Effects of Intermetallic Diffusion and Layer on the Fracture Mechanism of the Al–(Si)‐Coated 22MnB5 Plate by Magnetron Sputtering.

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Titel: Effects of Intermetallic Diffusion and Layer on the Fracture Mechanism of the Al–(Si)‐Coated 22MnB5 Plate by Magnetron Sputtering.
Autoren: Yu, Pengchao1 (AUTHOR), Zhang, Kaice2 (AUTHOR), Lv, Zhe1 (AUTHOR) lz19870522@126.com, Zhou, Yanwen1 (AUTHOR) zhouyanwen1966@163.com, Chen, Yu2 (AUTHOR)
Quelle: Steel Research International. Nov2025, Vol. 96 Issue 11, p118-129. 12p.
Schlagwörter: *EMBRITTLEMENT, *MAGNETRON sputtering, *KIRKENDALL effect, *DIFFUSION kinetics, *FRACTURE mechanics, *SILICON steel, *HOT pressing
Abstract: Although the application of hot‐dipped Al–Si‐coated steel in production processes prevents the high‐temperature oxidation and decarburization of uncoated steel, its intermetallic compounds and Kirkendall void cause embrittlement. Physical vapor deposition techniques such as magnetron sputtering (MS) have a lower working temperature, which can prevent the formation of alloy layers during coating preparation, thereby alleviating the imbalance in diffusion and embrittlement caused by Kirkendall void. Herein, Al–(Si)‐coated 22MnB5 steel is prepared via MS to compare the differences in morphology, element diffusion, alloy phase composition, and fracture toughness after hot stamping the Al–(Si)‐coated steel prepared by hot dipping. The results show that because of the lack of preformed alloy phase layers, the elemental diffusion of MS Al–(Si)‐coated steel during hot stamping is not suppressed, and the elements in the diffusion layer diffuse evenly, with a limited number of holes generated. In the MS Al–(Si)‐coated steel, the ratio of the alloy phase layer to the diffusion layer is ≈0.8, while the ratio for hot‐dip coated steel is 1.8, indicating that the hot‐dipped Al–(Si)‐coated steel produces more brittle intermetallic compound (IMC) phases during hot stamping, resulting in higher embrittlement caused by IMC phases during processing. [ABSTRACT FROM AUTHOR]
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  Data: Effects of Intermetallic Diffusion and Layer on the Fracture Mechanism of the Al–(Si)‐Coated 22MnB5 Plate by Magnetron Sputtering.
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  Data: <searchLink fieldCode="AR" term="%22Yu%2C+Pengchao%22">Yu, Pengchao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Kaice%22">Zhang, Kaice</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Lv%2C+Zhe%22">Lv, Zhe</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> lz19870522@126.com</i><br /><searchLink fieldCode="AR" term="%22Zhou%2C+Yanwen%22">Zhou, Yanwen</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> zhouyanwen1966@163.com</i><br /><searchLink fieldCode="AR" term="%22Chen%2C+Yu%22">Chen, Yu</searchLink><relatesTo>2</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Steel+Research+International%22">Steel Research International</searchLink>. Nov2025, Vol. 96 Issue 11, p118-129. 12p.
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  Data: *<searchLink fieldCode="DE" term="%22EMBRITTLEMENT%22">EMBRITTLEMENT</searchLink><br />*<searchLink fieldCode="DE" term="%22MAGNETRON+sputtering%22">MAGNETRON sputtering</searchLink><br />*<searchLink fieldCode="DE" term="%22KIRKENDALL+effect%22">KIRKENDALL effect</searchLink><br />*<searchLink fieldCode="DE" term="%22DIFFUSION+kinetics%22">DIFFUSION kinetics</searchLink><br />*<searchLink fieldCode="DE" term="%22FRACTURE+mechanics%22">FRACTURE mechanics</searchLink><br />*<searchLink fieldCode="DE" term="%22SILICON+steel%22">SILICON steel</searchLink><br />*<searchLink fieldCode="DE" term="%22HOT+pressing%22">HOT pressing</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Although the application of hot‐dipped Al–Si‐coated steel in production processes prevents the high‐temperature oxidation and decarburization of uncoated steel, its intermetallic compounds and Kirkendall void cause embrittlement. Physical vapor deposition techniques such as magnetron sputtering (MS) have a lower working temperature, which can prevent the formation of alloy layers during coating preparation, thereby alleviating the imbalance in diffusion and embrittlement caused by Kirkendall void. Herein, Al–(Si)‐coated 22MnB5 steel is prepared via MS to compare the differences in morphology, element diffusion, alloy phase composition, and fracture toughness after hot stamping the Al–(Si)‐coated steel prepared by hot dipping. The results show that because of the lack of preformed alloy phase layers, the elemental diffusion of MS Al–(Si)‐coated steel during hot stamping is not suppressed, and the elements in the diffusion layer diffuse evenly, with a limited number of holes generated. In the MS Al–(Si)‐coated steel, the ratio of the alloy phase layer to the diffusion layer is ≈0.8, while the ratio for hot‐dip coated steel is 1.8, indicating that the hot‐dipped Al–(Si)‐coated steel produces more brittle intermetallic compound (IMC) phases during hot stamping, resulting in higher embrittlement caused by IMC phases during processing. [ABSTRACT FROM AUTHOR]
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1002/srin.202400801
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 12
        StartPage: 118
    Subjects:
      – SubjectFull: EMBRITTLEMENT
        Type: general
      – SubjectFull: MAGNETRON sputtering
        Type: general
      – SubjectFull: KIRKENDALL effect
        Type: general
      – SubjectFull: DIFFUSION kinetics
        Type: general
      – SubjectFull: FRACTURE mechanics
        Type: general
      – SubjectFull: SILICON steel
        Type: general
      – SubjectFull: HOT pressing
        Type: general
    Titles:
      – TitleFull: Effects of Intermetallic Diffusion and Layer on the Fracture Mechanism of the Al–(Si)‐Coated 22MnB5 Plate by Magnetron Sputtering.
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            NameFull: Yu, Pengchao
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            NameFull: Zhang, Kaice
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            NameFull: Lv, Zhe
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            NameFull: Zhou, Yanwen
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            – D: 01
              M: 11
              Text: Nov2025
              Type: published
              Y: 2025
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