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Ion-Selective Properties of Armbrusterite Mineral and the Prospects for Its Laboratory Synthesis.

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Titel: Ion-Selective Properties of Armbrusterite Mineral and the Prospects for Its Laboratory Synthesis.
Autoren: Gryaznova, Darya, Panikorovskii, Taras, Kalashnikova, Galina, Bazai, Ayya, Glazunova, Margarita, Selivanova, Ekaterina, Gosteva, Alevtina, Yakovenchuk, Victor
Quelle: Molecules; Nov2025, Vol. 30 Issue 22, p4385, 20p
Schlagwörter: SORBENTS, CRYSTAL structure, CHEMICAL synthesis, SILICATE minerals, INFRARED spectroscopy, X-ray diffraction, ELECTRON microscopy
Abstract: In this paper, results of studying the properties of armbrusterite, a natural heterophyllosilicate, are presented. Due to its crystal structure consisting of parallel HOH-type sheets separated by a network of large-diameter (4–6 Å) channels, this mineral is of interest as a prototype for producing novel compounds to be used as sorbents. The studies were conducted by X-ray powder diffraction and X-ray single crystal diffraction analyses, electron microscopy, and IR spectroscopy. The natural sample is shown to be able to selectively extract monovalent cations from the solution of complex composition consisting of mono- and divalent salts. Furthermore, the preliminary results of hydrothermal synthesis of an analog of this mineral are reported. It is demonstrated that the mineral can be produced under milder conditions than the known methods for synthesizing heterophyllosilicates using platinum capsules (Tuttle bombs) at 380–450 °C. [ABSTRACT FROM AUTHOR]
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  Data: Ion-Selective Properties of Armbrusterite Mineral and the Prospects for Its Laboratory Synthesis.
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  Data: Molecules; Nov2025, Vol. 30 Issue 22, p4385, 20p
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  Data: <searchLink fieldCode="DE" term="%22SORBENTS%22">SORBENTS</searchLink><br /><searchLink fieldCode="DE" term="%22CRYSTAL+structure%22">CRYSTAL structure</searchLink><br /><searchLink fieldCode="DE" term="%22CHEMICAL+synthesis%22">CHEMICAL synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22SILICATE+minerals%22">SILICATE minerals</searchLink><br /><searchLink fieldCode="DE" term="%22INFRARED+spectroscopy%22">INFRARED spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22ELECTRON+microscopy%22">ELECTRON microscopy</searchLink>
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  Label: Abstract
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  Data: In this paper, results of studying the properties of armbrusterite, a natural heterophyllosilicate, are presented. Due to its crystal structure consisting of parallel HOH-type sheets separated by a network of large-diameter (4–6 Å) channels, this mineral is of interest as a prototype for producing novel compounds to be used as sorbents. The studies were conducted by X-ray powder diffraction and X-ray single crystal diffraction analyses, electron microscopy, and IR spectroscopy. The natural sample is shown to be able to selectively extract monovalent cations from the solution of complex composition consisting of mono- and divalent salts. Furthermore, the preliminary results of hydrothermal synthesis of an analog of this mineral are reported. It is demonstrated that the mineral can be produced under milder conditions than the known methods for synthesizing heterophyllosilicates using platinum capsules (Tuttle bombs) at 380–450 °C. [ABSTRACT FROM AUTHOR]
– Name: Abstract
  Label:
  Group: Ab
  Data: <i>Copyright of Molecules is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/molecules30224385
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      – Code: eng
        Text: English
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      – SubjectFull: SORBENTS
        Type: general
      – SubjectFull: CRYSTAL structure
        Type: general
      – SubjectFull: CHEMICAL synthesis
        Type: general
      – SubjectFull: SILICATE minerals
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      – SubjectFull: X-ray diffraction
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      – SubjectFull: ELECTRON microscopy
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            NameFull: Gryaznova, Darya
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            NameFull: Panikorovskii, Taras
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              Text: Nov2025
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              Y: 2025
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