode: edsbas.58B5EFC7
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– Name: Abstract
  Label: Description
  Group: Ab
  Data: In the writing of holographic photopolymers, the addition of a third-stage cure to the typical polyurethane matrix and acrylate writing monomer steps is used here to modify the ultimate thermomechanical properties of the final holographic photopolymer. Inclusion of a thermally latent, low-refractive-index epoxide homopolymerization increases the T g from a value of −22 &#176;C during the writing step to a final T g of 101 &#176;C after the epoxide cure. Critically, the diffraction grating structure is retained with high fidelity, an index contrast of 0.0057, and a diffraction efficiency of 89% achieved in these materials. Ultimately, the 3-stage design and final glassy nature of these materials promote thermal and dimensional stability of the final holographic material.
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  Data: https://figshare.com/articles/journal_contribution/Multistage_Networks_for_Glassy_Holographic_Photopolymers/28955605
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  Data: 10.1021/acsami.5c04731.s001
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        Value: 10.1021/acsami.5c04731.s001
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    Subjects:
      – SubjectFull: Medicine
        Type: general
      – SubjectFull: Neuroscience
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        Type: general
      – SubjectFull: ultimate thermomechanical properties
        Type: general
      – SubjectFull: typical polyurethane matrix
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      – SubjectFull: 101 ° c
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      – SubjectFull: final glassy nature
        Type: general
      – SubjectFull: diffraction grating structure
        Type: general
      – SubjectFull: glassy holographic photopolymers
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      – SubjectFull: final holographic photopolymer
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      – SubjectFull: final holographic material
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      – SubjectFull: materials promote thermal
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      – SubjectFull: g </ sub
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      – SubjectFull: holographic photopolymers
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      – SubjectFull: diffraction efficiency
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      – SubjectFull: thermally latent
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      – SubjectFull: stage design
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      – SubjectFull: stage cure
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      – SubjectFull: index contrast
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      – SubjectFull: epoxide cure
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      – TitleFull: Multistage Networks for Glassy Holographic Photopolymers
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              Y: 2025
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