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Atomic modifications by synchrotron radiation at the calcite–ethanol interface

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Title: Atomic modifications by synchrotron radiation at the calcite–ethanol interface
Authors: Pasarín, I. S., Bovet, Nicolas Emile, Glyvradal, Magni, Nielsen, Martin Meedom, Bohr, Jakob, Feidenhans'l, R., Stipp, Susan Louise Svane
Source: Journal of synchrotron radiation 19, 530-535 (2012). doi:10.1107/S0909049512021504
Pasarín, I S, Bovet, N E, Glyvradal, M, Nielsen, M M, Bohr, J, Feidenhans'l, R & Stipp, S L S 2012, ' Atomic modifications by synchrotron radiation at the calcite-ethanol interface ', Journal of Synchrotron Radiation, vol. 19, no. 4, pp. 530-535 . https://doi.org/10.1107/S0909049512021504
Publisher Information: International Union of Crystallography (IUCr), 2012.
Publication Year: 2012
Subject Terms: X-ray photoelectron spectroscopy, Ethanol, Calcium Carbonate: radiation effects, Surface Properties, Photoelectron Spectroscopy, Calcite, Ethanol: radiation effects, Hydrogen Bonding, X-ray reflectivity, Interface, 01 natural sciences, Calcium Carbonate, Calcium Carbonate: chemistry, Ethanol: chemistry, Synchrotrons, 0105 earth and related environmental sciences
Description: This article reports on studies of the chemical alterations induced by synchrotron radiation at the calcite-ethanol interface, a simple model system for interfaces between minerals and more complex organic molecules containing OH groups. A combination of X-ray reflectivity and X-ray photoelectron spectroscopy of natural calcite, cleaved in distilled ethanol to obtain new clean interfaces, indicated that, during a 5 h period, the two top atomic layers of calcite, CaCO(3), transform into calcium oxide, CaO, by releasing CO(2). Also, the occupation of the first ordered layer of ethanol attached to calcite by hydrogen bonds almost doubles. Comparison between radiated and non-radiated areas of the same samples demonstrate that these effects are induced only by radiation and not caused by aging. These observations contribute to establishing a time limit for synchrotron experiments involving fluid-mineral interfaces where the polar OH group, as present in ethanol, plays a key role in their molecular structure and bonding. Also, the chemical evolution observed in the interface provides new insight into the behavior of some complex organic molecules involved in biomineralization processes.
Document Type: Article
File Description: application/pdf
ISSN: 1600-5775
0909-0495
DOI: 10.1107/s0909049512021504
Access URL: https://backend.orbit.dtu.dk/ws/files/56550664/co5014.pdf
https://pubmed.ncbi.nlm.nih.gov/22713885
http://europepmc.org/abstract/MED/22713885
https://www.ncbi.nlm.nih.gov/pubmed/22713885
https://scripts.iucr.org/cgi-bin/paper?S0909049512021504
https://orbit.dtu.dk/en/publications/atomic-modifications-by-synchrotron-radiation-at-the-calciteethanol-interface(dfd83adf-b858-4cd3-baa9-d4b30f23d2ec).html
https://orbit.dtu.dk/files/56550664/co5014.pdf
https://pubmed.ncbi.nlm.nih.gov/22713885/
https://bib-pubdb1.desy.de/record/143940
https://orbit.dtu.dk/en/publications/dfd83adf-b858-4cd3-baa9-d4b30f23d2ec
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Accession Number: edsair.doi.dedup.....9fa32161b35e8e958fcf28c97ff2094c
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  Data: Atomic modifications by synchrotron radiation at the calcite–ethanol interface
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  Data: <searchLink fieldCode="AR" term="%22Pasarín%2C+I%2E+S%2E%22">Pasarín, I. S.</searchLink><br /><searchLink fieldCode="AR" term="%22Bovet%2C+Nicolas+Emile%22">Bovet, Nicolas Emile</searchLink><br /><searchLink fieldCode="AR" term="%22Glyvradal%2C+Magni%22">Glyvradal, Magni</searchLink><br /><searchLink fieldCode="AR" term="%22Nielsen%2C+Martin+Meedom%22">Nielsen, Martin Meedom</searchLink><br /><searchLink fieldCode="AR" term="%22Bohr%2C+Jakob%22">Bohr, Jakob</searchLink><br /><searchLink fieldCode="AR" term="%22Feidenhans'l%2C+R%2E%22">Feidenhans'l, R.</searchLink><br /><searchLink fieldCode="AR" term="%22Stipp%2C+Susan+Louise+Svane%22">Stipp, Susan Louise Svane</searchLink>
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  Data: Journal of synchrotron radiation 19, 530-535 (2012). doi:10.1107/S0909049512021504<br />Pasarín, I S, Bovet, N E, Glyvradal, M, Nielsen, M M, Bohr, J, Feidenhans'l, R & Stipp, S L S 2012, ' Atomic modifications by synchrotron radiation at the calcite-ethanol interface ', Journal of Synchrotron Radiation, vol. 19, no. 4, pp. 530-535 . https://doi.org/10.1107/S0909049512021504
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  Data: This article reports on studies of the chemical alterations induced by synchrotron radiation at the calcite-ethanol interface, a simple model system for interfaces between minerals and more complex organic molecules containing OH groups. A combination of X-ray reflectivity and X-ray photoelectron spectroscopy of natural calcite, cleaved in distilled ethanol to obtain new clean interfaces, indicated that, during a 5 h period, the two top atomic layers of calcite, CaCO(3), transform into calcium oxide, CaO, by releasing CO(2). Also, the occupation of the first ordered layer of ethanol attached to calcite by hydrogen bonds almost doubles. Comparison between radiated and non-radiated areas of the same samples demonstrate that these effects are induced only by radiation and not caused by aging. These observations contribute to establishing a time limit for synchrotron experiments involving fluid-mineral interfaces where the polar OH group, as present in ethanol, plays a key role in their molecular structure and bonding. Also, the chemical evolution observed in the interface provides new insight into the behavior of some complex organic molecules involved in biomineralization processes.
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      – SubjectFull: X-ray photoelectron spectroscopy
        Type: general
      – SubjectFull: Ethanol
        Type: general
      – SubjectFull: Calcium Carbonate: radiation effects
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