Magnetically recoverable nanostructured Pd complex of dendrimeric type ligand on the MCM-41: Preparation, characterization and catalytic activity in the Heck reaction
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| Title: | Magnetically recoverable nanostructured Pd complex of dendrimeric type ligand on the MCM-41: Preparation, characterization and catalytic activity in the Heck reaction |
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| Authors: | Zahra Ramazani, Mohammad Abdollahi-Alibeik, Najmeh Gharibpour |
| Source: | Main Group Metal Chemistry, Vol 43, Iss 1, Pp 184-199 (2020) |
| Publisher Information: | Walter de Gruyter GmbH, 2020. |
| Publication Year: | 2020 |
| Subject Terms: | mcm-41, reusable catalyst, fe3o4, 02 engineering and technology, palladium complex, 01 natural sciences, 0104 chemical sciences, 3. Good health, heck reaction, dendrimer ligand, Chemistry, 13. Climate action, 0210 nano-technology, QD1-999 |
| Description: | A palladium complex of a dendrimer type ligand of aminoethylacrylamide immobilized onto the mesoporous channels of MCM-41 with magnetic core was prepared and characterized using various techniques such as XRD, TEM, BET, FT-IR, TGA, and VSM. The prepared nanostructured material was found as a magnetically recoverable catalyst for Heck reaction of aryl halides and vinylic C–H. The catalyst is easily recoverable with an external magnet and is reusable with different leaching amounts depending to loading of Pd. A hot filtration test was also performed and gave evidence that Palladium in heterogeneous samples can dissolve and then redeposit on the surface of the support material. |
| Document Type: | Article |
| Language: | English |
| ISSN: | 2191-0219 0792-1241 |
| DOI: | 10.1515/mgmc-2020-0023 |
| Access URL: | https://www.degruyter.com/document/doi/10.1515/mgmc-2020-0023/pdf https://doaj.org/article/91ae10575a1b4f4bb0baa3dc0ba3710f https://www.degruyter.com/document/doi/10.1515/mgmc-2020-0023/html |
| Rights: | CC BY |
| Accession Number: | edsair.doi.dedup.....ccfc00d42a2d1c5c74bb97b5a8be4d4c |
| Database: | OpenAIRE |
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Nájsť tento článok vo Web of Science | Abstract: | A palladium complex of a dendrimer type ligand of aminoethylacrylamide immobilized onto the mesoporous channels of MCM-41 with magnetic core was prepared and characterized using various techniques such as XRD, TEM, BET, FT-IR, TGA, and VSM. The prepared nanostructured material was found as a magnetically recoverable catalyst for Heck reaction of aryl halides and vinylic C–H. The catalyst is easily recoverable with an external magnet and is reusable with different leaching amounts depending to loading of Pd. A hot filtration test was also performed and gave evidence that Palladium in heterogeneous samples can dissolve and then redeposit on the surface of the support material. |
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| ISSN: | 21910219 07921241 |
| DOI: | 10.1515/mgmc-2020-0023 |