An 80-Carbon Aromatic Saddle Enabled by a Naphthalene-Directed Scholl Reaction
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| Title: | An 80-Carbon Aromatic Saddle Enabled by a Naphthalene-Directed Scholl Reaction |
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| Authors: | Sai Ho Pun, Chi Kit Chan, Zhifeng Liu, Qian Miao |
| Source: | Organic Materials, Vol 02, Iss 03, Pp 248-252 (2020) |
| Publisher Information: | Georg Thieme Verlag KG, 2020. |
| Publication Year: | 2020 |
| Subject Terms: | 2. Zero hunger, Chemistry, eight-membered ring, negative curvature, QD1-999, 01 natural sciences, scholl reaction, polycyclic aromatics, 0104 chemical sciences, 3. Good health |
| Description: | Synthesis of an unprecedented aromatic saddle consisting of 80 sp2 carbons is enabled by including naphthylene groups in the substrate of the Scholl reaction. The negatively curved polycyclic framework of this aromatic saddle is revealed by the single crystal X-ray crystallography, and its stereodynamics are studied with density functional theory calculations. |
| Document Type: | Article Other literature type |
| Language: | English |
| ISSN: | 2625-1825 |
| DOI: | 10.1055/s-0040-1716499 |
| Access URL: | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1716499.pdf https://doaj.org/article/733b96f36068437a83c76e2432627c39 https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0040-1716499 https://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1716499.pdf https://www.thieme-connect.com/products/ejournals/html/10.1055/s-0040-1716499 https://www.thieme-connect.com/products/ejournals/pdf/10.1055/s-0040-1716499.pdf |
| Rights: | CC BY |
| Accession Number: | edsair.doi.dedup.....ae8a6a41c8923c66a578d33c8f408c1a |
| Database: | OpenAIRE |
Nájsť tento článok vo Web of Science | Abstract: | Synthesis of an unprecedented aromatic saddle consisting of 80 sp2 carbons is enabled by including naphthylene groups in the substrate of the Scholl reaction. The negatively curved polycyclic framework of this aromatic saddle is revealed by the single crystal X-ray crystallography, and its stereodynamics are studied with density functional theory calculations. |
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| ISSN: | 26251825 |
| DOI: | 10.1055/s-0040-1716499 |